{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679096095232.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.4139/sfj.55.360"}},{"identifier":{"@type":"HDL","@value":"http://hdl.handle.net/2433/299248"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"6965618"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/6965618"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I6965618"}},{"identifier":{"@type":"NAID","@value":"10012931608"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Electrodeposition of CdTe from Acidic Aqueous Solutions Containing Citric Acid"},{"@language":"ja","@value":"酸性クエン酸水溶液からのＣｄＴｅ薄膜電析"},{"@language":"ja-Kana","@value":"サンセイ クエンサン スイヨウエキ カラ ノ CdTe ハクマクデンセキ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Potentiostatic cathodic electrodeposition of CdTe compound on a gold-plated substrate was studied at 70<sup>º</sup>C using new acidic aqueous electrolytic baths (pH3.0) containing citric acid. The composition of the deposits was controlled by changing the deposition potential, which depended on the concentrations of Te(IV) and citrate. The stoichiometric CdTe layers obtained were polycrystalline, having a uniform surface morphology without pinholes. In the presence of citrate ions, the solubility of tetravalent tellurium species in the citrate bath at pH3.0 was more than 10mM, which was about one or two orders higher than that in conventional acidic sulfate baths. The increase in the solubility will be accounted for by a complexation between Te(IV) and citrate ions, which has not been reported so far. A set of linear sweep cathodic voltammograms for Te(IV)-citrate baths suggested the presence of the complex.<br>"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420001326219202560","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"30283633"},{"@type":"NRID","@value":"1000030283633"},{"@type":"ORCID","@value":"0000-0002-7564-9416"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0051980"}],"foaf:name":[{"@language":"en","@value":"MURASE Kuniaki"},{"@language":"ja","@value":"邑瀬 邦明"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Materials Science and Engineering, Kyoto University"},{"@language":"ja","@value":"京都大学大学院 工学研究科"}]},{"@id":"https://cir.nii.ac.jp/crid/1410009222422737795","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001235990"}],"foaf:name":[{"@language":"en","@value":"ODA Toru"},{"@language":"ja","@value":"小田 暢"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"京都大学大学院 工学研究科"},{"@language":"en","@value":"Department of Materials Science and Engineering, Kyoto University"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326212416896","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70208833"},{"@type":"NRID","@value":"1000070208833"},{"@type":"ORCID","@value":"0000-0003-3030-1632"},{"@type":"CINII_AUTHOR_ID","@value":"DA13692235"},{"@type":"URI","@value":"https://ci.nii.ac.jp/author/DA13692235#entity"},{"@type":"URI","@value":"https://viaf.org/viaf/NII%7CDA13692235"},{"@type":"NRID","@value":"9000402135587"},{"@type":"NRID","@value":"9000405884240"},{"@type":"NRID","@value":"9000409619950"},{"@type":"NRID","@value":"9000409619954"},{"@type":"NRID","@value":"9000409620033"},{"@type":"NRID","@value":"9000405757440"},{"@type":"NRID","@value":"9000409500013"},{"@type":"NRID","@value":"9000411073179"},{"@type":"NRID","@value":"9000412315692"},{"@type":"NRID","@value":"9000399166780"},{"@type":"NRID","@value":"9000412335231"},{"@type":"NRID","@value":"9000409619935"},{"@type":"NRID","@value":"9000404527984"},{"@type":"NRID","@value":"9000285477793"},{"@type":"NRID","@value":"9000408682249"},{"@type":"NRID","@value":"9000409619943"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0012741"}],"foaf:name":[{"@language":"en","@value":"HIRATO Tetsuji"},{"@language":"ja","@value":"平藤 哲司"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Materials Science and Engineering, Kyoto University"},{"@language":"ja","@value":"京都大学大学院 工学研究科"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658561763328","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70109015"},{"@type":"NRID","@value":"1000070109015"}],"foaf:name":[{"@language":"en","@value":"AWAKURA Yasuhiro"},{"@language":"ja","@value":"粟倉 泰弘"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Materials Science and Engineering, Kyoto University"},{"@language":"ja","@value":"京都大学大学院 工学研究科"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09151869"},{"@type":"LISSN","@value":"09151869"},{"@type":"EISSN","@value":"18843409"},{"@type":"NDL_BIB_ID","@value":"000000066619"},{"@type":"ISSN","@value":"09151869"},{"@type":"NCID","@value":"AN1005202X"}],"prism:publicationName":[{"@language":"en","@value":"Journal of The Surface Finishing Society of Japan"},{"@language":"ja","@value":"表面技術"},{"@language":"en","@value":"Journal of The Surface Finishing Society of Japan"},{"@language":"ja","@value":"表面技術"},{"@language":"en","@value":"J. Surf. Finish Soc. Jpn."},{"@language":"en","@value":"Journal of the Surface Finishing Society of Japan"}],"dc:publisher":[{"@language":"en","@value":"The Surface Finishing Society of Japan"},{"@language":"ja","@value":"一般社団法人 表面技術協会"}],"prism:publicationDate":"2004","prism:volume":"55","prism:number":"5","prism:startingPage":"360","prism:endingPage":"365"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/6965618"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I6965618"}],"availableAt":"2004","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Cadmium%20Telluride","dc:title":"Cadmium Telluride"},{"@id":"https://cir.nii.ac.jp/all?q=Compound%20Semiconductor","dc:title":"Compound Semiconductor"},{"@id":"https://cir.nii.ac.jp/all?q=Solar%20Cells","dc:title":"Solar Cells"},{"@id":"https://cir.nii.ac.jp/all?q=Citrate%20Complex","dc:title":"Citrate Complex"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Cadmium Telluride"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Compound Semiconductor"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Solar Cells"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Citrate Complex"}]}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040282256756859776","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"14350399"},{"@type":"JGN","@value":"JP14350399"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14350399/"}],"notation":[{"@language":"ja","@value":"フォトアシスト電解によるCdTe薄膜太陽電池作製プロセスのソフト化"},{"@language":"en","@value":"Development of a Soft Process for CdTe Solar Cell using Photo-assisted Electrodeposition"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282256797747328","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"15760548"},{"@type":"JGN","@value":"JP15760548"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15760548/"}],"notation":[{"@language":"ja","@value":"塩基性水溶液からのフォトアシスト高速電析CdTe薄膜を用いた太陽電池の高効率化"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011144371624448","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electrodeposition of CdTe from Basic Aqueous Solutions Containing Ethylenediamine"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144825269248","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Control of Composition and Conduction Type of CdTe Film Electrodeposited from Ammonia Alkaline Aqueous Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145043760128","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Investigation of the influence of the electrodeposition potential on the optical, photoelectrochemical and structural properties of as-deposited CdTe"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145137800064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electrodeposition of CdTe Films from Ammoniacal Alkaline Aqueous Solution at Low Cathodic Overpotentials"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017674348612224","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Elektrochemische Untersuchungen zur Festkörperdiffusion: Adsorption und Legierungsbildung im System Gold/Cadmium"}]},{"@id":"https://cir.nii.ac.jp/crid/1360025430215689856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Mesoporous materials 2.0: innovations in metals and chalcogenides for future applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518875476736","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cathodic Deposition and Characterization of Metallic or Semiconducting Binary Alloys or Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981471264902400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoassisted Electrodeposition of CdTe Layer from Ammoniacal Basic Aqueous Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843425011840","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Molybdenum(VI) complex formation—8. 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