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The transition temperatures are 558 K, 454 K and 142 K. With decreasing temperature, the symmetry of the crystal changes as follows: phase I, normal [<I>Pmcn</I>]; phase II, incommensurate [<B>q</B>=(1⁄3−δ)<B>c</B><SUP>*</SUP>]; phase III, commensurate [<I>P</I>2<SUB>1</SUB><I>cn</I>, <B>q</B>=<B>c</B><SUP>*</SUP>⁄3]; and phase IV, commensurate [<I>C</I>1<I>c</I>1, <B>q</B>=<B>a</B><SUP>*</SUP>⁄2+<B>b</B><SUP>*</SUP>⁄2+<B>c</B><SUP>*</SUP>⁄3]. Here the reciprocal vectors refer to the normal phase. In a narrow temperature range just above 142 K, the superreflection at (5/2 3/2 0) splits into two diffuse peaks. The general feature of the successive transitions is very similar to K<SUB>2</SUB>ZnCl<SUB>4</SUB>."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1030003658331776769","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20091209"},{"@type":"NRID","@value":"1000020091209"},{"@type":"NRID","@value":"9000002551396"},{"@type":"NRID","@value":"9000004565867"},{"@type":"NRID","@value":"9000006809110"},{"@type":"NRID","@value":"9000237878875"},{"@type":"NRID","@value":"9000254558402"},{"@type":"NRID","@value":"9000254560121"},{"@type":"NRID","@value":"9000254554708"},{"@type":"NRID","@value":"9000401854200"},{"@type":"NRID","@value":"9000401855725"},{"@type":"NRID","@value":"9000401865702"},{"@type":"NRID","@value":"9000401909410"},{"@type":"NRID","@value":"9000401881893"},{"@type":"NRID","@value":"9000401887473"},{"@type":"NRID","@value":"9000258197673"},{"@type":"NRID","@value":"9000258195139"},{"@type":"NRID","@value":"9000017243860"},{"@type":"NRID","@value":"9000016901683"},{"@type":"NRID","@value":"9000016874082"},{"@type":"NRID","@value":"9000243744511"},{"@type":"NRID","@value":"9000254569663"},{"@type":"NRID","@value":"9000254136621"},{"@type":"NRID","@value":"9000401889998"},{"@type":"NRID","@value":"9000398811393"},{"@type":"NRID","@value":"9000283260595"},{"@type":"NRID","@value":"9000237878877"},{"@type":"NRID","@value":"9000401845722"},{"@type":"NRID","@value":"9000401858333"},{"@type":"NRID","@value":"9000254562022"},{"@type":"NRID","@value":"9000003396766"},{"@type":"NRID","@value":"9000254566510"},{"@type":"NRID","@value":"9000401842109"},{"@type":"NRID","@value":"9000401846271"},{"@type":"NRID","@value":"9000401844953"},{"@type":"NRID","@value":"9000402058693"},{"@type":"NRID","@value":"9000401864362"},{"@type":"NRID","@value":"9000401881049"},{"@type":"NRID","@value":"9000258196787"},{"@type":"NRID","@value":"9000258195592"},{"@type":"NRID","@value":"9000258199700"},{"@type":"NRID","@value":"9000003406112"},{"@type":"NRID","@value":"9000402410332"},{"@type":"NRID","@value":"9000242847842"},{"@type":"NRID","@value":"9000242847837"},{"@type":"NRID","@value":"9000401844050"},{"@type":"NRID","@value":"9000402058738"},{"@type":"NRID","@value":"9000401863008"},{"@type":"NRID","@value":"9000401847944"},{"@type":"NRID","@value":"9000401884683"},{"@type":"NRID","@value":"9000016901366"},{"@type":"NRID","@value":"9000024334166"},{"@type":"NRID","@value":"9000246817193"},{"@type":"NRID","@value":"9000242855129"},{"@type":"NRID","@value":"9000254562863"},{"@type":"NRID","@value":"9000254136307"},{"@type":"NRID","@value":"9000401846069"},{"@type":"NRID","@value":"9000401847265"},{"@type":"NRID","@value":"9000401927055"},{"@type":"NRID","@value":"9000401895522"},{"@type":"NRID","@value":"9000401884817"},{"@type":"NRID","@value":"9000258193010"},{"@type":"NRID","@value":"9000402410329"},{"@type":"NRID","@value":"9000254558253"},{"@type":"NRID","@value":"9000254555963"},{"@type":"NRID","@value":"9000401894089"},{"@type":"NRID","@value":"9000401885917"},{"@type":"NRID","@value":"9000258197869"},{"@type":"NRID","@value":"9000002551370"},{"@type":"NRID","@value":"9000246817182"},{"@type":"NRID","@value":"9000254564071"},{"@type":"NRID","@value":"9000254134400"},{"@type":"NRID","@value":"9000254132610"},{"@type":"NRID","@value":"9000401856940"},{"@type":"NRID","@value":"9000401870405"},{"@type":"NRID","@value":"9000258186221"},{"@type":"NRID","@value":"9000258193680"},{"@type":"NRID","@value":"9000237878873"},{"@type":"NRID","@value":"9000246831583"},{"@type":"NRID","@value":"9000246831566"},{"@type":"NRID","@value":"9000401883298"},{"@type":"NRID","@value":"9000401890577"},{"@type":"NRID","@value":"9000258193389"},{"@type":"NRID","@value":"9000017243425"},{"@type":"NRID","@value":"9000243744514"},{"@type":"NRID","@value":"9000254132492"},{"@type":"NRID","@value":"9000401844664"},{"@type":"NRID","@value":"9000401869993"},{"@type":"NRID","@value":"9000401861015"},{"@type":"NRID","@value":"9000401857051"},{"@type":"NRID","@value":"9000401884270"},{"@type":"NRID","@value":"9000401888254"},{"@type":"NRID","@value":"9000401880085"},{"@type":"NRID","@value":"9000258196767"},{"@type":"NRID","@value":"9000016872473"},{"@type":"NRID","@value":"9000017243216"},{"@type":"NRID","@value":"9000020247668"},{"@type":"NRID","@value":"9000020146860"},{"@type":"NRID","@value":"9000242847816"},{"@type":"NRID","@value":"9000254570337"},{"@type":"NRID","@value":"9000254570561"},{"@type":"NRID","@value":"9000254139536"},{"@type":"NRID","@value":"9000401856317"},{"@type":"NRID","@value":"9000258198795"},{"@type":"NRID","@value":"9000016872058"},{"@type":"NRID","@value":"9000016874081"},{"@type":"NRID","@value":"9000016873952"},{"@type":"NRID","@value":"9000254567893"},{"@type":"NRID","@value":"9000254134807"},{"@type":"NRID","@value":"9000401857537"},{"@type":"NRID","@value":"9000401867031"},{"@type":"NRID","@value":"9000401866808"},{"@type":"NRID","@value":"9000401888022"},{"@type":"NRID","@value":"9000401893631"},{"@type":"NRID","@value":"9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