{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679106790656.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.78.1810"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"7469016"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/7469016"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I7469016"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/78/10/1810/56266266/bcsj.78.1810.pdf"}},{"identifier":{"@type":"NAID","@value":"130004151819"}},{"identifier":{"@type":"NAID","@value":"40006898733"}}],"dc:title":[{"@language":"en","@value":"Comparison of 8-Quinolinol Derivatives as Carriers for the Collection of Heavy Metals with Emulsion Globules"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"A series of 8-quinolinol derivatives has been examined as carriers for the collection of heavy metals with water-in-oil emulsion globules. The emulsion was prepared by dissolving 50 μmol of 8-quinolinol derivative and 30 mg of Span-80 (sorbitan monooleate) in 2.0 cm<SUP>3</SUP> of toluene and vigorously mixing with 0.50 cm<SUP>3</SUP> of 1.0 mol dm<SUP>−3</SUP> hydrochloric acid by ultrasonic irradiation. The resulting emulsion was gradually injected into 25 cm<SUP>3</SUP> of sample solution [containing 0.10 μg each of Fe(III), Co(II), Ni(II), Cu(II), Cd(II), and Pb(II)] at pH 4–8 and dispersed by stirring for 10 min as numerous tiny globules. When working with the parent compound, 8-quinolinol, Fe(III), Co(II), Ni(II), Cu(II), and Cd(II) were effectively transported through the toluene layer into the internal aqueous phase of the emulsion. However, Pb(II) was not transported at all. The derivatives of 5,7-dichloro-, 2-methyl-, and 5-octyloxymethyl-8-quinolinol were not useful for the simultaneous collection of the heavy metals. On the other hand, Kelex-100 (7-dodecenyl-8-quinolinol) allowed a nearly quantitative (more than 90%) collection of all the metals at pH 7–8. The effects of the substituents on the metal-collection efficiency are discussed in terms of the acidity and hydrophobicity of the carriers."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1030003658332288128","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20111833"},{"@type":"NRID","@value":"1000020111833"},{"@type":"NRID","@value":"9000253161655"},{"@type":"NRID","@value":"9000256025423"},{"@type":"NRID","@value":"9000257789674"},{"@type":"NRID","@value":"9000010055685"},{"@type":"NRID","@value":"9000020778354"},{"@type":"NRID","@value":"9000252808689"},{"@type":"NRID","@value":"9000253155498"},{"@type":"NRID","@value":"9000283295471"},{"@type":"NRID","@value":"9000001115697"},{"@type":"NRID","@value":"9000020773676"},{"@type":"NRID","@value":"9000253159465"},{"@type":"NRID","@value":"9000016409757"},{"@type":"NRID","@value":"9000256024166"},{"@type":"NRID","@value":"9000000090653"},{"@type":"NRID","@value":"9000253159033"},{"@type":"NRID","@value":"9000283300454"},{"@type":"NRID","@value":"9000257787816"},{"@type":"NRID","@value":"9000257787818"},{"@type":"NRID","@value":"9000001041117"},{"@type":"NRID","@value":"9000020795891"},{"@type":"NRID","@value":"9000252809603"},{"@type":"NRID","@value":"9000253155438"},{"@type":"NRID","@value":"9000253162307"},{"@type":"NRID","@value":"9000001672445"},{"@type":"NRID","@value":"9000020748768"},{"@type":"NRID","@value":"9000020655666"},{"@type":"NRID","@value":"9000258731334"},{"@type":"NRID","@value":"9000020727287"},{"@type":"NRID","@value":"9000256060234"},{"@type":"NRID","@value":"9000001714451"},{"@type":"NRID","@value":"9000253159402"},{"@type":"NRID","@value":"9000255701331"},{"@type":"NRID","@value":"9000257794945"},{"@type":"NRID","@value":"9000000086657"},{"@type":"NRID","@value":"9000001761445"},{"@type":"NRID","@value":"9000256896532"},{"@type":"NRID","@value":"9000021835829"},{"@type":"NRID","@