{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679098301440.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.70.699"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"4196813"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/4196813"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I4196813"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/70/3/699/56198414/bcsj.70.699.pdf"}},{"identifier":{"@type":"NAID","@value":"130004149732"}},{"identifier":{"@type":"NAID","@value":"10008917064"}}],"dc:title":[{"@language":"en","@value":"A Novel Sugar Sensing System Designed with a Cooperative Action of a Boronic-Acid-Appended Zinc Porphyrin and a 3-Pyridylboronic Acid Axial Ligand."},{"@language":"ja-Kana","@value":"Novel Sugar Sensing System Designed wit"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The cooperative action of two boronic acids is indispensable to the selective binding of saccharides in aqueous solution and the binding process can be spectrophotometrically monitored by using porphyrins as a chromophoric probe. It is not so easy, however, to synthesize porphyrins that satisfy these prerequisites, i.e., porphyrins bearing two appropriately-arranged boronic acid groups within a molecule. In this paper, we report that such a diboronic-acid-based porphyrin receptor can be easily designed by utilizing the self-assembling nature of a Zn(II) porphyrin and an axial ligand: That is, a mixture of boronic-acid-appended Zn(II) porphyrin (<b>1-Zn</b>) and 3-pyridylboronic acid (<b>2</b>) self-organizes to create a novel diboronic acid system for saccharide (S) recognition. Thus, the <b>1-Zn</b>·<b>2</b>·S ternary complexes give the CD spectral pattern inherent to saccharide absolute configuration. The present study is a new example for sugar sensing using a boronic acid-porphyrin self-assembly 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