{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001204257599744.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2116/analsci.17.875"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DC%2BD3MXlsFKqu7c%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"5848990"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/5848990"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I5848990"}},{"identifier":{"@type":"URI","@value":"https://link.springer.com/content/pdf/10.2116/analsci.17.875.pdf"}},{"identifier":{"@type":"URI","@value":"https://link.springer.com/article/10.2116/analsci.17.875/fulltext.html"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/analsci/17/7/17_7_875/_pdf"}},{"identifier":{"@type":"NAID","@value":"10007176881"}}],"dc:title":[{"@language":"en","@value":"Thermal Decomposition of Cerium(III) Acetate Hydrate by a Three-dimensional Thermal Analysis."},{"@language":"ja-Kana","@value":"Thermal Decomposition of Cerium 3 Acetate Hydrate by a Three dimensional Thermal Analysis"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The thermal decomposition of cerium(III) acetate hydrate, Ce(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub>·1.5H<sub>2</sub>O, in helium was successfully studied by the simultaneous measurement of TG-DTA and EGA by mass spectrometry (TG-DTA-MS) as well as that of X-ray diffractometry: DSC (XRD-DSC). TG-DTA-MS was useful to elucidate the complicated successive reactions accompanying the formation of intermediate products. Crystalline cerium(III) anhydrous acetate appeared at 212°C and transformed to another phase at 286°C. Cerium(III) anhydrous acetate decomposed in the temperature range of 300 - 700°C to cerium(IV) oxide <i>via</i> four decomposition steps; the chemical compositions of the three decomposition intermediate products were presumed to be Ce<sub>2</sub>O(CH<sub>3</sub>CO<sub>2</sub>)<sub>4</sub>, Ce<sub>2</sub>O<sub>2</sub>(CH<sub>3</sub>CO<sub>2</sub>)<sub>2</sub> and Ce<sub>2</sub>O<sub>2</sub>CO<sub>3</sub>. The endothermic dehydration and the exothermic crystallization were characterized by simultaneous XRD-DSC. It has been demonstrated that cerium(III) changed to cerium(IV) in the final step. A detailed decomposition mechanism of Ce(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub>·1.5H<sub>2</sub>O is discussed."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001204257599745","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000593567"}],"foaf:name":[{"@language":"en","@value":"ARII Tadashi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Thermal Analysis Division, Rigaku Corporation"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001204257003266","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000005687155"},{"@type":"NRID","@value":"9000401699111"},{"@type":"NRID","@value":"9000254575124"},{"@type":"NRID","@value":"9000258156756"}],"foaf:name":[{"@language":"en","@value":"KISHI Akira"}],"jpcoar:affiliationName":[{"@language":"en","@value":"X-ray Research Laboratory, Rigaku Corporation"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001204257599746","@type":"Researcher","foaf:name":[{"@language":"en","@value":"OGAWA Makoto"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Applied Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001204257599747","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000401702865"},{"@type":"NRID","@value":"9000258154800"},{"@type":"NRID","@value":"9000401672737"},{"@type":"NRID","@value":"9000005915163"},{"@type":"NRID","@value":"9000392810742"},{"@type":"NRID","@value":"9000000593575"},{"@type":"NRID","@value":"9000254880304"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0049957"}],"foaf:name":[{"@language":"en","@value":"SAWADA Yutaka"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Applied Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09106340"},{"@type":"LISSN","@value":"09106340"},{"@type":"EISSN","@value":"13482246"},{"@type":"NDL_BIB_ID","@value":"000000140209"},{"@type":"ISSN","@value":"09106340"},{"@type":"NCID","@value":"AA10500785"}],"prism:publicationName":[{"@language":"en","@value":"Analytical Sciences"},{"@language":"en","@value":"Anal. Sci."}],"dc:publisher":[{"@language":"en","@value":"The Japan Society for Analytical Chemistry"},{"@language":"ja","@value":"社団法人 日本分析化学会"}],"prism:publicationDate":"2001","prism:volume":"17","prism:number":"7","prism:startingPage":"875","prism:endingPage":"880"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/5848990"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I5848990"},{"@id":"https://link.springer.com/content/pdf/10.2116/analsci.17.875.pdf"},{"@id":"https://link.springer.com/article/10.2116/analsci.17.875/fulltext.html"},{"@id":"http://www.jstage.jst.go.jp/article/analsci/17/7/17_7_875/_pdf"}],"availableAt":"2001","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004232056895104","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Temperature-responsive chromatography for the separation of 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