{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679028116096.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2116/bunsekikagaku.42.6_351"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DyaK3sXkvVCrt7s%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"3825370"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/3825370"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I3825370"}},{"identifier":{"@type":"URI","@value":"https://dl.ndl.go.jp/pid/10893099"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"10893099"}},{"identifier":{"@type":"NAID","@value":"110002906577"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/digimeta/10893099"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/bunsekikagaku1952/42/6/42_6_351/_pdf"}},{"identifier":{"@type":"URI","@value":"http://dl.ndl.go.jp/info:ndljp/pid/10893099"}}],"dc:title":[{"@language":"en","@value":"Determination of boron by spectrophotometric FIA using Azomethine H."},{"@value":"アゾメチンＨを用いる吸光光度検出フローインジェクション法によるホウ素の定量"},{"@language":"ja-Kana","@value":"アゾメチン H オ モチイル キュウコウ コウド ケンシュツ フロー インジェ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"A spectrophotometric determination of boron with Azomethine H {1-(salicylidenamino)-8-hydroxynaphthalene-3, 6-disulfonic acid} by FIA has been conducted. A dualchannel FIA apparatus was used for the sake of both simplicity and convenience. A sample solution containing less than 1 ppm of boron was injected into a carrier stream (deionized water) and was merged with a reagent stream containing 0.25% (w/v) Azomethine H, 1% ascorbic acid, 1% EDTA and 0.8 M diammonium hydrogenphosphate buffer (pH 7.2). The mixture was flowed through 10 m long reaction tube (PTFE, 0.5 mm i.d.) at a flow rate of 0.9 ml/min. The absorbance was recorded at 425 nm. The calibration curve was linear over the range of 0.1 to 1.0 ppm of boron. The relative standard deviations (<I>n</I>=15) for 0.2 and 0.8 ppm of boron were 0.63 and 0.20%, respectively. The sample throughput was about 20 h<SUP>-1</SUP>. The proposed method was applied to the determination of boron in eye lotions."},{"@value":"アゾメチンH {1-(サリチリデンアミノ)-8-ヒドロキシナフタレン-3,6-ジスルホン酸}を吸光光度試薬とするホウ素のフローインジェクション法(FIA)を検討した.簡単な2流路系を採用し,試薬溶液にはそれぞれ1%(w/v)のアスコルビン酸とEDTAを含む0.25%(w/v)アゾメチンH溶液(0.8Mリン酸水素二アンモニウム緩衝溶液, pH7.2)を送液した.又,キャリヤー溶液はイオン交換水とし,これに六方インジェクションバルブを用いて試料溶液を注人した.検量線はホウ素0.1～1.0 ppmの範囲で良好な直線となり, 0.2及び0.8ppmの15回繰り返しによる相対標準偏差は,それぞれ0.63, 0.20%であった.ホウ素に対して25倍量の存在下で顕著な妨害を示すイオンはバナジウム(V)以外にはなく,選択性の優れたFIA法を確立した.本法を市販目薬中のホウ素の定量に応用した."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001204053805057","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020771127"},{"@type":"NRID","@value":"9000002459110"}],"foaf:name":[{"@language":"en","@value":"NOSE Kazuko"},{"@language":"ja","@value":"野瀬 和子"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Environmental Resources Research Center, Okayama University of Science"},{"@language":"ja","@value":"岡山理科大学環境資源研究センター"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001204051240832","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000283295490"},{"@type":"NRID","@value":"9000015659392"},{"@type":"NRID","@value":"9000253158893"},{"@type":"NRID","@value":"9000253156168"},{"@type":"NRID","@value":"9000009160149"},{"@type":"NRID","@value":"9000000086979"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0035482"}],"foaf:name":[{"@language":"en","@value":"ZENKI Michio"},{"@language":"ja","@value":"善木 道雄"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"岡山理科大学理学部化学科"},{"@language":"en","@value":"Department of Chemistry, Faculty of Science, Okayama University of Science"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001204053502336","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020710166"},{"@type":"NRID","@value":"9000020775550"},{"@type":"NRID","@value":"9000020731407"},{"@type":"NRID","@value":"9000020796434"},{"@type":"NRID","@value":"9000004508496"}],"foaf:name":[{"@language":"en","@value":"SHIMOISHI Yasuaki"},{"@language":"ja","@value":"下石 靖昭"}],"jpcoar:affiliationName":[{"@language":"en","@value":"School of Health Science, Okayama University"},{"@language":"ja","@value":"岡山大学医療技術短期大学部"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"05251931"},{"@type":"NDL_BIB_ID","@value":"000000021279"},{"@type":"ISSN","@value":"05251931"},{"@type":"LISSN","@value":"05251931"},{"@type":"PISSN","@value":"http://id.crossref.org/issn/05251931"},{"@type":"NCID","@value":"AN00222633"}],"prism:publicationName":[{"@language":"ja","@value":"分析化学"},{"@language":"en","@value":"BUNSEKI KAGAKU"},{"@language":"en","@value":"BUNSEKI KAGAKU"},{"@language":"en","@value":"Bunseki