{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679071275904.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.3327/jnst.34.484"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DyaK2sXktFWks70%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"4219696"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/4219696"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I4219696"}},{"identifier":{"@type":"DOI","@value":"10.1080/18811248.1997.9733695"}},{"identifier":{"@type":"NAID","@value":"10002077151"}}],"dc:title":[{"@language":"en","@value":"Ion Exchange of Cesium on Potassium Nickel Hexacyanoferrate (II) s."},{"@value":"Ion Exchange of Cesium on Potassium Nickel Hexacyanoferrate(2)s"},{"@language":"ja-Kana","@value":"Ion Exchange of Cesium on Potassium Nic"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The ion exchange of Cs<SUP>+</SUP> on a nonstoichiometric compound K<SUB>0.87</SUB>Ni<SUB>0.57</SUB>[NiFe(CN)<SUB>6</SUB>]•nH<SUB>2</SUB>O (KNiFC) was examined by batch methods. The distribution coefficient of Cs<SUP>+</SUP>, K<SUB>d, Cs</SUB>, was independent of Na<SUP>+</SUP> concentration up to 5M (=mol/dm<SUP>3</SUP>), while it decreased with increasing concentrations of both K<SUP>+</SUP> and NH<SUP>+</SUP><SUB>4</SUB>. The separation factor for Cs/Rb, α<SUB>Cs/Rb</SUB>, was 4.7×10<SUP>2</SUP> in the presence of 5M Na<SUP>+</SUP>. The decreasing order of K<SUB>d, Cs</SUB> in the coexisting cations was found to be NH<SUP>+</SUP><SUB>4</SUB>>K<SUP>+</SUP>, H<SUP>+</SUP> > Na<SUP>+</SUP>, Ca<SUP>2+</SUP>. The uptake of Cs<SUP>+</SUP> on KNiFC followed a Langmuir-type isotherm and the maximum amount of Cs<SUP>+</SUP> taken up was estimated to be 2.57±0.074mmol/g. The free energy of K<SUP>+</SUP>_ ?? _Cs<SUP>+</SUP> ion exchange was calculated to be -5.4±1.4kJ/mol by Kielland plot."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410282679070603008","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000053484"}],"foaf:name":[{"@language":"en","@value":"HARJULA Risto"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Laboratory of Radiochemistry, Department of Chemistry, University of Helsinki"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679070603137","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000053481"}],"foaf:name":[{"@language":"en","@value":"LEHTO Jukka"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Laboratory of Radiochemistry, Department of Chemistry, University of 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Hitoshi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Institute for Advanced Materials Processing, Tohoku University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00223131"},{"@type":"EISSN","@value":"18811248"},{"@type":"NDL_BIB_ID","@value":"000000118776"},{"@type":"ISSN","@value":"00223131"},{"@type":"LISSN","@value":"00223131"},{"@type":"NCID","@value":"AA00703720"}],"prism:publicationName":[{"@language":"en","@value":"Journal of Nuclear Science and Technology"},{"@language":"ja","@value":"Ｊｏｕｒｎａｌ　ｏｆ　Ｎｕｃｌｅａｒ　Ｓｃｉｅｎｃｅ　ａｎｄ　Ｔｅｃｈｎｏｌｏｇｙ（日本原子力学会英文論文誌）"},{"@language":"en","@value":"J. Nucl. Sci. Technol."},{"@language":"en","@value":"Journal of Nuclear Science and Technology"}],"dc:publisher":[{"@language":"en","@value":"Atomic Energy Society of Japan"},{"@language":"ja","@value":"一般社団法人 日本原子力学会"}],"prism:publicationDate":"1997","prism:volume":"34","prism:number":"5","prism:startingPage":"484","prism:endingPage":"489"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/4219696"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I4219696"}],"availableAt":"1997","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=ion%20exchange","dc:title":"ion exchange"},{"@id":"https://cir.nii.ac.jp/all?q=cesium","dc:title":"cesium"},{"@id":"https://cir.nii.ac.jp/all?q=cesium%20ions","dc:title":"cesium ions"},{"@id":"https://cir.nii.ac.jp/all?q=potassium%20nickel%20hexacyanoferrates","dc:title":"potassium