{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001205554227968.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.11494/kisoyuki.55.0.55.0"}},{"identifier":{"@type":"NAID","@value":"130004646390"}}],"dc:title":[{"@language":"en","@value":"Photochemical Mono-silylation of C60 with Silacyclopropane"},{"@language":"ja","@value":"シラシクロプロパンによるC60の光ケイ素化"}],"description":[{"type":"abstract","notation":[{"@language":"en","@value":"In this presentation, we report the photo-chemical reaction of C<SUB>60</SUB> with some silacyclopropanes. C<SUB>60</SUB> reacts with silacyclopropane upon photo-irradiation. In some case, the different major products were observed by the MALDI-TOF MASS spectra measurement. Under the condition of over 400 nm light irradiation, silacyclopropane adducts were obtained as major product. On the other hand, silylene adducts were observed as major product when the shorter wavelength light ( < 400 nm ) was applied for the reaction."},{"@language":"ja","@value":"C<SUB>60</SUB>の光励起により高い量子収率（Φ= 0.96）で生成するC<SUB>60</SUB>の励起三重項状態は、強い電子受容能と比較的長い寿命（τ = 40μs）を有することが知られ、これまでさまざまな電子供与性物質との間で電子移動を伴う反応の研究が行われてきた。 今回我々は、環状ケイ素化合物の一種であるシラシクロプロパン類とC<SUB>60</SUB>の光反応を行い、新規なC<SUB>60</SUB>_-_有機ケイ素付加体の合成およびその単離に成功した。　得られたC<SUB>60</SUB>付加体には、付加構造上の立体反転に伴う動きが存在し、<SUP>1</SUP>H-NMRの温度可変測定によりその活性化エネルギーを算出することにも成功している。 これら付加体の生成メカニズムについて考察したので報告する。（293文字）"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410290696693515401","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601870"}],"foaf:name":[{"@language":"en","@value":"Nakahodo Tsukasa"},{"@language":"ja","@value":"仲程 司"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Univ. of Tsukuba"},{"@language":"ja","@value":"筑波大TARAセ"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515397","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601874"}],"foaf:name":[{"@language":"en","@value":"Nagatsuka Junko"},{"@language":"ja","@value":"永塚 順子"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Univ. of Tsukuba"},{"@language":"ja","@value":"筑波大TARAセ"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515392","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601875"}],"foaf:name":[{"@language":"en","@value":"Sugitani Sachie"},{"@language":"ja","@value":"杉谷 幸愛"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Univ. of Tsukuba"},{"@language":"ja","@value":"筑波大TARAセ"}]},{"@id":"https://cir.nii.ac.jp/crid/1420282801182532736","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"10233678"},{"@type":"NRID","@value":"1000010233678"},{"@type":"NRID","@value":"9000000825101"},{"@type":"NRID","@value":"9000256009247"},{"@type":"NRID","@value":"9000257713894"},{"@type":"NRID","@value":"9000000262884"},{"@type":"NRID","@value":"9000000638902"},{"@type":"NRID","@value":"9000256019075"},{"@type":"NRID","@value":"9000401678435"},{"@type":"NRID","@value":"9000258600173"},{"@type":"NRID","@value":"9000258601847"},{"@type":"NRID","@value":"9000256019540"},{"@type":"NRID","@value":"9000258598581"},{"@type":"NRID","@value":"9000255709113"},{"@type":"NRID","@value":"9000283171345"},{"@type":"NRID","@value":"9000257715950"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0008995"}],"foaf:name":[{"@language":"en","@value":"Kako Masahiro"},{"@language":"ja","@value":"加固 昌寛"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Univ. of Electro-Communications"},{"@language":"ja","@value":"電通大 量子・物質工"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515402","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601877"}],"foaf:name":[{"@language":"en","@value":"Wakahara Takatsugu"},{"@language":"ja","@value":"若原 孝次"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"筑波大TARAセ"},{"@language":"en","@value":"Univ. of Tsukuba"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515398","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601878"}],"foaf:name":[{"@language":"en","@value":"Maeda Yutaka"},{"@language":"ja","@value":"前田 優"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Tokyo Gakugei univ."},{"@language":"ja","@value":"東学芸大教"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515400","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601879"}],"foaf:name":[{"@language":"en","@value":"Tsuchiya Takahiro"},{"@language":"ja","@value":"土屋 敬広"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"筑波大TARAセ"},{"@language":"en","@value":"Univ. of Tsukuba"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515394","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601880"}],"foaf:name":[{"@language":"en","@value":"Akasaka Takeshi"},{"@language":"ja","@value":"赤阪 健"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Univ. of Tsukuba"},{"@language":"ja","@value":"筑波大TARAセ"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515403","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601881"}],"foaf:name":[{"@language":"en","@value":"Sasaki Yoshiko"},{"@language":"ja","@value":"佐々木 佳子"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Tohoku Univ."