{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390001206453080064.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2355/isijinternational.40.121"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DC%2BD3cXit1yis7s%3D"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/isijinternational1989/40/2/40_2_121/_pdf"}},{"identifier":{"@type":"NAID","@value":"10004550698"}}],"dc:title":[{"@language":"en","@value":"Effect of Slag Composition on the Kinetics of Formation of Al2O3 MgO Inclusions in Aluminum Killed Ferritic Stainless Steel."}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Kinetics of both slag/metal reactions and metal/inclusion reactions were investigated experimentally using 20 kg vacuum induction furnace in order to clarify the mechanism of the formation of MgAl<sub>2</sub>O<sub>4</sub> spinel inclusions in aluminum killed ferritic stainless steel (SUS430).<br>The results obtained are summarized as follows :<br>1) By reducing CaO/SiO<sub>2</sub> and CaO/Al<sub>2</sub>O<sub>3</sub> ratio of top slag, MgO contents in Al<sub>2</sub>O<sub>3</sub> based inclusions decreased.<br>2) The two film theory was employed to analyze the rate determining step of slag/metal reaction (reduction of MgO in top slag). By this model, it was found that the rate determining step of the reaction was the mass transfer of Mg through the film in molten steel. The increase rate of Mg in molten steel is determined by the activities of soluble oxygen and MgO at the slag/metal interface, and hence by slag composition.<br>3) The unreacted core model was employed to analyze the rate determining step of metal/inclusions reaction.<br>The analysis showed that the rate determining step of the reaction in the case of 20 kg vacuum induction furnace was the diffusion of Mg in molten steel."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001206453080065","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000244855"}],"foaf:name":[{"@language":"en","@value":"Okuyama Goro"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Technical Research Labs., Kawasaki Steel Corp."}]},{"@id":"https://cir.nii.ac.jp/crid/1410001206453080067","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000244857"}],"foaf:name":[{"@language":"en","@value":"Yamaguchi Koji"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Technical Research Labs., Kawasaki Steel Corp."}]},{"@id":"https://cir.nii.ac.jp/crid/1410001206453080064","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000244859"}],"foaf:name":[{"@language":"en","@value":"Takeuchi Syuji"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Technical Research Labs., Kawasaki Steel Corp."}]},{"@id":"https://cir.nii.ac.jp/crid/1410001206453080066","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000244861"}],"foaf:name":[{"@language":"en","@value":"Sorimachi Ken-ichi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Technical Research Labs., Kawasaki Steel Corp."}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09151559"},{"@type":"EISSN","@value":"13475460"},{"@type":"PISSN","@value":"https://id.crossref.org/issn/09151559"},{"@type":"NCID","@value":"AA10680712"}],"prism:publicationName":[{"@language":"en","@value":"ISIJ International"},{"@language":"ja","@value":"ＩＳＩＪ　Ｉｎｔｅｒｎａｔｉｏｎａｌ"},{"@language":"en","@value":"ISIJ Int."},{"@language":"en","@value":"ISIJ International"},{"@language":"ja","@value":"ＩＳＩＪ　Ｉｎｔｅｒｎａｔｉｏｎａｌ"}],"dc:publisher":[{"@language":"en","@value":"The Iron and Steel Institute of Japan"},{"@language":"ja","@value":"一般社団法人 日本鉄鋼協会"}],"prism:publicationDate":"2000","prism:volume":"40","prism:number":"2","prism:startingPage":"121","prism:endingPage":"128"},"reviewed":"false","url":[{"@id":"http://www.jstage.jst.go.jp/article/isijinternational1989/40/2/40_2_121/_pdf"}],"availableAt":"2000","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=secondary%20steelmaking","dc:title":"secondary steelmaking"},{"@id":"https://cir.nii.ac.jp/all?q=stainless%20steel","dc:title":"stainless steel"},{"@id":"https://cir.nii.ac.jp/all?q=slag","dc:title":"slag"},{"@id":"https://cir.nii.ac.jp/all?q=inclusion","dc:title":"inclusion"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050564288507318400","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Dissolution Behavior of Mg from Magnesia-Chromite Refractory into Al-killed Molten Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306905631810816","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Three-Dimensional Imaging of Non-metallic Inclusions in Steel Using Ionoluminescence"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205126170880","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"凝固過程におけるマグネシウム蒸気添加した炭素鋼の不均質核生成"},{"@language":"en","@value":"Generation of Heterogeneous Nucleus in Carbon Steel during Solidification by            Magnesium Vapor Injected"},{"@language":"ja-Kana","@value":"ギョウコ カテイ ニ オケル マグネシウム ジョウキ テンカ シタ タンソコウ ノ フキンシツカク セイセイ"},{"@value":"Generation of Heterogeneous Nucleus in Carbon Steel during Solidification by Magnesium Vapor Injection"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206486513152","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formation and Evolution of Non-metallic Inclusions in Medium Mn Steel during Secondary Refining Process"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206487115008","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Dissolution Behavior of Mg from MgO–C Refractory in Al-killed Molten Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206487437952","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Technology to Control Mg Content in Molten Nickel Alloy of NW2201"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206489185536","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Investigation of Compositional Change of Inclusions in Martensitic Stainless Steel during Heat Treatment by Newly Developed Analysis Method"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206489434368","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Slag Composition on MgO·Al<sub>2</sub>O<sub>3</sub> Spinel-Type Inclusions in Molten Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001288100760448","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formation and Evolution of Oxide Inclusions in Titanium-Stabilized 18Cr