{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363670321142736128.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1139/v97-054"}},{"identifier":{"@type":"URI","@value":"https://cdnsciencepub.com/doi/pdf/10.1139/v97-054"}}],"dc:title":[{"@value":"Observation of a single-pot aromatic reductive denitration"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p> 4,N,N-Trimethyl-3-nitrobenzenamine gave reductive denitration products (ca. 28%) upon treatment with n-butyl nitrite in the presence of catalytic amounts of ammonium chloride and water in an unprecedented one-reagent single-pot process. The three isomeric N,N-dimethylnitrobenzenamines showed the same behaviour to a much lesser extent; the ortho isomer was partially (7%) transformed into 1-methylbenzotriazole. Keywords: aromatic protolytic denitration, nitroaromatics, n-butyl nitrite, E- and Z-nitrosamine. </jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383670321142736128","@type":"Researcher","foaf:name":[{"@value":"Angelo G. Giumanini"}]},{"@id":"https://cir.nii.ac.jp/crid/1383670321142736129","@type":"Researcher","foaf:name":[{"@value":"Giancarlo Verardo"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00084042"},{"@type":"EISSN","@value":"14803291"}],"prism:publicationName":[{"@value":"Canadian Journal of Chemistry"}],"dc:publisher":[{"@value":"Canadian Science Publishing"}],"prism:publicationDate":"1997-04-01","prism:volume":"75","prism:number":"4","prism:startingPage":"469","prism:endingPage":"473"},"reviewed":"false","dc:rights":["http://www.nrcresearchpress.com/page/about/CorporateTextAndDataMining"],"url":[{"@id":"https://cdnsciencepub.com/doi/pdf/10.1139/v97-054"}],"createdAt":"2006-05-09","modifiedAt":"2025-07-02","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360009142579664256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Transition-Metal-Catalyzed Denitrative Coupling of Nitroarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691589725184","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Reductive Denitration of Nitroarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857593724462592","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cross-Coupling Reactions of Nitroarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361412893389985792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Pd/NHC-catalyzed cross-coupling reactions of nitroarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1391131406304615040","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Pd-Catalyzed Denitrative Couplings"},{"@language":"ja","@value":"パラジウム触媒を用いた脱ニトロ型カップリング反応の開発"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1139/v97-054"},{"@type":"CROSSREF","@value":"10.1021/acscatal.0c02990_references_DOI_3SRG1bYCQauGVQqncnKf1P73AzF"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.8b00430_references_DOI_3SRG1bYCQauGVQqncnKf1P73AzF"},{"@type":"CROSSREF","@value":"10.1021/acs.accounts.1c00220_references_DOI_3SRG1bYCQauGVQqncnKf1P73AzF"},{"@type":"CROSSREF","@value":"10.1039/c9cc05055h_references_DOI_3SRG1bYCQauGVQqncnKf1P73AzF"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.79.11_references_DOI_3SRG1bYCQauGVQqncnKf1P73AzF"}]}