{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679112391040.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.44.2750"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/44/10/2750/55951294/bcsj.44.2750.pdf"}},{"identifier":{"@type":"NAID","@value":"130001976537"}}],"dc:title":[{"@language":"en","@value":"Studies of Benzoylsulfene. IV. The Cycloaddition Reactions of Benzoylsulfene with Cinnamylideneamines"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The reaction of benzoylmethanesulfonyl chloride with cinnamylideneamines in the presence of triethylamine has been investigated; the products were identified, by spectral studies as well as by chemical transformations, as the corresponding Diels-Alder adducts of benzoylsulfene as a dienophile to the α,β-unsaturated anils, 2-substituted 5<I>H</I>, 6<I>H</I>-6-benzoyl-5-phenyl-1,2-thiazine 1,1-dioxides, in which the phenyl and benzoyl groups are quasi-equatorial and quasi-axial respectively. The cycloadducts underwent inversion, on treatment with sodium methoxide in methanol or with silica gel in chloroform, to the corresponding epimers, in which both the phenyl and benzoyl groups are quasi-equatorial."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410282679112391040","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020423247"}],"foaf:name":[{"@language":"en","@value":"Tsuge Otohiko"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Research Institute of Industrial Science, Kyushu University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679112391041","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020423254"}],"foaf:name":[{"@language":"en","@value":"Iwanami Sumio"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Research Institute of Industrial Science, Kyushu University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"LISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@language":"en","@value":"Bulletin of the Chemical Society of Japan"},{"@language":"en","@value":"Bull. Chem. Soc. Jpn."}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"1971","prism:volume":"44","prism:number":"10","prism:startingPage":"2750","prism:endingPage":"2755"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/44/10/2750/55951294/bcsj.44.2750.pdf"}],"availableAt":"1971","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360574095219108352","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ueber Condensationsderivate des Aethylendiamins"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644029374720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Cycloaddition Reactions of Benzoylsulfene with Anils"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855568934759808","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Über die Darstellung von β‐Lactamen Durch Anlagerung von Ketenen An Δ‐Thiazoline und Schiffsche Basen"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981468455865856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The proton resonance spectra and conformations of the prolines"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981468639701248","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<b>N.m.r. Coupling Constants and Conformations of Cycloölefins</b>"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262943495638144","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"V.—Studies in phototropy and thermotropy. Part VIII. Cinnamylideneamines. 2 : 4-Dihydroxybenzylideneamines"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270846039424","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Preparation of β-Ketosulfonyl Chlorides<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205148740224","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The Cycloaddition Reactions of Benzoylsulfene with Carbodiimides"},{"@value":"ベンゾイルスルフェンのカルボジイミド類への環化付加反応"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679113794304","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Studies of Acyl and Thioacyl Isocyanates. IX. The Cycloaddition Reactions of Benzoyl and Thiobenzoyl Isocyanates with Anils"},{"@value":"Studies of Acyl and Thioacyl Isocyanates. X. The Cycloaddition Reaction of Benzoyl and Thiobenzoyl Isocyanates with Benzaldazines"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0027707522"},{"@type":"CROSSREF","@value":"10.1246/bcsj.44.2750"},{"@type":"CIA","@value":"130001976537"},{"@type":"OPENAIRE","@value":"doi_dedup___::6ef3922918055800933b4d2d640c5cf2"},{"@type":"CROSSREF","@value":"10.1246/bcsj.45.2877_references_DOI_XBNNbJ10tTbJD4unTfGQX4x6VO4"}]}