{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001205129356800.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi1898.61.384"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1898/61/3/61_3_384/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004273986"}}],"dc:title":[{"@language":"en","@value":"Mechanism of Emulsion Polymerization of Vinyl Acetate"},{"@value":"酢酸ビニルの乳化重合機構"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@value":"ポリエチレンオキシドドデシルエーテル(P=45)を加えて,酢酸ビニル,カプロン酸ビニル,スチレンの塊状および乳化重合を行った。酢酸ビニルとラジカル反応性がほぼ等しく,水溶性が極度に小さいカプロン酸ビニルはスチレンと同じく,Smith-Ewart式にしたがい,スチレンの乳化重合でもモノマーの溶解度を増してメタノール・水系で乳化重合するとSmith-Ewart式にしたがわなくなることを見出した。このことは酢酸ビニルの乳化重合がスチレンのそれと相違するのは,ラジカル反応性の差よりむしろ水溶性の差の方が重要であることを示している。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410290696923923585","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256408054"}],"foaf:name":[{"@language":"en","@value":"Okamura Seizo"},{"@language":"ja","@value":"岡村 誠三"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"京都大学工学部繊維化学教室"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696923923584","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256408055"}],"foaf:name":[{"@language":"en","@value":"Motoyama Takuhiko"},{"@language":"ja","@value":"本山 卓彦"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"京都大学工学部繊維化学教室"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00232734"},{"@type":"EISSN","@value":"21850860"}],"prism:publicationName":[{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"},{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"}],"prism:publicationDate":"1958","prism:volume":"61","prism:number":"3","prism:startingPage":"384","prism:endingPage":"387"},"reviewed":"false","url":[{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1898/61/3/61_3_384/_pdf"}],"availableAt":"1958","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Medicine","dc:title":"General Medicine"}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0037976671"},{"@type":"CROSSREF","@value":"10.1246/nikkashi1898.61.384"},{"@type":"CIA","@value":"130004273986"}]}