{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670321140865280.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/adfm.201200696"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.201200696"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.201200696"}}],"dc:title":[{"@value":"Phosphorous Pentasulfide as a Novel Additive for High‐Performance Lithium‐Sulfur Batteries"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Lithium‐sulfur (Li‐S) batteries suffer from rapid capacity decay and low energy efficiency because of the low solubility of lithium sulfide (Li<jats:sub>2</jats:sub>S) in organic solvents and the intrinsic polysulfide shuttle phenomenon. Here, a novel additive, phosphorus pentasulfide (P<jats:sub>2</jats:sub>S<jats:sub>5</jats:sub>) in organic electrolyte, is reported to boost the cycling performance of Li‐S batteries. The function of the additive is two‐fold: 1) P<jats:sub>2</jats:sub>S<jats:sub>5</jats:sub> promotes the dissolution of Li<jats:sub>2</jats:sub>S and alleviates the loss of capacity caused by the precipitation of Li<jats:sub>2</jats:sub>S and 2) P<jats:sub>2</jats:sub>S<jats:sub>5</jats:sub> passivates the surface of lithium metal and therefore eliminates the polysulfide shuttle phenomenon. A Li‐S test cell demonstrates a high reversible capacity of 900–1350 mAh g<jats:sup>−1</jats:sup> and a high coulombic efficiency of ≥90% for at least 40 stable cycles at 0.1 C.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670321140865408","@type":"Researcher","foaf:name":[{"@value":"Zhan Lin"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321140865409","@type":"Researcher","foaf:name":[{"@value":"Zengcai Liu"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321140865280","@type":"Researcher","foaf:name":[{"@value":"Wujun Fu"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321140865411","@type":"Researcher","foaf:name":[{"@value":"Nancy J. Dudney"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321140865410","@type":"Researcher","foaf:name":[{"@value":"Chengdu Liang"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1616301X"},{"@type":"EISSN","@value":"16163028"}],"prism:publicationName":[{"@value":"Advanced Functional Materials"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2012-06-14","prism:volume":"23","prism:number":"8","prism:startingPage":"1064","prism:endingPage":"1069"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.201200696"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.201200696"}],"createdAt":"2012-06-14","modifiedAt":"2025-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285707295803520","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Potentiostatic way to fabricate Li2Sx cathode with suppressed polysulfide formation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846639473200512","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electrochemical Performance of All‐Solid‐State Li/S Batteries with Sulfur‐Based Composite Electrodes Prepared by Mechanical Milling at High Temperature"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846640970570368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effects of compatibility of polymer binders with solvate ionic liquid electrolytes on discharge and charge reactions of lithium-sulfur batteries"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641602887680","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ionic Liquid Electrolytes for Lithium–Sulfur Batteries"}]},{"@id":"https://cir.nii.ac.jp/crid/1391412326419437184","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrochemical Evaluation of Lithium-Metal Anode in Highly Concentrated Ethylene Carbonate Based Electrolytes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adfm.201200696"},{"@type":"CROSSREF","@value":"10.1002/ente.201200019_references_DOI_UPwmXvcmpO7ARubn6EGytR4M5Ww"},{"@type":"CROSSREF","@value":"10.1021/jp408037e_references_DOI_UPwmXvcmpO7ARubn6EGytR4M5Ww"},{"@type":"CROSSREF","@value":"10.5796/electrochemistry.20-00087_references_DOI_UPwmXvcmpO7ARubn6EGytR4M5Ww"},{"@type":"CROSSREF","@value":"10.1016/j.jpowsour.2018.07.107_references_DOI_UPwmXvcmpO7ARubn6EGytR4M5Ww"},{"@type":"CROSSREF","@value":"10.1016/j.jpowsour.2016.01.045_references_DOI_UPwmXvcmpO7ARubn6EGytR4M5Ww"}]}