{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001204569378560.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1252/jcej.08we289"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"10285386"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/10285386"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I10285386"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/jcej/42/7/42_08we289/_pdf"}},{"identifier":{"@type":"NAID","@value":"10025306657"}}],"dc:title":[{"@language":"en","@value":"Performance of a Bench-Scale Annular-Type Packed-Bed Photocatalytic Reactor for Decomposition of Indigo Carmine Dissolved in Water"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"A bench-scale annular-type packed-bed photocatalytic reactor with TiO<SUB>2</SUB>-coated glass beads as the photocatalyst was designed; the performance of the reactor was evaluated by using it for the photocatalytic decomposition of indigo carmine (IC) dissolved in water. The reactor was operated in a recirculation batch mode, and the dye solution in the reservoir was recirculated through the photocatalyst bed in the annular space of the reactor. The concentration of the dye in the reservoir decreased gradually with an increase in the operation time. The time course of the change in the IC concentration was calculated numerically by assuming first-order kinetics, and the overall rate constant of photocatalytic decomposition was determined by fitting the calculated time course to the experimental value obtained for various treatment times. The overall decomposition rate constants decreased with an increase in the initial concentration of the IC solution. The rate-controlling step in the photocatalytic decomposition was the mass transfer of IC from the bulk of the solution to the catalyst surface when the flow rate was less than 1 dm<SUP>3</SUP>/min; however, when the flow rate exceeded the transition flow rate, the reaction occurring at the catalyst surface was the rate-controlling step."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001204569378560","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000016415379"}],"foaf:name":[{"@language":"en","@value":"Hama Yoshinori"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001204569378562","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000016415382"}],"foaf:name":[{"@language":"en","@value":"Itamochi Masakazu"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326214951424","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90380112"},{"@type":"NRID","@value":"1000090380112"},{"@type":"NRID","@value":"9000409331405"},{"@type":"NRID","@value":"9000398139802"},{"@type":"NRID","@value":"9000258664748"},{"@type":"NRID","@value":"9000016415385"},{"@type":"NRID","@value":"9000413332329"},{"@type":"NRID","@value":"9000258663761"},{"@type":"NRID","@value":"9000256060302"},{"@type":"NRID","@value":"9000002642819"},{"@type":"NRID","@value":"9000409331402"},{"@type":"NRID","@value":"9000254732292"},{"@type":"NRID","@value":"9000414374880"},{"@type":"NRID","@value":"9000258671770"},{"@type":"NRID","@value":"9000404089123"},{"@type":"NRID","@value":"9000315681226"},{"@type":"NRID","@value":"9000002120278"},{"@type":"NRID","@value":"9000006792934"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0119876"}],"foaf:name":[{"@language":"en","@value":"Horikawa Toshihide"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima"}]},{"@id":"https://cir.nii.ac.jp/crid/1420282801201450624","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"80274257"},{"@type":"NRID","@value":"1000080274257"},{"@type":"NRID","@value":"9000381485397"},{"@type":"NRID","@value":"9000409331404"},{"@type":"NRID","@value":"9000345222272"},{"@type":"NRID","@value":"9000398139803"},{"@type":"NRID","@value":"9000283369862"},{"@type":"NRID","@value":"9000347087672"},{"@type":"NRID","@value":"9000240037178"},{"@type":"NRID","@value":"9000258680671"},{"@type":"NRID","@value":"9000006734809"},{"@type":"NRID","@value":"9000021561511"},{"@type":"NRID","@value":"9000409296993"},{"@type":"NRID","@value":"9000396137190"},{"@type":"NRID","@value":"9000000005850"},{"@type":"NRID","@value":"9000390428778"},{"@type":"NRID","@value":"9000345343205"},{"@type":"NRID","@value":"9000016415388"},{"@type":"NRID","@value":"9000410015186"},{"@type":"NRID","@value":"9000283369819"},{"@type":"NRID","@value":"9000008574123"},{"@type":"NRID","@value":"9000404681243"},{"@type":"NRID","@value":"9000345323538"},{"@type":"NRID","@value":"9000315681203"},{"@type":"NRID","@value":"9000243876681"},{"@type":"NRID","@value":"9000411251040"},{"@type":"NRID","@value":"9000255998688"},{"@type":"NRID","@value":"9000256051962"},{"@type":"NRID","@value":"9000315681190"},{"@type":"NRID","@value":"9000315681198"},{"@type":"NRID","@value":"9000363212640"},{"@type":"NRID","@value":"9000404346352"},{"@type":"NRID","@value":"9000262371052"},{"@type":"NRID","@value":"9000311508575"},{"@type":"NRID","@value":"9000399411636"},{"@type":"NRID","@value":"9000405686669"},{"@type":"NRID","@value":"9000380134130"},{"@type":"NRID","@value":"9000409331398"},{"@type":"NRID","@value":"9000409297065"},{"@type":"NRID","@value":"9000409846570"},{"@type":"NRID","@value":"9000258671771"},{"@type":"NRID","@value":"9000257791565"},{"@type":"NRID","@value":"9000256011894"},{"@type":"NRID","@value":"9000283369783"},{"@type":"NRID","@value":"9000315681224"},{"@type":"NRID","@value":"9000315681235"},{"@type":"NRID","@value":"9000243723363"},{"@type":"NRID","@value":"9000402943899"},{"@type":"NRID","@value":"9000410503169"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0184045"}],"foaf:name":[{"@language":"en","@value":"Katoh