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The negative thermal expansion (NTE) of antiperovskite manganese nitrides is greater than −30 ppm/K in α (coefficient of linear thermal expansion), which is several to ten times as large as that of conventional NTE materials. The giant NTE of the manganese nitrides can compensate or control large thermal expansion of plastics by forming composites. We attempt to make the fine-grained NTE manganese nitrides for thermal expansion control of light transmitting plastics. In the fine-graining process, NTE of manganese nitrides changed because of a change in the chemical composition. A technique to control NTE and grain size simultaneously is necessary for the manganese nitride filler.<br>"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410290696583339776","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000265564125"}],"foaf:name":[{"@language":"en","@value":"Ichigo Masayoshi"},{"@language":"ja","@value":"市古 征義"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University"},{"@language":"ja","@value":"名古屋大学大学院工学研究科結晶材料工学専攻"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326211413248","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60283454"},{"@type":"NRID","@value":"1000060283454"},{"@type":"NRID","@value":"9000003247294"},{"@type":"NRID","@value":"9000006844546"},{"@type":"NRID","@value":"9000412163290"},{"@type":"NRID","@value":"9000345326644"},{"@type":"NRID","@value":"9000412162614"},{"@type":"NRID","@value":"9000024993038"},{"@type":"NRID","@value":"9000401982928"},{"@type":"NRID","@value":"9000401970955"},{"@type":"NRID","@value":"9000401907226"},{"@type":"NRID","@value":"9000390871358"},{"@type":"NRID","@value":"9000010570168"},{"@type":"NRID","@value":"9000045647875"},{"@type":"NRID","@value":"9000401904798"},{"@type":"NRID","@value":"9000401804747"},{"@type":"NRID","@value":"9000258196079"},{"@type":"NRID","@value":"9000392873880"},{"@type":"NRID","@value":"9000257840985"},{"@type":"NRID","@value":"9000409848814"},{"@type":"NRID","@value":"9000401981802"},{"@type":"NRID","@value":"9000257856521"},{"@type":"NRID","@value":"9000412381567"},{"@type":"NRID","@value":"9000402005615"},{"@type":"NRID","@value":"9000401896356"},{"@type":"NRID","@value":"9000258195198"},{"@type":"NRID","@value":"9000019057094"},{"@type":"NRID","@value":"9000401975192"},{"@type":"NRID","@value":"9000018934402"},{"@type":"NRID","@value":"9000346930471"},{"@type":"NRID","@value":"9000331905550"},{"@type":"NRID","@value":"9000401972644"},{"@type":"NRID","@value":"9000401899296"},{"@type":"NRID","@value":"9000408890996"},{"@type":"NRID","@value":"9000258195748"},{"@type":"NRID","@value":"9000388463344"},{"@type":"NRID","@value":"9000255728328"},{"@type":"NRID","@value":"9000401881406"},{"@type":"NRID","@value":"9000394967622"},{"@type":"NRID","@value":"9000401889157"},{"@type":"NRID","@value":"9000257845257"},{"@type":"NRID","@value":"9000107346879"},{"@type":"NRID","@value":"9000401887492"},{"@type":"NRID","@value":"9000410195040"},{"@type":"NRID","@value":"9000409792328"},{"@type":"NRID","@value":"9000242834487"},{"@type":"NRID","@value":"9000401886096"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0069118"}],"foaf:name":[{"@language":"en","@value":"Takenaka Koshi"},{"@language":"ja","@value":"竹中 康司"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University"},{"@language":"ja","@value":"名古屋大学大学院工学研究科結晶材料工学専攻"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00214876"},{"@type":"LISSN","@value":"00214876"},{"@type":"EISSN","@value":"18806880"},{"@type":"EISSN","@value":"24337501"},{"@type":"NDL_BIB_ID","@value":"000000018323"},{"@type":"ISSN","@value":"00214876"},{"@type":"NCID","@value":"AN00187860"}],"prism:publicationName":[{"@language":"ja","@value":"日本金属学会誌"},{"@language":"en","@value":"Journal of the Japan Institute of Metals and Materials"},{"@language":"en","@value":"J. Japan Inst. Metals"},{"@language":"en","@value":"J. Japan Inst. Metals and Materials"},{"@language":"en","@value":"Journal of the Japan Institute of Metals"},{"@language":"ja","@value":"日本金属学会誌"},{"@language":"en","@value":"J.Japan Inst.Metals"},{"@language":"ja","@value":"日本金屬學會誌"}],"dc:publisher":[{"@language":"en","@value":"The Japan Institute of Metals and Materials"},{"@language":"ja","@value":"公益社団法人 日本金属学会"}],"prism:publicationDate":"2013","prism:volume":"77","prism:number":"10","prism:startingPage":"415","prism:endingPage":"418"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/024943650"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I024943650"},{"@id":"https://www.jstage.jst.go.jp/article/jinstmet/77/10/77_JAW201302/_pdf"}],"availableAt":"2013","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=negative%20thermal%20expansion","dc:title":"negative thermal expansion"},{"@id":"https://cir.nii.ac.jp/all?q=antiperovskite%20manganese%20nitride","dc:title":"antiperovskite