value":"9000253154864"},{"@type":"NRID","@value":"9000257787634"},{"@type":"NRID","@value":"9000256059666"},{"@type":"NRID","@value":"9000257791885"},{"@type":"NRID","@value":"9000257789764"},{"@type":"NRID","@value":"9000253156594"},{"@type":"NRID","@value":"9000257790928"},{"@type":"NRID","@value":"9000021117126"},{"@type":"NRID","@value":"9000256024930"},{"@type":"NRID","@value":"9000001678682"},{"@type":"NRID","@value":"9000020702020"},{"@type":"NRID","@value":"9000020775605"},{"@type":"NRID","@value":"9000253158256"},{"@type":"NRID","@value":"9000253155285"},{"@type":"NRID","@value":"9000257787138"},{"@type":"NRID","@value":"9000015659361"},{"@type":"NRID","@value":"9000253154655"},{"@type":"NRID","@value":"9000256053685"},{"@type":"NRID","@value":"9000009771418"},{"@type":"NRID","@value":"9000364790412"},{"@type":"NRID","@value":"9000364790420"},{"@type":"NRID","@value":"9000364790271"},{"@type":"NRID","@value":"9000364790361"},{"@type":"NRID","@value":"9000364790452"},{"@type":"NRID","@value":"9000364790444"},{"@type":"NRID","@value":"9000364790633"},{"@type":"NRID","@value":"9000364790267"},{"@type":"NRID","@value":"9000364790545"},{"@type":"NRID","@value":"9000364790561"},{"@type":"NRID","@value":"9000364790349"},{"@type":"NRID","@value":"9000364790390"},{"@type":"NRID","@value":"9000364790565"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0045967"}],"foaf:name":[{"@language":"en","@value":"Hiraide Masataka"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679106790656","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000010055683"},{"@type":"NRID","@value":"9000256024165"}],"foaf:name":[{"@language":"en","@value":"Ohkouchi Ryohei"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751147267584","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"10362287"},{"@type":"NRID","@value":"1000010362287"},{"@type":"NRID","@value":"9000020948776"},{"@type":"NRID","@value":"9000010055681"},{"@type":"NRID","@value":"9000412173704"},{"@type":"NRID","@value":"9000018826641"},{"@type":"NRID","@value":"9000016409751"},{"@type":"NRID","@value":"9000256024164"},{"@type":"NRID","@value":"9000019189326"},{"@type":"NRID","@value":"9000021013390"},{"@type":"NRID","@value":"9000001672443"},{"@type":"NRID","@value":"9000259323738"},{"@type":"NRID","@value":"9000001480681"},{"@type":"NRID","@value":"9000256060232"},{"@type":"NRID","@value":"9000255701330"},{"@type":"NRID","@value":"9000256022221"},{"@type":"NRID","@value":"9000257794943"},{"@type":"NRID","@value":"9000283553331"},{"@type":"NRID","@value":"9000021117125"},{"@type":"NRID","@value":"9000000962976"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0157334"}],"foaf:name":[{"@language":"en","@value":"Matsumiya Hiroaki"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"LISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"},{"@type":"NDL_BIB_ID","@value":"000000118949"},{"@type":"ISSN","@value":"00092673"},{"@type":"NCID","@value":"AA00580132"}],"prism:publicationName":[{"@language":"en","@value":"Bulletin of the Chemical Society of Japan"},{"@language":"en","@value":"Bull. Chem. Soc. Jpn."}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"2005","prism:volume":"78","prism:number":"10","prism:startingPage":"1810","prism:endingPage":"1813"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/7469016"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I7469016"},{"@id":"https://academic.oup.com/bcsj/article-pdf/78/10/1810/56266266/bcsj.78.1810.pdf"}],"availableAt":"2005","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360574096225043712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Liquid distribution equilibria in the copper(II)—7-(1-vinyl- 3,3,6,6-tetramethylhexyl)-8-quinolinol 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8-quinolinol for