nickel hexacyanoferrates"},{"@id":"https://cir.nii.ac.jp/all?q=distribution%20coefficient","dc:title":"distribution coefficient"},{"@id":"https://cir.nii.ac.jp/all?q=separation%20factors","dc:title":"separation factors"},{"@id":"https://cir.nii.ac.jp/all?q=Langmuir%20isotherm","dc:title":"Langmuir isotherm"},{"@id":"https://cir.nii.ac.jp/all?q=thermodynamic%20equilibrium%20constant","dc:title":"thermodynamic equilibrium constant"},{"@id":"https://cir.nii.ac.jp/all?q=free%20energy","dc:title":"free energy"},{"@id":"https://cir.nii.ac.jp/all?q=Kielland%20plot","dc:title":"Kielland plot"},{"@id":"https://cir.nii.ac.jp/all?q=ion-exchange%20selectivity","dc:title":"ion-exchange selectivity"},{"@id":"https://cir.nii.ac.jp/all?q=concentration%20dependence","dc:title":"concentration dependence"},{"@id":"https://cir.nii.ac.jp/all?q=distribution%20functions","dc:title":"distribution functions"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285708573022208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Efficient synthesis of size-controlled open-framework nanoparticles fabricated with a micro-mixer: route to the improvement of Cs adsorption performance"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567181350695424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Adsorption behavior of a carbonized paper sludge towards 137Cs"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574094420064384","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@value":"Adsorption Studies on Clay Minerals. 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A Formulation of the Thermodynamics of Exchange Adsorption"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848657008508928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Mechanism of K + , Cs + ion exchange in nickel ferrocyanide: A density functional theory study"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204142533120","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Simultaneous Enhancement of Cs-Adsorption and Magnetic Properties of Prussian Blue by Thermal Partial Oxidation"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204157159040","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"放射能高汚染水からの放射性物質の選択的除去および安定化処理"},{"@language":"en","@value":"Selective Decontamination and Stable Solidification of Radioactive Nuclides in High-Activity-Level-Contaminated Water"},{"@language":"ja-Kana","@value":"ホウシャノウ コウオセンスイ カラ ノ ホウシャセイ ブッシツ ノ センタクテキ ジョキョ オヨビ アンテイカ ショリ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204434262016","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Preparation of Adsorptive Fibers for Removal of Cesium from Seawater"},{"@value":"海水中のセシウム除去のための吸着繊維の作製"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204435018624","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Separation of Cesium: Adsorption and Desorption Properties of Hexacyanidoferrate(II)s Immobilized in Silica Gel"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204435655680","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"(1) Selective separation and solidification of radioactive nuclides by zeolites"},{"@value":"(1)ゼオライトによる放射性核種の選択的分離・固化"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204510870656","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Salt Concentration of Cesium Solution on Cesium-Binding Capacity of Potassium Cobalt-Hexacyanoferrate-Impregnated Fiber"},{"@value":"不溶性フェロシアン化物担持繊維のセシウム吸着容量に及ぼすセシウム水溶液の塩濃度の効果"},{"@language":"ja-Kana","@value":"フヨウセイ フェロシアンカブツタンジセンイ ノ セシウム キュウチャク ヨウリョウ ニ オヨボス セシウム スイヨウエキ ノ シオ ノウド ノ コウカ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679088218496","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"放射能高汚染水処理に係る検討事例"},{"@language":"en","@value":"Examples of High-Activity-Level Water Treatment"},{"@language":"ja-Kana","@value":"ホウシャノウ コウオセン ミズショリ ニ カカル ケントウ 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