{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679102465024.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.54.552"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/54/2/552/56102990/bcsj.54.552.pdf"}},{"identifier":{"@type":"NAID","@value":"130001987417"}}],"dc:title":[{"@language":"en","@value":"The stability of spherical micelles of dodecyltrimethylammonium chloride in aqueous NaCl solutions."}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Light scattering from solutions of dodecyltrimethylammonium chloride in water and 4.00 M (1 M=1 mol dm<SUP>−3</SUP>) NaCl has been measured at 25 °C, and the critical micelle concentrations and the micellar molecular weights have been determined. The critical micelle concentration, when combined with the previous data, follows the linear Corrin-Harkins equation over the whole range of NaCl concentrations. The micellar molecular weight remains low, <I>i.e.</I>, about 20000 even in the presence of 4.00 M NaCl, and the double-logarithmic relation between the micellar molecular weight and the ionic strength is represented by a straight line over the whole range of NaCl concentrations, when plotted together with the previous data. These results indicate that only spherical micelles are formed by dodecyltrimethylammonium chloride in the presence of added NaCl. The stability of the spherical micelle is attributed to the low degree of binding of Cl<SUP>−</SUP> on the cationic micelles."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410282679102465025","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020955419"}],"foaf:name":[{"@language":"en","@value":"Ozeki Sumio"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry, Faculty of Science, Nagoya University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679102465024","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020955423"}],"foaf:name":[{"@language":"en","@value":"Ikeda Shoichi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry, Faculty of Science, Nagoya University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"LISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@language":"en","@value":"Bulletin of the Chemical Society of Japan"},{"@language":"en","@value":"Bull. Chem. Soc. Jpn."}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"1981","prism:volume":"54","prism:number":"2","prism:startingPage":"552","prism:endingPage":"555"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/54/2/552/56102990/bcsj.54.552.pdf"}],"availableAt":"1981","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219104551296","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The Salt-Induced Sphere–Rod Transition of Micelles of 1-Tetradecylpyridinium Bromide in Aqueous NaBr Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219105171200","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Aggregate Structure of <i>N</i>-(Perfluoroalkylmethyl)-<i>N</i>,<i>N</i>,<i>N</i>-trimethylammonium Chloride by Transmission Electron Microscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146200755328","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Light scattering by ideal colloidal electrolytes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707353588992","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular dynamics study of the structure of anionic SDS, cationic DTAC, zwitterionic DDAO, and nonionic C12E8 spherical micelles in solution"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619052061056","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micellar Molecular Weights of Some Paraffin Chain Salts by Light Scattering"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619588970496","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Deduction of micellar shape from angular dissymmetry measurements of light scattered from aqueous sodium dodecyl sulfate solutions at high sodium chloride concentrations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567184121571968","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular dynamics study of the aggregation rate for zwitterionic dodecyldimethylamine oxide and cationic dodecyltrimethylammonium chloride micelles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095619856640","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micelle Shape from Dissymmetry Measurements."}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644031467264","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Adsorption of Dodecyldimethylammonium Chloride on Aqueous Surfaces of Concentrated NaCl Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644032741248","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A 14N NMR Relaxation Study of Aqueous Alkyltrimethylammonium Salt Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644033815424","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Size of Micelles of 1-Dodecylpyridinium Chloride in Aqueous NaCl Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644034178944","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Determination of the Critical Micelle Concentrations and Microviscosity with a Fluorescence Probe, Auramine"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518410477312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micelle molecular weight of dodecyldimethylammonium chloride in aqueous solutions, and the transition of micelle shape in concentrated NaCl solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521402403968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Intrinsic Viscosity and Flexibility of Rodlike Detergent Micelles"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699996054588160","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"COUNTERIONS AND MICELLE SIZE. 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