Formation of Amorphous TiO₂ Film on Ti Using Anodizing in Concentrated H₃PO₄ Aqueous Solution and Its Osteoconductivity
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- Yamamoto Dai
- Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University
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- Iida Takanori
- Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University
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- Kuroda Kensuke
- Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University
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- Ichino Ryoichi
- EcoTopia Science Institute, Nagoya University
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- Okido Masazumi
- Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University
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- Seki Azusa
- Hamri Co., Ltd.
書誌事項
- タイトル別名
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- Formation of Amorphous TiO<sub>2</sub> Film on Ti Using Anodizing in Concentrated H<sub>3</sub>PO<sub>4</sub> Aqueous Solution and Its Osteoconductivity
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Anodizing of Ti specimens were performed in concentrated H3PO4 aqueous solutions with a purpose to incorporate a large amount of phosphate ion into anodized coatings, and their osteoconductivity was evaluated in in vivo test. Ti specimens were anodized in 0.1–11 M H3PO4 aqueous solutions up to 200 V at a rate of 0.1 V s−1. Anodized coatings were evaluated with SEM, TEM, XRD, XPS, and laser microscope. Anodized specimens were implanted in rats’ tibia for 14 d, and then extracted.<BR>When anodized in concentrated (≥2 M) H3PO4 aqueous solutions under spark discharge, crystallized anatase transformed to amorphous anatase by containing a large amount of PO43− in crystal lattice of TiO2. The amorphous anatase coatings had better osteoconductivity than the crystallized anatase coatings. It is not exactly clear what was the intrinsic factor for the high osteoconductivity, but the crystallinity of anatase and/or PO43− in the film is considered to be responsible for the difference in bone-forming ability of TiO2 films.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 53 (3), 508-512, 2012
公益社団法人 日本金属学会
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詳細情報
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- CRID
- 1390001204251625856
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- NII論文ID
- 10030259545
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- NII書誌ID
- AA1151294X
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- COI
- 1:CAS:528:DC%2BC38XmslWktL0%3D
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 023463938
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- KAKEN
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- 抄録ライセンスフラグ
- 使用不可