kagaku"},{"@language":"ja","@value":"分析化学"}],"dc:publisher":[{"@language":"en","@value":"The Japan Society for Analytical Chemistry"},{"@language":"ja","@value":"公益社団法人 日本分析化学会"}],"prism:publicationDate":"1993","prism:volume":"42","prism:number":"6","prism:startingPage":"351","prism:endingPage":"355"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/3825370"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I3825370"},{"@id":"https://dl.ndl.go.jp/pid/10893099"},{"@id":"http://id.ndl.go.jp/digimeta/10893099"},{"@id":"http://www.jstage.jst.go.jp/article/bunsekikagaku1952/42/6/42_6_351/_pdf"},{"@id":"http://dl.ndl.go.jp/info:ndljp/pid/10893099"}],"availableAt":"1993","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=spectrophotometric%20FIA%20of%20boron","dc:title":"spectrophotometric FIA of boron"},{"@id":"https://cir.nii.ac.jp/all?q=Azomethine%20H","dc:title":"Azomethine H"},{"@id":"https://cir.nii.ac.jp/all?q=determination%20of%20boron%20in%20eye%20lotion","dc:title":"determination of boron in eye lotion"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1362544418951910400","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@value":"An automated procedure for the determination of boron in plant tissue"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794873257728","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@value":"Spectrophotometric determination of boron with an azomethine H derivative"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204051530496","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Determination of boron using ion-exclusion chromatography with postcolumn derivatization method."},{"@value":"ポストカラム誘導体化イオン排除クロマトグラフィーによるホウ素の定量"},{"@language":"ja-Kana","@value":"ポスト カラム 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Direct determination of boron in iron and Steel by ion-pair reversed-phase HPLC with a Laboratory-packed column."},{"@language":"ja","@value":"高度技術を支える分析化学　　自作カラムを用いるイオン対逆相分配高速液体クロマトグラフィーによる鉄及び鋼中の微量ホウ素の直接定量"},{"@value":"自作カラムを用いるイオン対逆相分配高速液体クロマトグラフィーによる鉄及び鋼中の微量ホウ素の直接定量"},{"@language":"ja-Kana","@value":"ジサク カラム オ モチイル イオンツイ ギャクソウ ブンパイ コウソク エキタイ クロマトグラフィー ニ ヨル テツ オヨビ コウ チュウ ノ ビリョウ ホウソ ノ チョクセツ テイリョウ"},{"@value":"自作カラムを用いるイオン対逆相分配高速液体クロマトグラフィーによる鉄及び鋼中の微量ホウ素の直接定量(<特集>高度技術を支える分析化学)"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679029513728","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Spectrophotometric determination of boron in glass with 1-(salicylideneamino)-8-hydroxynaphthalene-3,6-disulfonic acid."},{"@value":"１‐（サリチリデンアミノ）‐８‐ヒドロキシナフタリン‐３，６‐ジスルホン酸を用いるガラス中の微量ほう素の吸光光度定量"},{"@language":"ja-Kana","@value":"1 サリチリデンアミノ 8 ヒドロキシナフタリン 3 6 ジスルホンサン オ"},{"@language":"ja","@value":"1-(サリチリデンアミノ)-8-ヒドロキシナフタリン-3,6-ジスルホン酸を用いるガラス中の微量ホウ素の吸光光度定量(<特集>無機材料分析のためのスペクトロメトリー)"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679347574784","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A Simple and Rapid Determination Method of Boron in Wastewater Using Ion-Selective Electrode."},{"@value":"イオン電極を用いた排水中ホウ素の簡易・迅速測定法"},{"@language":"ja-Kana","@value":"イオン デンキョク オ モチイタ ハイスイ チュウ ホウソ ノ カンイ ジンソク ソクテイホウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1520290882955463808","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"フローインジェクション分析:無機分析への応用"},{"@language":"ja-Kana","@value":"フロー インジェクション ブンセキ ムキ ブンセキ エ ノ オウヨウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1571417124436845312","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571417124436851584","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571698599413558272","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572543024343694464","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572824499320403456","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974297114752","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573387449273819904","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573387449273830016","@type":"Article","relationType":["cites"]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0007961379"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I3825370"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R100000039-I10893099"},{"@type":"CROSSREF","@value":"10.2116/bunsekikagaku.42.6_351"},{"@type":"NDL_DC","@value":"info:ndljp/pid/10893099"},{"@type":"CIA","@value":"110002906577"},{"@type":"OPENAIRE","@value":"doi_dedup___::7ec603b78c0b2d65f8db120e118011c1"},{"@type":"CROSSREF","@value":"10.2116/analsci.30.885_references_DOI_WrlXJHISZT4wqrfSs7H6e4n5cOB"},{"@type":"CROSSREF","@value":"10.2116/bunsekikagaku.50.867_references_DOI_WrlXJHISZT4wqrfSs7H6e4n5cOB"},{"@type":"CROSSREF","@value":"10.2355/tetsutohagane1955.89.9_973_references_DOI_WrlXJHISZT4wqrfSs7H6e4n5cOB"}]}