{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679110392192.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.44.726"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/44/3/726/55954546/bcsj.44.726.pdf"}},{"identifier":{"@type":"NAID","@value":"130001976202"}}],"dc:title":[{"@language":"en","@value":"<SUP>119</SUP>Sn-Mössbauer and <SUP>1</SUP>H- and <SUP>55</SUP>Mn-NMR Spectroscopic Studies of a Series of Compounds, R<SUB>3−<I>x</I></SUB>X<I><SUB>x</SUB></I>Sn-Mn(CO)<SUB>5</SUB>"},{"@value":"119Sn-Mössbauer and 1H- and 55Mn-NMR Spectroscopic Studies of a Series of Compounds, R3−<i>x</i>X<i>x</i>Sn-Mn(CO)5"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The electronic configuration around the tin atom for a series of organotin-manganese compounds, R<SUB>3−<I>x</I></SUB>X<I><SUB>x</SUB></I>Sn–Mn(CO)<SUB>5</SUB>, has been studied by <SUP>119</SUP>Sn-Mössbauer and <SUP>1</SUP>H- and <SUP>55</SUP>Mn-NMR spectroscopies. All the results obtained from these spectroscopic measurements show that the Mn(CO)<SUB>5</SUB> group is a stronger electron donor than the methyl, phenyl, or halogen group and that the tin-manganese bond prefers the sσ-character whereas the tin-halogen bond prefers the pσ-character. The relationship between the <SUP>55</SUP>Mn-chemical shift and the <SUP>119</SUP>Sn-isomer shift indicates some σ-electron withdrawal from manganese to tin. The phenyl group reduces the magnitude of quadrupole splitting more than the methyl group; this fact may be due to the mesomeric effect of the phenyl group through the π-bond between tin and ligand atoms. The relationship among the <SUP>119</SUP>Sn-isomer shift, the <SUP>1</SUP>H-chemical shift, and the coupling constant <I>J</I>(<SUP>119</SUP>Sn-<SUP>1</SUP>H(CH<SUB>3</SUB>)) is also shown."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410282679110392194","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020397963"}],"foaf:name":[{"@language":"en","@value":"Onaka Satoru"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry, Faculty of Science, The University of Tokyo"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679110392193","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020397969"}],"foaf:name":[{"@language":"en","@value":"Sasaki Yukiyoshi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry, Faculty of Science, The University of Tokyo"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679110392192","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020397975"}],"foaf:name":[{"@language":"en","@value":"Sano Hirotoshi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry, Faculty of Science, Ochanomizu University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"LISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@language":"en","@value":"Bulletin of the Chemical Society of Japan"},{"@language":"en","@value":"Bull. Chem. Soc. Jpn."}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"1971","prism:volume":"44","prism:number":"3","prism:startingPage":"726","prism:endingPage":"730"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/44/3/726/55954546/bcsj.44.726.pdf"}],"availableAt":"1971","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219099877504","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The Infrared Spectra and Normal Coordinate Treatments of X3M–Mn(CO)5(X=Cl, Br, and I; M=Si, Ge, and Sn). 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