FORMATION OF AMINO ACID CONDENSATES PARTLY HAVING PEPTIDE BONDS IN A SIMULATED SUBMARINE HYDROTHERMAL ENVIRONMENT
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- Chandru Kuhan
- Department of Chemistry, Graduate School and Faculty of Engineering, Yokohama National University
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- Obayashi Yumiko
- Department of Chemistry, Graduate School and Faculty of Engineering, Yokohama National University
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- Kaneko Takeo
- Department of Chemistry, Graduate School and Faculty of Engineering, Yokohama National University
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- Kobayashi Kensei
- Department of Chemistry, Graduate School and Faculty of Engineering, Yokohama National University
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説明
<p> Although abiotic polymerization of amino acids is an important step in origin of life study, it has often eluded that their formation could be limited in the hydrothermal systems. To show this we heated an aqueous solution of several amino acids in a simulated hydrothermal environment to assess the possible formation of peptides among the heated products. Peptide concentrations estimated by the Lowry method were significantly higher when the mixture was heated at 300℃ than those at lower temperatures, despite having more than 80% of the initial amino acids decomposed. We also revealed that the peptides measured here were only part of the bonds in the heated products. The major heat products were non-peptide amino acid condensates (NPACs) that only possess partial peptide bonds. The role of NPACs should be examined though they were often ignored in the classical chemical evolution scenario so far.</p>
収録刊行物
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- Viva Origino
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Viva Origino 41 (3), 24-28, 2013
生命の起原および進化学会
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詳細情報 詳細情報について
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- CRID
- 1390009073680003712
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- NII論文ID
- 110009817131
- 130008137606
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- NII書誌ID
- AA11148698
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- ISSN
- 13466933
- 09104003
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- NDL書誌ID
- 025555669
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- NDL-Digital
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可