{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679068548352.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.5650/jos1996.47.777"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"4546063"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/4546063"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I4546063"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/jos1996/47/8/47_8_777/_pdf"}},{"identifier":{"@type":"NAID","@value":"10002276279"}}],"dc:title":[{"@language":"en","@value":"Synthesis of a Methacrylate Monomer Containing Perfluorooctyl Group Derived from Dicyclopentadiene and the Wetting Property of its Copolymer"},{"@value":"ジシクロペンタジエンから誘導されるペルフルオロオクチル基含有メタクリレートの合成とその共重合物のぬれ特性"},{"@language":"ja-Kana","@value":"ジシクロペンタジエン カラ ユウドウサレル ペルフルオロオクチルキ ガンユウ"}],"description":[{"type":"abstract","notation":[{"@language":"en","@value":"A methacrylate introduced the perfluorooctyl group was synthesised from the 2-(perfluorooctyl) ethanol and dicyclopentadiene. The monomer and 2-(perfluorooctyl) ethyl methacrylate as control were effective for copolymerzation with styrene. Each monomer reactivity ratio were r<SUB>1</SUB>=1.35, r<SUB>2</SUB>=0.48 and r<SUB>1</SUB>=1.22, r<SUB>2</SUB>=0.99 (1: styrene) respectively.<BR>Contact angle of water on the coating sample of copolymer with styrene and cured coating sample of unsaturated polyester mixed with the monomer increased as perfluorooctyl group concentration. The former angle increased gradually with perfluorooctyl group concentration, while the latter did rapidly. It supposedly depend on localizing of perfluorooctyl group on the surface because of special properties of fluoro organic compounds."},{"@value":"2-(ペルフルオロオクチル)エタノールとジシクロペンタジエンの付加反応物からペルフルオロオクチル基が導入されたメタクリレートを合成した。<BR>本モノマーおよびコントロールに選定した2-(ペルフルオロオクチル)エチルメタクリレートとスチレンとの共重合性は優れ,各々モノマー反応性比はr<SUB>1</SUB>=1.35, r<SUB>2</SUB>=0.49およびr<SUB>1</SUB>=1.22, r<SUB>2</SUB>=0.99 (1:スチレン)であった。<BR>スチレンとの共重合体の塗膜およびモノマー混入の不飽和ポリエステル樹脂の硬化膜の水の接触角はペルフルオロオクチル基濃度と共に増加した。前者で徐々に増加するのに対して,後者では急激に増加した。これは有機フッ素化合物の特異性によるペルフルオロオクチル基の表面への偏在によるものと思われる。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001204092305792","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000079314"}],"foaf:name":[{"@language":"en","@value":"YOSHIMURA Hikoji"},{"@language":"ja","@value":"吉村 彦二"}],"jpcoar:affiliationName":[{"@language":"en","@value":"AMCO Enterprises Incorporated"},{"@language":"ja","@value":"アムコエンタープライズ株式会社"}]},{"@id":"https://cir.nii.ac.jp/crid/1410572171331428480","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000080325"}],"foaf:name":[{"@language":"en","@value":"USUI Masao"},{"@language":"ja","@value":"碓井 正雄"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Tokyo Metropolitan Industrial Technology Research Institute"},{"@language":"ja","@value":"東京都立産業技術研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1410572171331428482","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000080326"}],"foaf:name":[{"@language":"en","@value":"SHINDO Yoshio"},{"@language":"ja","@value":"進藤 良夫"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Tokyo Metropolitan Industrial Technology Research Institute"},{"@language":"ja","@value":"東京都立産業技術研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1410572171331428484","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000080327"}],"foaf:name":[{"@language":"en","@value":"ITO Yoichi"},{"@language":"ja","@value":"伊東 洋一"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"東京都立産業技術研究所"},{"@language":"en","@value":"Tokyo Metropolitan Industrial Technology Research Institute"}]},{"@id":"https://cir.nii.ac.jp/crid/1410572171331428483","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000080328"}],"foaf:name":[{"@language":"en","@value":"NINOMIYA Atsuyuki"},{"@language":"ja","@value":"二宮 淳行"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Tokyo Metropolitan Industrial Technology Research Institute"},{"@language":"ja","@value":"東京都立産業技術研究所"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13418327"},{"@type":"EISSN","@value":"18841996"},{"@type":"NDL_BIB_ID","@value":"000000097916"},{"@type":"ISSN","@value":"13418327"},{"@type":"LISSN","@value":"13418327"},{"@type":"NCID","@value":"AN10512582"}],"prism:publicationName":[{"@language":"en","@value":"Journal of Japan Oil Chemists' Society"},{"@language":"ja","@value":"日本油化学会誌"},{"@language":"en","@value":"J. Jpn. Oil Chem. Soc."},{"@language":"ja","@value":"日本油化学会誌"}],"dc:publisher":[{"@language":"en","@value":"Japan Oil Chemists' Society"},{"@language":"ja","@value":"公益社団法人 日本油化学会"}],"prism:publicationDate":"1998","prism:volume":"47","prism:number":"8","prism:startingPage":"777","prism:endingPage":"782,790"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/4546063"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I4546063"},{"@id":"https://www.jstage.jst.go.jp/article/jos1996/47/8/47_8_777/_pdf"}],"availableAt":"1998","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=perfluorooctyl","dc:title":"perfluorooctyl"},{"@id":"https://cir.nii.ac.jp/all?q=contact%20angle","dc:title":"contact angle"},{"@id":"https://cir.nii.ac.jp/all?q=methacrylate","dc:title":"methacrylate"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1570009749181931648","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570291224158436480","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571135649104467456","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571698599041994624","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571980074018702592","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572261549011310208","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572543023972124032","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573668923894862976","@type":"Article","relationType":["cites"]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0035277117"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I4546063"},{"@type":"CROSSREF","@value":"10.5650/jos1996.47.777"},{"@type":"CIA","@value":"10002276279"}]}