{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679095921280.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.63.2044"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/63/7/2044/56214395/bcsj.63.2044.pdf"}},{"identifier":{"@type":"NAID","@value":"130001979500"}}],"dc:title":[{"@language":"en","@value":"Electrosorption of tetraethylene glycol monododecyl ether at the polarized nitrobenzene-water interface."}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The adsorption of tetraethylene glycol monododecyl ether, C12E4, has been studied by measuring the electrocapillary curves at the polarized interface between the nitrobenzene solution of 0.1 mol dm<SUP>−3</SUP> tetrapentylammonium tetraphenylborate and the aqueous solution of 0.05 mol dm<SUP>−3</SUP> lithium chloride. C12E4 adsorbed at the interface over the entire polarized potential range of 250 mV. Although C12E4 itself is a neutral molecule, its surface activity was greatly affected by changing the potential drop across the interface; an increase in the potential of the aqueous phase with respect to the potential in the nitrobenzene phase markedly enhanced the adsorption. The complex formation between the adsorbed C12E4 molecules and Li<SUP>+</SUP> ions in the aqueous side of the interface was shown to play a decisive role in determining the dependence of adsorption on the electrical potential difference across the interface. A proposed model for complex formation at the interface based on the Gouy–Chapman double-layer theory well-explained the observed trend in the adsorption Gibbs energy when the potential drop across the interface was changed."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001204052226560","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021775695"},{"@type":"NRID","@value":"9000021879881"},{"@type":"NRID","@value":"9000000011363"},{"@type":"NRID","@value":"9000021868453"},{"@type":"NRID","@value":"9000021786242"},{"@type":"NRID","@value":"9000000023956"},{"@type":"NRID","@value":"9000021782155"},{"@type":"NRID","@value":"9000257716049"},{"@type":"NRID","@value":"9000021861115"},{"@type":"NRID","@value":"9000021776182"},{"@type":"NRID","@value":"9000021773447"},{"@type":"NRID","@value":"9000021825746"},{"@type":"NRID","@value":"9000021870336"},{"@type":"NRID","@value":"9000364790427"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0157157"}],"foaf:name":[{"@language":"en","@value":"Kakiuchi Takashi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679095921282","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021782159"}],"foaf:name":[{"@language":"en","@value":"Usui Taketoshi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679095921280","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021782161"}],"foaf:name":[{"@language":"en","@value":"Senda Mitsugi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"LISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@language":"en","@value":"Bulletin of the Chemical Society of Japan"},{"@language":"en","@value":"Bull. Chem. Soc. Jpn."}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"1990","prism:volume":"63","prism:number":"7","prism:startingPage":"2044","prism:endingPage":"2050"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/63/7/2044/56214395/bcsj.63.2044.pdf"}],"availableAt":"1990","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219102945408","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effect of Counterionic Species on the Adsorption of Tetradecyltrimethylammonium Ion at the Polarized Nitrobenzene–Water Interface"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219102960128","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Electrocapillary Curves of the Phosphatidylcholine Monolayer at the Polarized Oil–Water Interface. I. Measurement of Interfacial Tension Using a Computer-Aided Pendant-Drop Method"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144146826112","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electrocapillary phenomena at oil-water interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145700518784","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electrocapillarity and electroadsorption"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694073545344","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electrochemical Instability in Liquid–Liquid Two-Phase Systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694078742400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Thermodynamics of the Electrocapillarity of Oil–Water Interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169056694528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Electrocapillary Curves of the Phosphatidylcholine Monolayer at the Polarized Oil–Water Interface. II. Double Layer Structure of Dilauroylphosphatidylcholine Monolayer at the Nitrobenzene–Water Interface"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095343529088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Barium ion-selective electrode based on a neutral carrier complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644030824192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal-ion Complexation of Noncyclic Poly(oxyethylene) Derivatives. I. Solvent Extraction of Alkali and Alkaline Earth Metal Thiocyanates and Iodides"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045394869504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ion transport by heart mitochondria"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699995859483520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"LI. <i>A contribution to the theory of electrocapillarity</i>"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469566447744","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"�ber die Beeinflussung der Adsorption von Neutralmolek�len durch ein elektrisches Feld"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469608217600","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Influence of the steady-state conditions on the electrosorption properties of dodecanolpolyglycol ethers below and above the critical micelle concentration"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470347789824","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electric Fields across Water-Nitrobenzene Interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945099098368","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The role of non-ionic polyoxyethylene ether surfactants on ion transfer across aqueous/organic solution interfaces studied by polarography with the electrolyte dropping electrode"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419067177216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Boundary Tension at Water-Organic Liquid Interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370570068480","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electrocapillary phenomena at oil-water interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319342891904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Wechselstrompolarographische Untersuchungen zur Bestimmung der kritischen Micellkonzentration von Dodecylpolyglykoläthern in wäßrigen Elektrolytlösungen"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204119299072","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of poly(oxyethylene) chain length on electrosorption of hexa and octa(ethylene glycol) mono n-dodecyl ethers at the polarized nitrobenzene-water interface."},{"@value":"Effect of Poly(oxyethylene) Chain Length on Electrosorption of Hexa and Octa(ethylene glycol) Mono <i>n</i>-Dodecyl Ethers at the Polarized Nitrobenzene–Water Interface"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204256216192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Solvent extraction of lanthanoid and yttrium ions with poly(oxyethylene)alkylphenylether."}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679101721856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Structure of the electrical double layer at the interface between nitrobenzene solution of tetrabutylammonium tetraphenylborate and aqueous solution of lithium chloride."}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679106206336","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The effect of the electrical potential difference on the adsorption of the hexadecyltrimethylammonium ion at the polarized nitrobenzene-water interface."}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679232398720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Solvent extraction of lanthanoid, yttrium and some polyvalent metal ions with phosphoric acid esters of Triton X-100."}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0000321803"},{"@type":"CROSSREF","@value":"10.1246/bcsj.63.2044"},{"@type":"CIA","@value":"130001979500"},{"@type":"OPENAIRE","@value":"doi_dedup___::94e672a607a77e3446c2834cae154cc4"},{"@type":"CROSSREF","@value":"10.1246/bcsj.63.3264_references_DOI_aNNjfsoSd1rzOd8WzuaNJnb6hnj"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20110217_references_DOI_aNNjfsoSd1rzOd8WzuaNJnb6hnj"}]}