{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001205201352832.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2116/analscix.24.x283"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/analscix/24/0/24_0_x283/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004442938"}}],"dc:title":[{"@language":"en","@value":"Synthesis and Crystal Structure of a Mononuclear Copper(II) Complex of N,N'-Bis-2,3,4-trihydroxybenzylidene-1,2-phenylendiamine"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The mononuclear complex [Cu<sup>II</sup>(H<sub>4</sub>bzphen)]·CH<sub>3</sub>OH, [H<sub>6</sub>bzphen = <i>N</i>,<i>N</i>′-bis-2,3,4-trihydroxybenzylidene-1,2-phenylendiamine] was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic system, space group <i>P</i>2<sub>1</sub>/<i>n</i> and <i>Z</i> = 4 with cell parameters <i>a</i> = 14.601(14)Å, <i>b</i> = 8.574(3)Å, <i>c</i> = 15.953(9)Å, <i>β</i> = 109.49(8)°, <i>V</i> = 1882.8(21)Å<sup>3</sup>. H<sub>6</sub>bzphen acts as a tetradentate planar ligand, and the copper(II) has tetragonal planar geometry. The crystal packing is stabilized by inter-molecular <i>π</i>-<i>π</i> stacking interactions and hydrogen bonds."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420845751144798592","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90221952"},{"@type":"NRID","@value":"1000090221952"},{"@type":"NRID","@value":"9000257710430"},{"@type":"NRID","@value":"9000257705229"},{"@type":"NRID","@value":"9000255699615"},{"@type":"NRID","@value":"9000391871868"},{"@type":"NRID","@value":"9000257799721"},{"@type":"NRID","@value":"9000283626259"},{"@type":"NRID","@value":"9000256006874"},{"@type":"NRID","@value":"9000255698644"},{"@type":"NRID","@value":"9000283626415"},{"@type":"NRID","@value":"9000396148033"},{"@type":"NRID","@value":"9000021878821"},{"@type":"NRID","@value":"9000368417914"},{"@type":"NRID","@value":"9000414559935"},{"@type":"NRID","@value":"9000257706253"},{"@type":"NRID","@value":"9000257701777"},{"@type":"NRID","@value":"9000256016466"},{"@type":"NRID","@value":"9000255698223"},{"@type":"NRID","@value":"9000256011187"},{"@type":"NRID","@value":"9000340948639"},{"@type":"NRID","@value":"9000256018360"},{"@type":"NRID","@value":"9000257799456"},{"@type":"NRID","@value":"9000314068036"},{"@type":"NRID","@value":"9000007291603"},{"@type":"NRID","@value":"9000414870359"},{"@type":"NRID","@value":"9000414870354"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/koi-ken"}],"foaf:name":[{"@language":"en","@value":"KOIKAWA Masayuki"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658928002304","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"30633664"},{"@type":"NRID","@value":"1000030633664"},{"@type":"NRID","@value":"9000257799722"},{"@type":"NRID","@value":"9000363868829"}],"foaf:name":[{"@language":"en","@value":"MATSUDA Yayoi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658377768960","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40039269"},{"@type":"NRID","@value":"1000040039269"},{"@type":"NRID","@value":"9000020288964"},{"@type":"NRID","@value":"9000257799723"},{"@type":"NRID","@value":"9000283626260"},{"@type":"NRID","@value":"9000283626419"},{"@type":"NRID","@value":"9000257799457"}],"foaf:name":[{"@language":"en","@value":"TOKII Tadashi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University"}]}],"publication":{"publicationIdentifier":[{"@type":"EISSN","@value":"13482238"}],"prism:publicationName":[{"@language":"en","@value":"Analytical Sciences: X-ray Structure Analysis Online"},{"@language":"en","@value":"Anal. Sci. X"}],"dc:publisher":[{"@language":"en","@value":"The Japan Society for Analytical Chemistry"},{"@language":"ja","@value":"社団法人 日本分析化学会"}],"prism:publicationDate":"2008","prism:volume":"24","prism:startingPage":"X283","prism:endingPage":"X284"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://www.jstage.jst.go.jp/article/analscix/24/0/24_0_x283/_pdf"}],"availableAt":"2008","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Materials%20Chemistry","dc:title":"Materials Chemistry"},{"@id":"https://cir.nii.ac.jp/all?q=Analytical%20Chemistry","dc:title":"Analytical Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011144986031360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Tripodal Trimanganese(III) Complexes of New Unsymmetrical Pentadentate Ligands Derived from 2‐(Salicylideneamino)phenol: Syntheses, Crystal Structures and Properties"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570824886144","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Self-Assembly of a Copper(II)-Based Metallosupramolecular Hexagon"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699995949779456","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Molecular association, chelate conformation and reactivity correlations in substituted o-phenylenebis(salicylidenato)copper(II) complexes: UV-visible, EPR and X-ray structural investigations"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699996146459520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ruthenium(II) Polypyridyl Complexes:  Potential Precursors, Metalloligands, and Topo II Inhibitors"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943624513536","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"[<i>o</i>-Phenylenebis(salicylideneaminato)]copper(II)"}]},{"@id":"https://cir.nii.ac.jp/crid/1882553967386434432","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 691346: Experimental Crystal Structure Determination"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0032321104"},{"@type":"CROSSREF","@value":"10.2116/analscix.24.x283"},{"@type":"CIA","@value":"130004442938"},{"@type":"OPENAIRE","@value":"doi_dedup___::3cbd1878ab4fc1a8f3cbfe8f7784e709"}]}