Sensitization Reaction of Oxime Type Photoacid Generator
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- Takahara Shigeru
- Graduate School of Advanced Integration Science, Chiba University
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- Suzuki Shota
- Graduate School of Advanced Integration Science, Chiba University
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- Tsumita Tomoaki
- Graduate School of Advanced Integration Science, Chiba University
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- Allonas Xavier
- Department of Photochemistry, Universite de haute Alsace
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- Fouassier Jeam-Pierre
- Department of Photochemistry, Universite de haute Alsace
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- Yamaoka Tsuguo
- Graduate School of Advanced Integration Science, Chiba University
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説明
Pyrromethene dye/oxime type of photoacid generator (PAG) photoinitiating system based on the singlet electron transfer mechanism was found. The photoacid generation quantum yield (φacid) for the sensitization by the pyrromethene dye was much higher than that for the direct excitation of the PAG, giving a high sensitivity to the photopolymer. The sensitizer/PAG photoinitiating system was extended in UV light area with an anthracene derivative. The electric structure of the PAG and the radical anion were estimated by the ab initio molecular orbital (MO) calculation. The corresponding PAG radical anions give reasonable result for the enhancement of φacid.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 21 (4), 499-504, 2008
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詳細情報 詳細情報について
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- CRID
- 1390001204324077952
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- NII論文ID
- 130004464673
- 40016109013
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- NII書誌ID
- AA11576862
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- COI
- 1:CAS:528:DC%2BD1cXosVKqtr4%3D
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 9548981
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- 本文言語コード
- en
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- データソース種別
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- NDLサーチ
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- 使用不可