{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001204416799232.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi.1974.1724"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1972/1974/9/1974_9_1724/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004155080"}}],"dc:title":[{"@language":"en","@value":"Effects of Physico-chemical Properties of a Detergent Builder on Detergencies"},{"@language":"ja","@value":"洗剤の洗浄力におよぼすビルダー溶液物性の影響"}],"description":[{"type":"abstract","notation":[{"@language":"en","@value":"The relationships between physico-chemical properties of various organic compound solutions (Table 1) and detergencies or physico-chemical properties of the detergents (sodium linear alkylbenzene sulfonate, 20%; sodium tripolyphosphate (STPP) or an organic compound (a builder), 20%; sodium silicate, 5%; sodium carbonate, 3%; sodium sulfate, 42%; moisture, 10%) were studied in order to seek the satisfactory replacements for STPP which is known as the most important and the useful detergent builder. The detergents were examined for solubilization capacity (X1), the critical micelle concentration (X2), pH (X3), dispersion capacity (X, ), calcium ion sequestration capacity (X5), buffer index (X, ) and detergencies (D) at various laundering conditions. Builders were also examined for xs, x4, xs and x6, where the notation, x for a builder is referred to the corresponding X for the detergent. It was found the X1, X1, X3 and X, were not affected by the corresponding x, respectively (Table 2). On the other hand, X5=ax5-1-b (Fig.2) and X8=cx, -Fd (Fig.3), where a, b, c and d are constants. Thus, the relationships, D at 0.1% and 3.5°DH cc x, (Fig.4) and D at 0.1% and 3.5°DH cc \"Ixis (Fig.5), indicate that the physico-chemical properties required for builders as replacements for STPP are calcium ion sequestration capacity and buffer index. It was clarified by the computer cluster analysis that D at various laundering conditions also relates to x5 and and that chelating agents and polyelectrolytes are better replacements for STPP than polymeric non-electrolytes and lower molecular organic salts (Figs.6 and 7)."},{"@language":"ja","@value":"洗剤の重要なビルダーとして用いられているトリ,ポリリン酸ナトリウム(STPP)の代替物質を探索するため,さまざまな種類の有機系化合物の溶液物性と洗剤(直鎖アルキルベンゼンスルホン酸ナトリウム20%;STPPあるいは=有機系化合物(STPP代替ビルダー)20%;ケイ酸ナトリウム5%;Na<sub>2</sub>CO<sub>3</sub>3%;Na<sub>2</sub>SO<sub>4</sub>42%;水10%)の溶液物性あるいは洗浄力の関係を検討した。洗剤につい℃は,可溶化能(Xi),臨界ミセル濃度(瓦),RH(X,),分散能(瓦),カルシウムイオン捕捉龍(瓦),緩衝能(X6)およびさまざまな洗浄条件におげる洗浄力(D)を測定した。またビルダーについても,,Xs,x4,x5およびx6を測定した(xは洗剤のXにそれぞれ対応するビルダ,--の溶液物性)。X1,X2,X3および瓦はそれぞれ対応するxの影響を受けなかった。-方,X5=aXs+bおよびX6=c,/+dなる関係が明らかとなった(a,b,cおよびdは定数)。ゆえに,-定の洗浄条件におけるDOCXs,,Dcc～/魂なる関係は,STPP代替ビルター-に必要な物性がカルシウムイオン捕捉能と緩衝能であることを示唆している,コンピューターによるクラスター分析によって,前に述べた関係がいろいろの洗浄条件でも成立する傾向にあること,STPP代替ビルダーとしては,キレート性化合物と高分子電解質が低分子量の有機カルボン酸塩と非解離性水溶性高分子よりすぐれていることが明らかとなった。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410006850497337857","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256035277"}],"foaf:name":[{"@language":"en","@value":"MURATA Moriyasu"},{"@language":"ja","@value":"村田 守康"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"花王石鹸株式会社家庭品研究所"},{"@language":"en","@value":"Household Goods Research Laboratories, Kao Soap Co., Lid."}]},{"@id":"https://cir.nii.ac.jp/crid/1410006850497337856","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256035278"}],"foaf:name":[{"@language":"en","@value":"ARAI Haruhiko"},{"@language":"ja","@value":"荒井 明彦"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"花王石鹸株式会社家庭品研究所"},{"@language":"en","@value":"Household Goods Research Laboratories, Kao Soap Co., Lid."}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03694577"},{"@type":"EISSN","@value":"21850925"}],"prism:publicationName":[{"@language":"en","@value":"NIPPON KAGAKU KAISHI"},{"@language":"ja","@value":"日本化学会誌（化学と工業化学）"},{"@language":"en","@value":"Nippon Kagaku Kaishi"},{"@language":"ja","@value":"日化"},{"@language":"en","@value":"NIPPON KAGAKU KAISHI"},{"@language":"ja","@value":"日本化学会誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"1974-09-10","prism:volume":"1974","prism:number":"9","prism:startingPage":"1724","prism:endingPage":"1730"},"reviewed":"false","url":[{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1972/1974/9/1974_9_1724/_pdf"}],"availableAt":"1974-09-10","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0037407809"},{"@type":"CROSSREF","@value":"10.1246/nikkashi.1974.1724"},{"@type":"CIA","@value":"130004155080"}]}