Determination of Raman Phonon Strain Shift Coefficient of Strained Silicon and Strained SiGe

  • Wong L. H.
    School of Materials Science and Engineering, Nanyang Technological University Chartered Semiconductor Manufacturing Ltd.
  • Wong C. C.
    School of Materials Science and Engineering, Nanyang Technological University
  • Liu J. P.
    Chartered Semiconductor Manufacturing Ltd.
  • Zang H.
    Physics Department, Blk. S12, Faculty of Science, National University of Singapore
  • Chan L.
    Chartered Semiconductor Manufacturing Ltd.
  • Shen Z. X.
    Physics Department, Blk. S12, Faculty of Science, National University of Singapore
  • Hsia L. C.
    Chartered Semiconductor Manufacturing Ltd.
  • Ni Z. H.
    Physics Department, Blk. S12, Faculty of Science, National University of Singapore
  • Sohn D. K.
    Chartered Semiconductor Manufacturing Ltd.

Bibliographic Information

Published
2005
DOI
  • 10.1143/jjap.44.7922
Publisher
The Japan Society of Applied Physics

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Description

The use of Raman spectroscopy to characterize strain in strained Si and strained SiGe has been widely accepted. To use Raman spectroscopy for quantitative biaxial strain measurements, the strain shift coefficient for Si–Si vibration from strained Si (bSi–SiStSi) and strained SiGe (bSi–SiStSiGe) must be known. So far, bSi–SiStSiGe is commonly used to calculate strain in strained Si, which may result in inaccurate strain values. In this work, we report the first direct measurement of bSi–SiStSi by correlating high-resolution X-ray diffraction and Raman spectroscopy, which yields a measured value of −784±4 cm−1. We also show that the strain shift coefficient of SiGe, bSi–SiStSiGe, is a strong function of Ge concentration (x), and follows the empirical relation: b=−773.9−897.7x for x<0.35.

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