{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1363951796198364800.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/aenm.201500218"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Faenm.201500218"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/aenm.201500218"}}],"dc:title":[{"@value":"Porphyrin‐Based Bulk Heterojunction Organic Photovoltaics: The Rise of the Colors of Life"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Organic photovoltaics (OPV) represent a thin‐film PV technology that offers attractive prospects for low‐cost and aesthetically appealing (colored, flexible, uniform, semitransparent) solar cells that are printable on large surfaces. In bulk heterojunction (BHJ) OPV devices, organic electron donor and acceptor molecules are intimately mixed within the photoactive layer. Since 2005, the power conversion efficiency of said devices has increased substantially due to insights in the underlying physical processes, device optimization, and chemical engineering of a vast number of novel light‐harvesting organic materials, either small molecules or conjugated polymers. As Nature itself has developed porphyrin chromophores for solar light to energy conversion, it seems reasonable to pursue artificial systems based on the same types of molecules. Porphyrins and their analogues have already been successfully implemented in certain device types, notably in dye‐sensitized solar cells, but they have remained largely unexplored in BHJ organic solar cells. Very recent successes do show, however, the strong (latent) prospects of porphyrinoid semiconductors as light‐harvesting and charge transporting materials in such devices. Here, an overview on the state‐of‐the‐art of porphyrin‐based solution‐processed BHJ OPV is provided and insights are given into the pathways to follow and hurdles to overcome toward further improvements of porphyrinic materials and devices.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1383951796198364801","@type":"Researcher","foaf:name":[{"@value":"Jurgen Kesters"}],"jpcoar:affiliationName":[{"@value":"Design & Synthesis of Organic Semiconductors (DSOS) Institute for Materials Research (IMO‐IMOMEC)Hasselt University  Agoralaan 1 – Building D ,3590 Diepenbeek Belgium"}]},{"@id":"https://cir.nii.ac.jp/crid/1383951796198364802","@type":"Researcher","foaf:name":[{"@value":"Pieter Verstappen"}],"jpcoar:affiliationName":[{"@value":"Design & Synthesis of Organic Semiconductors (DSOS) Institute for Materials Research (IMO‐IMOMEC)Hasselt University  Agoralaan 1 – Building D ,3590 Diepenbeek Belgium"}]},{"@id":"https://cir.nii.ac.jp/crid/1383951796198364805","@type":"Researcher","foaf:name":[{"@value":"Mathias Kelchtermans"}],"jpcoar:affiliationName":[{"@value":"Design & Synthesis of Organic Semiconductors (DSOS) Institute for Materials Research (IMO‐IMOMEC)Hasselt University  Agoralaan 1 – Building D ,3590 Diepenbeek Belgium"}]},{"@id":"https://cir.nii.ac.jp/crid/1383951796198364800","@type":"Researcher","foaf:name":[{"@value":"Laurence Lutsen"}],"jpcoar:affiliationName":[{"@value":"Design & Synthesis of Organic Semiconductors (DSOS) Institute for Materials Research (IMO‐IMOMEC)Hasselt University  Agoralaan 1 – Building D ,3590 Diepenbeek Belgium"},{"@value":"IMOMEC Division, IMEC  Wetenschapspark 1 3590 Diepenbeek Belgium"}]},{"@id":"https://cir.nii.ac.jp/crid/1383951796198364804","@type":"Researcher","foaf:name":[{"@value":"Dirk Vanderzande"}],"jpcoar:affiliationName":[{"@value":"Design & Synthesis of Organic Semiconductors (DSOS) Institute for Materials Research (IMO‐IMOMEC)Hasselt University  Agoralaan 1 – Building D ,3590 Diepenbeek Belgium"},{"@value":"IMOMEC Division, IMEC  Wetenschapspark 1 3590 Diepenbeek Belgium"}]},{"@id":"https://cir.nii.ac.jp/crid/1383951796198364803","@type":"Researcher","foaf:name":[{"@value":"Wouter Maes"}],"jpcoar:affiliationName":[{"@value":"Design & Synthesis of Organic Semiconductors (DSOS) Institute for Materials Research (IMO‐IMOMEC)Hasselt University  Agoralaan 1 – Building D ,3590 Diepenbeek Belgium"},{"@value":"IMOMEC Division, IMEC  Wetenschapspark 1 3590 Diepenbeek Belgium"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16146832"},{"@type":"EISSN","@value":"16146840"}],"prism:publicationName":[{"@value":"Advanced Energy Materials"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-05-05","prism:volume":"5","prism:number":"13","prism:startingPage":"1500218"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Faenm.201500218"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/aenm.201500218"}],"createdAt":"2015-05-05","modifiedAt":"2025-10-07","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050001338252030208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The Impact of Kinetically Restricted Structure on Thermal Conversion of Zinc Tetraphenylporphyrin Thin Films to the Triclinic and Monoclinic Phases"},{"@value":"Impact of Kinetically Restricted Structure on Thermal Conversion of Zinc Tetraphenylporphyrin Thin Films to the Triclinic and Monoclinic Phases"},{"@value":"Impact of kinetically restricted structure on thermal conversion of zinc tetraphenylporphyrin thim films to the triclinic and monoclinic phases"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004229946890496","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Magnesium Tetra(phenylethynyl)porphyrin: Stepwise Synthetic Route, Crystal Structures, and Longer Singlet Excited‐State Lifetime than Zinc Congener"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233133122688","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Probing Charge Carrier Dynamics in Porphyrin-Based Organic Semiconductor Thin Films by Time-Resolved THz Spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360009142901370496","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Dual Emission of a Free‐Base 5‐Oxaporphyrinium Cation from its <i>cis</i>‐ and <i>trans</i>‐NH Tautomers"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013168876116736","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Impact of substituents on the performance of small-molecule semiconductors in organic photovoltaic devices <i>via</i> regulating morphology"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708575315840","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electrochemical fabrication of one-dimensional porphyrinic wires on electrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360290617656452992","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Dynamic behavior of photogenerated charge carriers in diketopyrrolopyrrole-linked tetrabenzoporphyrin-based bulk 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