{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1364233269633192576.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/s0022-328x(00)87057-6"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0022328X00870576?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0022328X00870576?httpAccept=text/plain"}}],"dc:title":[{"@value":"Hydrosilylation of α,β-unsaturated nitriles and esters catalyzed by tris (triphenylphosphine)chlororhodium"}],"description":[{"notation":[{"@value":"Abstract   The hydrosilylation of α,β-unsaturated nitriles and esters such as acrylonitrile, crotononitrile, cinnamonitrile, ethyl and methyl acrylate, ethyl and methyl crotonate and ethyl and methyl methacrylate using tris(triphenylphosphine)chlororhodium as a catalyst is described. The hydrosilylation of α,β-unsaturated nitriles provided α-adduct exclusively in high yield except in the case of trichlorosilane which afforded β-adduct with acrylonitrile. On the other hand, the hydrosilylation of α,β-unsaturated esters gave rather complex results. The selectivity of the reactions was dramatically affected by the substituent of the ester group and that on the β-carbon. Thus, the hydrosilylation of ethyl acrylate with triethylsilane afforded a β-adduct, but, that of ethyl crotonate using the same hydrosilane gave a 1,4-adduct exclusively. Possible mechanisms for these reactions are discussed."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1384233269633192576","@type":"Researcher","foaf:name":[{"@value":"Iwao Ojima"}]},{"@id":"https://cir.nii.ac.jp/crid/1384233269633192577","@type":"Researcher","foaf:name":[{"@value":"Miyoko Kumagai"}]},{"@id":"https://cir.nii.ac.jp/crid/1384233269633192578","@type":"Researcher","foaf:name":[{"@value":"Yoichiro Nagai"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"0022328X"}],"prism:publicationName":[{"@value":"Journal of Organometallic Chemistry"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"1976-05","prism:volume":"111","prism:number":"1","prism:startingPage":"43","prism:endingPage":"60"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0022328X00870576?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0022328X00870576?httpAccept=text/plain"}],"createdAt":"2002-07-25","modifiedAt":"2019-05-01","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233252067328","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Markovnikov-Selective Hydrosilylation of Electron-Deficient Alkenes with Arylsilanes Catalyzed by Mono(phosphine)palladium(0)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183202798720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Direct Use of Esters in the Mukaiyama Aldol Reaction: A Powerful and Convenient Alternative to Aldehydes"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679550907776","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Preparation of Hyperbranched Polymethacrylates by Self-Condensing Group Transfer Polymerization"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680318198272","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"モノ（ホスフィン）パラジウム（0）錯体触媒による高活性Markovnikov型ヒドロメタル化反応：ヘテロ二核ヒドリドパラジウム中間体の合成と反応性"},{"@language":"en","@value":"Markovnikov-Selective Hydrometallation Catalyzed by Mono (phosphine) palladium (0) Complexes: Synthesis and Reactivity of Heterodinuclear Hydridopalladium Intermediate"},{"@language":"ja-Kana","@value":"モノ(ホスフィン)パラジウム(0)サクタイ ショクバイ ニ ヨル コウカッセイ Markovnikovガタ ヒドロメタルカ ハンノウ : ヘテロ ニカク ヒドリドパラジウム チュウカンタイ ノ ゴウセイ ト ハンノウセイ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681266623488","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A Novel Approach to Synthesis of Optically Active Poly(.BETA.-hydroxy carbonyl)s by Aldol Polymerization Based on Mukaiyama Aldol Reaction."},{"@value":"A Novel Approach to the Synthesis of Optically Active Poly(β-hydroxy carbonyl)s by Aldol Polymerization Based on Mukaiyama Aidol Reaction"},{"@language":"ja-Kana","@value":"Novel Approach to the Synthesis of Optically Active Poly ベーターhydroxy carbonyl s by Aldol Polymerization Based on Mukaiyama Aidol Reaction"},{"@value":"A Novel Approach to the Synthesis of Optically Active Poly(β-hydroxy carbonyl)s by Aldol Polymerization Based on Mukaiyama Aldol Reaction"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/s0022-328x(00)87057-6"},{"@type":"OPENAIRE","@value":"doi_dedup___::18e41e46633308de4de43302b142e229"},{"@type":"CROSSREF","@value":"10.1021/om500964g_references_DOI_DLiZYCuhvGLheCCRak2QZCVct3r"},{"@type":"CROSSREF","@value":"10.1021/ol3001443_references_DOI_DLiZYCuhvGLheCCRak2QZCVct3r"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.73.616_references_DOI_DLiZYCuhvGLheCCRak2QZCVct3r"},{"@type":"CROSSREF","@value":"10.1246/cl.1997.1245_references_DOI_DLiZYCuhvGLheCCRak2QZCVct3r"},{"@type":"CROSSREF","@value":"10.1295/polymj.31.1045_references_DOI_DLiZYCuhvGLheCCRak2QZCVct3r"}]}