Masahiro"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001204568720897","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000016415390"}],"foaf:name":[{"@language":"en","@value":"Tomida Tahei"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Advanced Materials, Institute of Technology and Science, The University of Tokushima"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219592"},{"@type":"EISSN","@value":"18811299"},{"@type":"NDL_BIB_ID","@value":"000000128548"},{"@type":"ISSN","@value":"00219592"},{"@type":"LISSN","@value":"00219592"},{"@type":"NCID","@value":"AA00709658"}],"prism:publicationName":[{"@language":"en","@value":"JOURNAL OF CHEMICAL ENGINEERING OF JAPAN"},{"@language":"en","@value":"J. Chem. Eng. Japan /  JCEJ"},{"@language":"en","@value":"jcej"},{"@language":"en","@value":"J. Chem. Eng. Japan"},{"@language":"en","@value":"Journal of Chemical Engineering of Japan"}],"dc:publisher":[{"@language":"en","@value":"The Society of Chemical Engineers, Japan"},{"@language":"ja","@value":"公益社団法人 化学工学会"}],"prism:publicationDate":"2009","prism:volume":"42","prism:number":"7","prism:startingPage":"502","prism:endingPage":"507"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/10285386"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I10285386"},{"@id":"http://www.jstage.jst.go.jp/article/jcej/42/7/42_08we289/_pdf"}],"availableAt":"2009","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Packed-Bed%20Photocatalytic%20Reactor","dc:title":"Packed-Bed Photocatalytic Reactor"},{"@id":"https://cir.nii.ac.jp/all?q=Bench-Scale","dc:title":"Bench-Scale"},{"@id":"https://cir.nii.ac.jp/all?q=Annular-Type","dc:title":"Annular-Type"},{"@id":"https://cir.nii.ac.jp/all?q=TiO%3CSUB%3E2%3C/SUB%3E-Coated%20Glass%20Beads","dc:title":"TiO<SUB>2</SUB>-Coated Glass Beads"},{"@id":"https://cir.nii.ac.jp/all?q=Indigo%20Carmine","dc:title":"Indigo Carmine"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011145917861632","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Scaling-up from first principles of a photocatalytic reactor for air pollution remediation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146166569216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photocatalytic treatment of water containing dinitrophenol and city water over TiO2/SiO2"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620757481216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The mathematical modeling of batch recirculation reactors for kinetics studies"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096574401664","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photocatalytic oxidation of 2,4,6-trichlorophenol in water using a cocurrent downflow contactor reactor (CDCR)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570709502208","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Performance of immobilized photocatalytic reactors in continuous mode"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044271542528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photocatalytic oxidation of multicomponent systems of herbicides: Scale-up of laboratory kinetics rate data to plant scale"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045121478528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Titanium dioxide photocatalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518485245824","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effect of mass transfer and catalyst layer thickness on photocatalytic reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993823553152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Design, modelling and experimentation of a new large-scale photocatalytic reactor for water treatment"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699995307151104","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Scaling-up of slurry reactors for the photocatalytic degradation of 4-chlorophenol"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943622347648","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Preliminary analysis of a tellerette packed-bed photocatalytic reactor"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943698963072","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Heterogeneous water phase catalysis as an environmental application: a review"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944792999424","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Evaluation of two solar pilot scale fixed-bed photocatalytic reactors"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420064313088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A study of photocatalytic degradation of trichloroethylene in vapor phase on TiO2 photocatalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420777233280","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photocatalytic oxidation for indoor air purification: a literature review"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107369112135552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photocatalysis in water environments using artificial and solar light"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843261020544","@type":"Article","relationType":["references","cites"],"jpcoar:relatedTitle":[{"@value":"Environmental Applications of Semiconductor Photocatalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388846121598976","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388846208828544","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetics and mechanism of the heterogeneous catalyzed oxidative degradation of indigo carmine"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318929108480","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Comparison of the efficiency of immobilized and suspended systems in photocatalytic degradation"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320972793344","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Decolourization of textile industry wastewater by the photocatalytic degradation process"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795693642496","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Experimental comparison of three reactor designs for photocatalytic water purification"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269585732992","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photocatalytic Degradation of Dyes in Water: Case Study of Indigo and of Indigo Carmine"}]},{"@id":"https://cir.nii.ac.jp/crid/1570009751816348416","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Performance of Immobilized Photocatalytic Reactors in Continuous Mode"}]},{"@id":"https://cir.nii.ac.jp/crid/1570291226538593536","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Scaling-Up from First Principles of a Photocatalytic Reactor for Air Pollution Remediation"}]},{"@id":"https://cir.nii.ac.jp/crid/1570291226786730624","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Mass Transfer and Catalyst Layer Thickness on Photocatalytic Reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1570291226798641664","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Heterogeneous Water Phase Catalysis as an Environmental Application : a Review"}]},{"@id":"https://cir.nii.ac.jp/crid/1570572700891303040","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Experimental Comparison of Three Reactor Designs for Photocatalytic Water Purification"}]},{"@id":"https://cir.nii.ac.jp/crid/1570854175868014336","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photocatalytic Treatment of Water Containing Dinitrophenol and City Water over TiO_2/SiO_2"}]},{"@id":"https://cir.nii.ac.jp/crid/1570854176734353280","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A Study of Photocatalytic Degradation of Trichloroethylene in Vapor Phase on TiO_2 Photocatalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1570854176764046080","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571417124027765760","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The Mathematical Modeling of Batch Recirculation Reactors for Kinetics Studies"}]},{"@id":"https://cir.nii.ac.jp/crid/1571417125021054336","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Decolourization of Textile Industry Wastewater by the Photocatalytic Degradation Process"}]},{"@id":"https://cir.nii.ac.jp/crid/1571417125821436928","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Scaling-Up of Slurry Reactors for the Photocatalytic Degradation of 4-Chlorophenol"}]},{"@id":"https://cir.nii.ac.jp/crid/1571980074970223744","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photocatalytic Degradation of Dyes in Water : Case Study of Indigo and of Indigo Carmine"}]},{"@id":"https://cir.nii.ac.jp/crid/1571980076641969536","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Design Modelling and Experimentation of a New Large-Scale Photocatalytic Reactor for Water Treatment"}]},{"@id":"https://cir.nii.ac.jp/crid/1573105974548738688","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Titanium dioxide photocatalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1573105974881315456","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Comparison of the Efficiency of Immobilized and Suspended Systems in Photocatalytic Degradation"}]},{"@id":"https://cir.nii.ac.jp/crid/1573387451282222336","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photocatalytic Oxidation of Multicomponent Systems of Herbicides : Scale-Up of Laboratory Kinetics Rate Data to Plant Scale"}]},{"@id":"https://cir.nii.ac.jp/crid/1573387451531644672","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Evaluation of Two Solar Pilot Scale Fixed-Bed Photocatalytic Reactors"}]},{"@id":"https://cir.nii.ac.jp/crid/1573387451541908096","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Kinetics and Mechanism of the Heterogeneous Catalyzed Oxidative Degradation of Indigo Carmine"}]},{"@id":"https://cir.nii.ac.jp/crid/1573668925635118848","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photocatalytic Oxidation of 2,4,6-Trichlorophenol in Water Using a Cocurrent Downflow Contractor Reactor (CDCR)"}]},{"@id":"https://cir.nii.ac.jp/crid/1573668925635121024","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Preliminary Analysis of a Tellerette Packed-Bed Photocatalytic Reactor"}]},{"@id":"https://cir.nii.ac.jp/crid/1574231876464809984","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Photocatalysis in Water Environments Using Artificial and Solar Light"}]},{"@id":"https://cir.nii.ac.jp/crid/1574231876470902016","@type":"Article","relationType":["cites"]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0033398205"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I10285386"},{"@type":"CROSSREF","@value":"10.1252/jcej.08we289"},{"@type":"CIA","@value":"10025306657"},{"@type":"OPENAIRE","@value":"doi_dedup___::37ce223161afdebffffbb46724fa03cc"}]}