Stainless Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390009095529862528","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Control of Heterogeneous Nucleation in Carbon Steel by Magnesium Vapor Injection during Continuous Casting"},{"@language":"ja","@value":"連続鋳造過程における溶鋼中へのマグネシウム蒸気添加による不均質核生成の制御"},{"@language":"ja-Kana","@value":"レンゾク チュウゾウ カテイ ニ オケル ヨウコウ チュウ エ ノ マグネシウム ジョウキ テンカ ニ ヨル フキンシツカク セイセイ ノ セイギョ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680102834816","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Compositions of Non-metallic Inclusions on CC Nozzle Clogging of a Fe-Cr-Ni-Mo System Stainless Steel"},{"@language":"ja","@value":"Fe-Cr-Ni-Mo系ステンレス鋼のCC浸漬ノズル閉塞に及ぼす非金属介在物組成の影響"},{"@language":"ja-Kana","@value":"Fe-Cr-Ni-Moケイ ステンレスコウ ノ CC シンシ ノズル ヘイソク ニ オヨボス ヒキンゾク カイザイブツ ソセイ ノ エイキョウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680103075584","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formation Mechanism of Inclusions Containing MgO Al2O3 Spinet in Type 304 Stainless Steel"},{"@language":"ja","@value":"ＳＵＳ３０４ステンレス鋼スラブ中のスピネルを含む介在物の生成機構"},{"@language":"ja-Kana","@value":"SUS304 ステンレスコウ スラブチュウ ノ スピネル オ フクム カイザイブツ ノ セイセイ キコウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681463051008","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Slag Composition on the Oxidation Kinetics of Alloying Elements during Electroslag Remelting of Stainless Steel: Part-2 Control of Titanium and Aluminum Content"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681464341632","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Mg and Ca Treatment on Behavior and Particle Size of Inclusions in Bearing Steels"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681464515840","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Behavior of Alloying Elements during Drawing-Ingot-Type Electroslag Remelting of Stainless Steel Containing Titanium"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681464571264","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Characteristics of Inclusions Generated during Al-Mg Complex Deoxidation of Molten Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681464584448","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Control of MgO Al2O3 Spinel Inclusions in Stainless Steels"},{"@value":"Control of MgO·Al2O3 Spinel Inclusions in Stainless Steels"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681464900224","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Evolution of Different Inclusions during Ladle Treatment and Continuous Casting of Stainless Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681465381376","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formation of MgO·Al<sub>2</sub>O<sub>3</sub> Inclusions in High Strength Alloyed Structural Steel Refined by CaO–SiO<sub>2</sub>–Al<sub>2</sub>O<sub>3</sub>–MgO Slag"},{"@value":"Formation of MgO&middot;Al<sub>2</sub>O<sub>3</sub> Inclusions in High Strength Alloyed Structural Steel Refined by CaO&ndash;SiO<sub>2</sub>&ndash;Al<sub>2</sub>O<sub>3</sub>&ndash;MgO Slag"}]},{"@id":"https://cir.nii.ac.jp/crid/1390290493077777408","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Non-metallic Inclusion Evolution during Argon Oxygen Decarburization and Ladle Processing"}]},{"@id":"https://cir.nii.ac.jp/crid/1390564237991321984","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Evolution Mechanism of Inclusions in Al-killed, Ti-bearing 11Cr Stainless Steel with Ca Treatment"}]},{"@id":"https://cir.nii.ac.jp/crid/1390564238081270016","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formation and Evolution of Silicate Inclusions in Molten Steel by Magnesium Treatment"}]},{"@id":"https://cir.nii.ac.jp/crid/1390566775134691840","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Characterisation of Binary Phase Mixtures of Magnesium-Aluminate Spinel and Calcium-Aluminates Using Time-Gated Raman Spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1390569535482391168","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A Novel Model to Design the Equilibrium Slag Compositions for Bearing Steel: Verification and Application"}]},{"@id":"https://cir.nii.ac.jp/crid/1390574411905427200","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Dissolution Behavior of Mg and Ca from Dolomite Refractory into Al-killed Molten Steel"},{"@language":"ja","@value":"ドロマイト耐火物からAl脱酸溶鋼へのMgとCaの溶出挙動"}]},{"@id":"https://cir.nii.ac.jp/crid/1390575588683098496","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Al<sub>2</sub>O<sub>3</sub> and TiO<sub>2</sub> Contents in the Refining Slag on Al and Ti Contents of Incoloy825 Alloy"}]},{"@id":"https://cir.nii.ac.jp/crid/1390845702309098496","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Composition Change of Inclusions in High Carbon Steel before and after Addition of Aluminum"},{"@language":"ja","@value":"高炭素鋼中におけるAl添加前後の介在物組成変化"},{"@language":"ja-Kana","@value":"コウタンソコウ チュウ ニ オケル Al テンカ ゼンゴ ノ カイザイブツ ソセイ ヘンカ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390845702324570496","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of CaO–MgO–SiO<sub>2</sub>–Al<sub>2</sub>O<sub>3</sub>–TiO<sub>2</sub> Slags with Different CaF<sub>2</sub> Contents on Inclusions in Ti-Stabilized 20Cr Stainless Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390848250104966016","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Evolution of Mg–Al-based Inclusions with Changes in Mg Content during Ladle Treatment Based on a Coupled Reaction Model"}]},{"@id":"https://cir.nii.ac.jp/crid/1390848647552188800","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Composition Changes of Inclusions by Reaction with Slag and Refractory: A Review"}]},{"@id":"https://cir.nii.ac.jp/crid/1390850323950661504","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Composition Change of Inclusions in High Carbon Steel before and after Addition of Aluminum"}]},{"@id":"https://cir.nii.ac.jp/crid/1390857063659797248","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Al<sub>2</sub>O<sub>3</sub> on Viscosity and Refining Ability of High Basicity Slag for Heat-resistant Austenitic Stainless Steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1391412881283074304","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formation, 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