{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363951794635413120.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1007/s100510050227"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s100510050227.pdf"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/article/10.1007/s100510050227/fulltext.html"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s100510050227"}}],"dc:title":[{"@value":"Extensive stretch of polysiloxane network chains with random- and super-coiled conformations"}],"description":[{"notation":[{"@value":"The stress-elongation                                                                           $$(\\lambda )$$                   relations at large deformations for the polymer network chains with randomcoiled and supercoiled conformations are investigated using the polysiloxane networks with high elongations at break far over 10. Supercoil is the conformation of network chains in deswollen polymer networks which are made by removing solvent from the networks crosslinked in solutions at low polymer concentrations. The validity of the scaling concept of Pincus blob for the mechanical response of a polymer chain is experimentally confirmed for the network composed of randomcoiled chains. The analysis of the stress-λ relations for the deswollen networks comprised of supercoiled chains on the basis of the Pincus blob concept suggests that supercoil is a much more contracted conformation relative to randomcoil."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380848480477660037","@type":"Researcher","foaf:name":[{"@value":"K. Urayama"}]},{"@id":"https://cir.nii.ac.jp/crid/1383951794635413120","@type":"Researcher","foaf:name":[{"@value":"S. Kohjiya"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14346028"}],"prism:publicationName":[{"@value":"The European Physical Journal B"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"1998-04","prism:volume":"2","prism:number":"1","prism:startingPage":"75","prism:endingPage":"78"},"reviewed":"false","dc:rights":["http://www.springer.com/tdm"],"url":[{"@id":"http://link.springer.com/content/pdf/10.1007/s100510050227.pdf"},{"@id":"http://link.springer.com/article/10.1007/s100510050227/fulltext.html"},{"@id":"http://link.springer.com/content/pdf/10.1007/s100510050227"}],"createdAt":"2002-08-25","modifiedAt":"2019-05-29","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285708578305024","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Supercoiling transformation of chemical gels"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183863526144","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Mechanical properties of tetra-PEG gels with supercoiled network structure"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183865758464","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Applicability of a particularly simple model to nonlinear elasticity of slide-ring gels with movable cross-links as revealed by unequal biaxial deformation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641749414528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and properties of soft nanocomposite materials with novel organic/inorganic network structures"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848655292755328","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Soft Nanohybrid Materials Consisting of Polymer–Clay Networks"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205091369856","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Viscoelastic Behavior of Scarcely Crosslinked Poly(dimethyl siloxane) Gels: 2. Effects of Sol Component and Network Strand Length"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205093390848","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Viscoelastic Behavior of Scarcely Crosslinked Poly(dimethyl siloxane) Gel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680067734656","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Studies on Mechanical and Physicochemical Properties of Polymer Gels"},{"@language":"ja","@value":"高分子ゲルの力学的および物理化学的性質に関する研究"},{"@language":"ja-Kana","@value":"コウブンシ ゲル ノ リキガクテキ オヨビ モノ リカガクテキ セイシツ ニ カンスル ケンキュウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390849931316180992","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"日本一 (世界一) 伸びるゴム"}]},{"@id":"https://cir.nii.ac.jp/crid/1390850424378736128","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"網目構造を制御したエラストマーのレオロジー"},{"@language":"ja-Kana","@value":"アミメ コウゾウ オ セイギョ シタ エラストマー ノ レオロジー"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1007/s100510050227"},{"@type":"OPENAIRE","@value":"doi_dedup___::65158fd44a5e2ae652b2119cc25c6c81"},{"@type":"CROSSREF","@value":"10.1039/c5sm01550b_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.1678/rheology.33.257_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.1678/rheology.34.135_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.1063/1.4863917_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.1063/1.4897134_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.4325/seikeikakou.26.10_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.1678/rheology.35.191_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.1038/pj.2010.141_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.1007/12_2014_287_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"},{"@type":"CROSSREF","@value":"10.4325/seikeikakou.18.104_references_DOI_5DKx0b5S1yo46pRTj54sPtoX913"}]}