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It is found that the successful reversible gain or loss of electrons by ionization is useful for controlling the stability and reactivity of M@C82 towards both nucleophiles and electrophiles."},{"@language":"ja","@value":"フラーレン内に金属原子が内包された金属内包フラーレンは、内部金属からフラーレンケージへ電子移動した興味深い電子構造を有している。今回、金属内包フラーレンの化学的還元と酸化を行い、対応するイオン種の定量的合成に成功した。常磁性金属内包フラーレンの化学的還元は、安定性の向上、分離、構造解析に有効であることを見出した。更に、合成したイオン種の求電子試薬との化学反応について検討致したところ、金属内包フラーレンの化学反応性を酸化還元により制御し得ることも見出した。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420564276159430656","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"10345324"},{"@type":"NRID","@value":"1000010345324"},{"@type":"NRID","@value":"9000401789070"},{"@type":"NRID","@value":"9000255702186"},{"@type":"NRID","@value":"9000258601891"},{"@type":"NRID","@value":"9000333213838"},{"@type":"NRID","@value":"9000002021734"},{"@type":"NRID","@value":"9000405705190"},{"@type":"NRID","@value":"9000006028981"},{"@type":"NRID","@value":"9000000659688"},{"@type":"NRID","@value":"9000283741079"},{"@type":"NRID","@value":"9000257723189"},{"@type":"NRID","@value":"9000321638145"},{"@type":"NRID","@value":"9000258600175"},{"@type":"NRID","@value":"9000258601846"},{"@type":"NRID","@value":"9000359904375"},{"@type":"NRID","@value":"9000257847179"},{"@type":"NRID","@value":"9000258598580"},{"@type":"NRID","@value":"9000010304781"},{"@type":"NRID","@value":"9000258600236"},{"@type":"NRID","@value":"9000413491013"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0090009"}],"foaf:name":[{"@language":"en","@value":"Maeda 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Japan"},{"@language":"ja","@value":"基礎有機化学会（基礎有機化学連合討論会）"}],"prism:publicationDate":"2005","prism:volume":"55","prism:number":"0","prism:startingPage":"57","prism:endingPage":"57"},"availableAt":"2005","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Endohedral%20metallofullerene","dc:title":"Endohedral metallofullerene"},{"@id":"https://cir.nii.ac.jp/all?q=Ionization","dc:title":"Ionization"},{"@id":"https://cir.nii.ac.jp/all?q=Chemical%20reactivity","dc:title":"Chemical 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