{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670321098641536.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/smll.201700936"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fsmll.201700936"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/smll.201700936"}}],"dc:title":[{"@value":"Graphdiyne‐Supported NiCo<sub>2</sub>S<sub>4</sub> Nanowires: A Highly Active and Stable 3D Bifunctional Electrode Material"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and overall water splitting are major energy and chemical conversion efforts. Progress in electrocatalytic reactions have shown that the future is limitless in many fields. However, it is urgent to develop efficient electrocatalysts. Here, the first graphdiyne‐supported efficient and bifunctional electrocatalyst is reported using 3D graphdiyne foam as scaffolds, and NiCo<jats:sub>2</jats:sub>S<jats:sub>4</jats:sub> nanowires as building blocks (NiCo<jats:sub>2</jats:sub>S<jats:sub>4</jats:sub> NW/GDF). NiCo<jats:sub>2</jats:sub>S<jats:sub>4</jats:sub> NW/GDF exhibits outstanding catalytic activity and stability toward both OER and HER, as well as overall water splitting in alkaline media. Remarkably, it enables a high‐performance alkaline water electrolyzer with 10 and 20 mA cm<jats:sup>−2</jats:sup> at very low cell voltages of 1.53 and 1.56 V, respectively, and remarkable stability over 140 h of continuous electrolysis operation at 20 mA cm<jats:sup>−2</jats:sup>. The results indicate that this catalyst has a bifunction that overcomes all reported bifunctional, nonprecious‐metal‐based ones.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670321098641536","@type":"Researcher","foaf:name":[{"@value":"Yurui Xue"}],"jpcoar:affiliationName":[{"@value":"Beijing National Laboratory for Molecular Sciences (BNLMS) CAS Key Laboratory of Organic Solids Institute of Chemistry CAS Research/Education Center for Excellence in Molecular Sciences Chinese Academy of Sciences  Beijing 100190 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321098641539","@type":"Researcher","foaf:name":[{"@value":"Zicheng Zuo"}],"jpcoar:affiliationName":[{"@value":"Beijing National Laboratory for Molecular Sciences (BNLMS) CAS Key Laboratory of Organic Solids Institute of Chemistry CAS Research/Education Center for Excellence in Molecular Sciences Chinese Academy of Sciences  Beijing 100190 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321098641540","@type":"Researcher","foaf:name":[{"@value":"Yongjun Li"}],"jpcoar:affiliationName":[{"@value":"Beijing National Laboratory for Molecular Sciences (BNLMS) CAS Key Laboratory of Organic Solids Institute of Chemistry CAS Research/Education Center for Excellence in Molecular Sciences Chinese Academy of Sciences  Beijing 100190 P. R. China"},{"@value":"School of Chemistry and Chemical Engineering University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321098641538","@type":"Researcher","foaf:name":[{"@value":"Huibiao Liu"}],"jpcoar:affiliationName":[{"@value":"Beijing National Laboratory for Molecular Sciences (BNLMS) CAS Key Laboratory of Organic Solids Institute of Chemistry CAS Research/Education Center for Excellence in Molecular Sciences Chinese Academy of Sciences  Beijing 100190 P. R. China"},{"@value":"School of Chemistry and Chemical Engineering University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321098641537","@type":"Researcher","foaf:name":[{"@value":"Yuliang Li"}],"jpcoar:affiliationName":[{"@value":"Beijing National Laboratory for Molecular Sciences (BNLMS) CAS Key Laboratory of Organic Solids Institute of Chemistry CAS Research/Education Center for Excellence in Molecular Sciences Chinese Academy of Sciences  Beijing 100190 P. R. China"},{"@value":"School of Chemistry and Chemical Engineering University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16136810"},{"@type":"EISSN","@value":"16136829"}],"prism:publicationName":[{"@value":"Small"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2017-06-14","prism:volume":"13","prism:number":"31","prism:startingPage":"1700936"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fsmll.201700936"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/smll.201700936"}],"createdAt":"2017-06-14","modifiedAt":"2023-10-05","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285708609263232","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A pyrazine-incorporated graphdiyne nanofilm as a metal-free electrocatalyst for the hydrogen evolution reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793935784064","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The Accelerating World of Graphdiynes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/smll.201700936"},{"@type":"CROSSREF","@value":"10.1039/c8ta07347c_references_DOI_14g5uvmc81ROG06ySv6kQqiDttf"},{"@type":"CROSSREF","@value":"10.1002/adma.201804211_references_DOI_14g5uvmc81ROG06ySv6kQqiDttf"}]}