},{"@language":"ja","@value":"東北大学　多元研"}]},{"@id":"https://cir.nii.ac.jp/crid/1410290696693515395","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258601871"}],"foaf:name":[{"@language":"en","@value":"Itoh Osamu"},{"@language":"ja","@value":"伊藤 攻"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Tohoku Univ."},{"@language":"ja","@value":"東北大学　多元研"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658374350721","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"30285093"},{"@type":"NRID","@value":"1000030285093"},{"@type":"NRID","@value":"9000006672159"},{"@type":"NRID","@value":"9000016498739"},{"@type":"NRID","@value":"9000258594262"},{"@type":"NRID","@value":"9000363880003"}],"foaf:name":[{"@language":"en","@value":"Kobayashi Kaoru"},{"@language":"ja","@value":"小林 郁"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"分子研"},{"@language":"en","@value":"IMS"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658312732289","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"30134901"},{"@type":"NRID","@value":"1000030134901"},{"@type":"NRID","@value":"9000258600212"},{"@type":"NRID","@value":"9000017113444"},{"@type":"NRID","@value":"9000001819357"},{"@type":"NRID","@value":"9000006566488"},{"@type":"NRID","@value":"9000256045188"},{"@type":"NRID","@value":"9000256030328"},{"@type":"NRID","@value":"9000258600183"},{"@type":"NRID","@value":"9000022456607"},{"@type":"NRID","@value":"9000258596370"},{"@type":"NRID","@value":"9000258597318"},{"@type":"NRID","@value":"9000257715088"},{"@type":"NRID","@value":"9000009217269"},{"@type":"NRID","@value":"9000000638850"},{"@type":"NRID","@value":"9000258602172"},{"@type":"NRID","@value":"9000258597431"},{"@type":"NRID","@value":"9000258601885"},{"@type":"NRID","@value":"9000006582903"},{"@type":"NRID","@value":"9000283741615"},{"@type":"NRID","@value":"9000258597729"},{"@type":"NRID","@value":"9000283122854"},{"@type":"NRID","@value":"9000257715317"},{"@type":"NRID","@value":"9000258602255"},{"@type":"NRID","@value":"9000258598268"},{"@type":"NRID","@value":"9000258594263"},{"@type":"NRID","@value":"9000258598655"},{"@type":"NRID","@value":"9000258594355"},{"@type":"NRID","@value":"9000258601063"},{"@type":"NRID","@value":"9000258601837"},{"@type":"NRID","@value":"9000257725965"},{"@type":"NRID","@value":"9000000659658"},{"@type":"NRID","@value":"9000283741269"},{"@type":"NRID","@value":"9000283740445"},{"@type":"NRID","@value":"9000258601407"},{"@type":"NRID","@value":"9000283123046"},{"@type":"NRID","@value":"9000283741111"},{"@type":"NRID","@value":"9000256048029"},{"@type":"NRID","@value":"9000256028219"},{"@type":"NRID","@value":"9000258599603"},{"@type":"NRID","@value":"9000283124474"},{"@type":"NRID","@value":"9000322100732"},{"@type":"NRID","@value":"9000255698867"},{"@type":"NRID","@value":"9000258601857"},{"@type":"NRID","@value":"9000283122857"},{"@type":"NRID","@value":"9000283122096"},{"@type":"NRID","@value":"9000283122081"},{"@type":"NRID","@value":"9000257715618"},{"@type":"NRID","@value":"9000256027266"},{"@type":"NRID","@value":"9000258600214"},{"@type":"NRID","@value":"9000258599454"},{"@type":"NRID","@value":"9000257715938"},{"@type":"NRID","@value":"9000257732542"},{"@type":"NRID","@value":"9000258594338"},{"@type":"NRID","@value":"9000258594359"},{"@type":"NRID","@value":"9000258599287"},{"@type":"NRID","@value":"9000258420568"},{"@type":"NRID","@value":"9000258594357"},{"@type":"NRID","@value":"9000258600412"},{"@type":"NRID","@value":"9000258599308"},{"@type":"NRID","@value":"9000258601873"},{"@type":"NRID","@value":"9000256021610"},{"@type":"NRID","@value":"9000258598590"},{"@type":"NRID","@value":"9000258600200"},{"@type":"NRID","@value":"9000258595445"},{"@type":"NRID","@value":"9000258594791"},{"@type":"NRID","@value":"9000258597450"},{"@type":"NRID","@value":"9000258599293"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0009062"}],"foaf:name":[{"@language":"en","@value":"Nagase Shigeru"},{"@language":"ja","@value":"永瀬 茂"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"分子研"},{"@language":"en","@value":"IMS"}]}],"publication":{"prism:publicationName":[{"@language":"en","@value":"Abstracts of Symposium on Physical Organic Chemistry"},{"@language":"ja","@value":"基礎有機化学討論会要旨集（基礎有機化学連合討論会予稿集）"}],"dc:publisher":[{"@language":"en","@value":"The Society of Physical Organic Chemistry, Japan"},{"@language":"ja","@value":"基礎有機化学会（基礎有機化学連合討論会）"}],"prism:publicationDate":"2005","prism:volume":"55","prism:number":"0","prism:startingPage":"55","prism:endingPage":"55"},"availableAt":"2005","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Fullerene","dc:title":"Fullerene"},{"@id":"https://cir.nii.ac.jp/all?q=Silacycropropane","dc:title":"Silacycropropane"},{"@id":"https://cir.nii.ac.jp/all?q=Photochemical-reaction","dc:title":"Photochemical-reaction"},{"@id":"https://cir.nii.ac.jp/all?q=%E3%83%95%E3%83%A9%E3%83%BC%E3%83%AC%E3%83%B3","dc:title":"フラーレン"},{"@id":"https://cir.nii.ac.jp/all?q=%E3%82%B7%E3%83%A9%E3%82%B7%E3%82%AF%E3%83%AD%E3%83%97%E3%83%AD%E3%83%91%E3%83%B3","dc:title":"シラシクロプロパン"},{"@id":"https://cir.nii.ac.jp/all?q=%E5%85%89%E5%8F%8D%E5%BF%9C","dc:title":"光反応"}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:1003239226"},{"@type":"CIA","@value":"130004646390"}]}