graphite-furnace atomic absorption spectrometry"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368903247872","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Preconcentration of trace elements from seawater with silica-immobilized 8-hydroxyquinoline"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843386137472","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Selective collection of inorganic iron(III) colloids in water with oxine-impregnated water-in-oil emulsion"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320933758592","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Preconcentration of trace elements in sea water by complexation with 8-hydroxyquinoline and adsorption on C18 bonded silica gel"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270349030528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Polymer-mediated extraction of 8-quinolinolato metal chelates for the determination of metal ions in water with graphite furnace atomic absorption spectrometry"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204254537728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Graphite furnace atomic absorption spectrometric determination of ultra-trace levels of cobalt after solvent extraction using W/O/w emulsions as liquid surfactant membranes."}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204256135168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of hydrophobic substituent on solvent extraction of copper(II) with 5-alkyloxymethyl-8-quinolinol or 5-dialkylaminomethyl-8-quinolinol and separation of copper(II)."}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204354110080","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Simultaneous separation of traces of cobalt, nickel, and copper from an aluminum matrix with an emulsion containing mixed ligands for graphite-furnace atomic absorption spectrometry"},{"@language":"ja","@value":"混合配位子含有エマルションを用いるアルミニウムマトリックスからの微量コバルト，ニッケル，及び銅の同時分離／黒鉛炉原子吸光定量"},{"@language":"ja-Kana","@value":"コンゴウ ハイイシ ガンユウ エマルション オ モチイル アルミニウム マトリックス カラ ノ ビリョウ コバルト ニッケル オヨビ ドウ ノ ドウジ ブンリ コクエンロ ゲンシ キュウコウ テイリョウ"},{"@value":"混合配位子含有エマルションを用いるアルミニウムマトリックスからの微量コバルト,ニッケル,及び銅の同時分離/黒鉛炉原子吸光定量(<特集>若手研究者の初論文特集)"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205128239616","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Separation of Trace Metals from an Iron Matrix with Emulsion Globules for Inductively Coupled Plasma-Mass Spectrometry"},{"@language":"ja","@value":"エマルション分離‐誘導結合プラズマ質量分析法による高純度鉄中の微量不純物元素の定量"},{"@value":"エマルション分離--誘導結合プラズマ質量分析法による高純度鉄中の微量不純物元素の定量"},{"@language":"ja-Kana","@value":"エマルション ブンリ ユウドウ ケツゴウ プラズマ シツリョウ ブンセキホウ ニ ヨル コウジュンドテツ チュウ ノ ビリョウ フジュンブツ ゲンソ ノ テイリョウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679028936064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Separation of traces of copper(II) from iron(III) with 8-quinolinol-impregnated emulsion globules."},{"@language":"ja","@value":"８‐キノリノール含有エマルションを用いる鉄（ＩＩＩ）中の微量銅（ＩＩ）の分離"},{"@value":"8-キノリノール含有エマルションを用いる鉄(III)中の微量銅(II)の分離"},{"@language":"ja-Kana","@value":"8 キノリノール ガンユウ エマルション オ モチイル テツ 3 チュウ ノ ビリョウ ドウ 2 ノ ブンリ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679232802048","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Kinetic separation of nickel(II) and cobalt(II) with 5-octyloxymethyl-8-quinolinol by differential extraction."}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0025620937"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I7469016"},{"@type":"CROSSREF","@value":"10.1246/bcsj.78.1810"},{"@type":"CIA","@value":"40006898733"},{"@type":"CIA","@value":"130004151819"},{"@type":"OPENAIRE","@value":"doi_dedup___::b9d7ad0edaff93d86c902541b7b2b8a7"},{"@type":"CROSSREF","@value":"10.2355/tetsutohagane.93.85_references_DOI_HRyBPRF6eYdKHtvXaowBkHcMmxc"}]}