manganese nitride"},{"@id":"https://cir.nii.ac.jp/all?q=plastics%20matrix%20composite","dc:title":"plastics matrix composite"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782111082240","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"22360291"},{"@type":"JGN","@value":"JP22360291"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22360291/"}],"notation":[{"@language":"ja","@value":"逆ペロフスカイトの材料学"},{"@language":"en","@value":"Materials Science of Antiperovskites"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216802672512","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233905233408","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Tailoring thermal 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treatment"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145693456640","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mechanical Properties of Metallic Perovskite Mn\n                    <sub>3</sub>\n                    Cu\n                    <sub>0.5</sub>\n                    Ge\n                    <sub>0.5</sub>\n                    N:High‐Stiffness Isotropic Negative Thermal Expansion Material"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707053671168","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Thermal expansion adjustable polymer matrix composites with giant negative thermal expansion filler"}]},{"@id":"https://cir.nii.ac.jp/crid/1360286995747828736","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Spray‐dry synthesis of\n                    <i>β</i>\n                    ‐Cu\n          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measurements"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046038741888","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Negative Thermal Expansion in (HfMg)(WO\n                    <sub>4</sub>\n                    )\n                    <sub>3</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046203559936","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW\n            <sub>2</sub>\n            O\n            <sub>8</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418906251520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Preparation and near zero thermal expansion property of Mn3Cu0.5A0.5N (A=Ni, Sn)/Cu composites"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368904633856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Giant negative thermal expansion in Ge-doped anti-perovskite manganese nitrides"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319089961088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Compounds That Contract on Heating"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320618782848","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Giant negative thermal expansion in antiperovskite manganese nitrides"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670321249927552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Negative thermal expansion in Ge-free antiperovskite manganese nitrides: Tin-doping effect"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793282446336","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Negative thermal expansion ceramics: A review"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793787547136","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Adjustable Zero Thermal Expansion in Antiperovskite Manganese Nitride"}]},{"@id":"https://cir.nii.ac.jp/crid/1390003825176453760","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Negative Thermal Expansion of <i>β</i>-Cu<sub>1.8</sub>Zn<sub>0.2</sub>V<sub>2</sub>O<sub>7</sub> Ceramic Fine Particles Synthesized by a Spray-Drying Method"},{"@language":"ja","@value":"スプレードライ法による<i>β</i>-Cu<sub>1.8</sub>Zn<sub>0.2</sub>V<sub>2</sub>O<sub>7</sub>セラミック微粒子の負熱膨張特性"},{"@value":"スプレードライ法によるβ-Cu[1.8]Zn[0.2]V₂O₇セラミック微粒子の負熱膨張特性"},{"@language":"ja-Kana","@value":"スプレードライホウ ニ ヨル v-Cu[1.8]Zn[0.2]V ₂ O ₇ セラミック ビリュウシ ノ フネツ ボウチョウ トクセイ"},{"@value":"Negative thermal expansion of β-Cu1.8Zn0.2V2O7 ceramic fine particles synthesized by a spray-drying method"}]},{"@id":"https://cir.nii.ac.jp/crid/1390013784258489472","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Systematic Study on the Role of the Third Zn-Site Element in Zn<sub>2−</sub><i><sub>x</sub></i>Mg<i><sub>x</sub></i>P<sub>2</sub>O<sub>7</sub> Showing Giant Negative Thermal Expansion"},{"@value":"Systematic Study on the Role of the Third Zn-Site Element in Zn[2-x]Mg[x]P₂O₇ Showing Giant Negative Thermal Expansion"}]},{"@id":"https://cir.nii.ac.jp/crid/1390285697596857600","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Thermal Management of Advanced Electronic Devices by Negative Thermal Expansion Particulates"},{"@language":"ja","@value":"負熱膨張性微粒子による電子デバイスのサーマル・マネジメント"},{"@language":"ja-Kana","@value":"フネツ ボウチョウセイ ビリュウシ ニ ヨル デンシ デバイス ノ サーマル ・ 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