{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001204144000000.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.20150373"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"027165363"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/027165363"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I027165363"}},{"identifier":{"@type":"URI","@value":"https://dl.ndl.go.jp/pid/11343238"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"11343238"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/digimeta/11343238"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/89/3/354/56278769/bcsj.20150373.pdf"}},{"identifier":{"@type":"NAID","@value":"130005137575"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Structural Design of Coordination Polymers Based on Manganese and Chromium Ions Bridged by Oxalate Ligands"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Coordination polymers based on oxalate-bridged {[Mn<sup>II</sup>Cr<sup>III</sup>(oxalate)<sub>3</sub>]<sup>−</sup>}<sub>∞</sub> complexes of (DAT-2H<sup>2+</sup>)(DCH[18]crown-6)<sub>2</sub>[Mn<sup>II</sup>(CH<sub>3</sub>OH)Cr<sup>III</sup>(oxalate)<sub>3</sub>]<sup>−</sup><sub>2</sub>(CH<sub>3</sub>OH)<sub>3</sub> and (DABCO-H<sup>+</sup>)<sub>2</sub>(DABCO-2H<sup>2+</sup>)[Mn<sup>II</sup>(CH<sub>3</sub>OH)(Cl<sup>−</sup>)Cr<sup>III</sup>(oxalate)<sub>3</sub>]<sup>2−</sup><sub>2</sub>(CH<sub>3</sub>OH), where DAT, DABCO, and DCH[18]crown-6 denote 2,5-diaminotoluene, 1,4-diazabicyclo[2.2.2]octane, and <i>cis</i>-<i>syn</i>-<i>cis</i>-dicyclohexano[18]crown-6, respectively, were synthesized. The crystal structure of the former complex was composed of [Mn<sup>II</sup>(Λ)(CH<sub>3</sub>OH)Cr<sup>III</sup>(Λ)(oxalate)<sub>3</sub>]<sup>−</sup> units, whereas that of the latter crystal was composed of [Mn<sup>II</sup>(Λ)(CH<sub>3</sub>OH)(Cl<sup>−</sup>)Cr<sup>III</sup>(Δ)(oxalate)<sub>3</sub>]<sup>2−</sup> units. The large flexible supramolecular cation in the former provided the two-dimensional structure of [Mn<sup>II</sup>(Λ)(CH<sub>3</sub>OH)Cr<sup>III</sup>(Λ)(oxalate)<sub>3</sub>]<sup>−</sup>, although the two-dimensional honeycomb structure of the {[Mn<sup>II</sup>(Δ)Cr<sup>III</sup>(Λ)(oxalate)<sub>3</sub>]<sup>−</sup>}<sub>∞</sub> and {[Mn<sup>II</sup>(Λ)Cr<sup>III</sup>(Δ)(oxalate)<sub>3</sub>]<sup>−</sup>}<sub>∞</sub> networks are often observed for the oxalate complexes. The round-shaped DABCO molecule in the latter induced a one-dimensional chain structure of [Mn<sup>II</sup>(Λ)(CH<sub>3</sub>OH)Cr<sup>III</sup>(Δ)(oxalate)<sub>3</sub>]<sup>−</sup>. The former crystal showed a magnetic field dependence of magnetization typical for a spin-canting system."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001204144000002","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000317561812"}],"foaf:name":[{"@language":"en","@value":"Yoshitake Masashi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Graduate School of Environmental Science, Hokkaido 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