Photoelectrochemical Growth and Reactions of Oriented Silver Nanocrystals(<Special Issue>Light-induced Crystal Growth)

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  • 銀ナノ結晶の光電気化学的な配向成長および反応(<特集>光で成長する結晶)
  • 銀ナノ結晶の光電気化学的な配向成長および反応
  • ギン ナノ ケッショウ ノ ヒカリ デンキ カガクテキ ナ ハイコウ セイチョウ オヨビ ハンノウ

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Anisotropic Ag nanoparticles grow epitaxially on TiO_2 single crystals by photoelectrochemical reduction of Ag^+. Under different conditions and on different substrates, biaxially and uniaxially orientated crystalline nanorods or pyramids, uniaxially oriented triangular nanoplates, or trapezoidal pyramids are grown preferentially, without need for a masking layer. The oriented anisotropic Ag nanoparticles would be applied to plasmon-based photofunctional materials and devices that are responsive to polarized visible and/or near infrared light, including near infrared photochromic materials.

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