書誌事項
- タイトル別名
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- The Reaction Mechanisms of O<sub>2</sub> Formation in Photosynthesis
- コウゴウセイ ニ オケル サンソ ハッセイ ノ ハンノウ キコウ
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抄録
<p>Photosystems are natural energy conversion systems evolved for over 2,700 million years. Among the photosystems, photosystem II (PSII) catalyzes the light-driven water decomposition reaction with the production of O2, protons and electrons to reduce plastoquinone. The reaction is important not only for understanding natural photosynthesis but also for creating efficient artificial photosynthesis. In this review, PSII catalytic intermediate states and their reaction mechanisms elucidated by experimental and theoretical approaches are introduced mainly following the development of the X-ray crystallography. For the O2 formation mechanism, two representative mechanisms, acid-base and radical coupling, are explained. Finally, we discuss the geometrical and electronic structures of inorganic model complex in comparison with those of the native catalytic center in PSII.</p>
収録刊行物
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- 生物物理
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生物物理 58 (3), 127-133, 2018
一般社団法人 日本生物物理学会
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詳細情報 詳細情報について
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- CRID
- 1390001288035517312
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- NII論文ID
- 130007378606
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- NII書誌ID
- AN00129693
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- ISSN
- 13474219
- 05824052
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- NDL書誌ID
- 029114665
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可