Dynamic Helicity Control of a Single-helical Oligooxime Complex and Acid–Base-triggered Repeated Helicity Inversion Mediated by Amino Acids
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- Sairenji Shiho
- Faculty of Pure and Applied Sciences, University of Tsukuba
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- Akine Shigehisa
- Graduate School of Natural Science and Technology, Kanazawa University
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- Nabeshima Tatsuya
- Faculty of Pure and Applied Sciences, University of Tsukuba Tsukuba Research Center for Interdisciplinary Materials Science, University of Tsukuba
Abstract
Helicity of a single-helical oligooxime complex [(L)Zn3La]3+ was controlled efficiently by coordination with various kinds of α-amino acids. The helicity depends on the residues of the amino acids. A mixture of [(L)Zn3La]3+ and cysteic acid underwent helicity inversion repeatedly by the alternate addition of an acid and a base.
Journal
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- Chemistry Letters
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Chemistry Letters 43 (7), 1107-1109, 2014
The Chemical Society of Japan
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Details
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- CRID
- 1390001204588473472
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- NII Article ID
- 130004868263
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- COI
- 1:CAS:528:DC%2BC2cXht1enu7jL
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- ISSN
- 13480715
- 03667022
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed