{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679160334976.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1143/jpsj.71.826"}},{"identifier":{"@type":"BIBCODE","@value":"2002JPSJ...71..826M"}},{"identifier":{"@type":"URI","@value":"http://journals.jps.jp/doi/pdf/10.1143/JPSJ.71.826"}},{"identifier":{"@type":"NAID","@value":"130004538140"}},{"identifier":{"@type":"NAID","@value":"210000104148"}}],"dc:title":[{"@language":"en","@value":"Estimation of .PI.d-Interactions in Organic Conductors Including Magnetic Anions."},{"@value":"Estimation of πd-Interactions in Organic Conductors Including Magnetic Anions"},{"@value":"Estimation of the πd-interactions in organic conductors including magnetic anions"},{"@value":"Estimation of πd-interaction in organic conductors including magnetic anions"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Magnetic interactions in organic conductors including magnetic anions, such as λ-(BETS)<FONT SIZE=\"-1\"><SUB>2</SUB></FONT>FeCl<FONT SIZE=\"-1\"><SUB>4</SUB></FONT> and κ-(BETS)<FONT SIZE=\"-1\"><SUB>2</SUB></FONT>FeX<FONT SIZE=\"-1\"><SUB>4</SUB></FONT> [X = Cl and Br], are estimated from intermolecular overlap integrals; the overlaps between anions afford J<FONT SIZE=\"-1\"><SUB>dd</SUB></FONT>, and those between anions and donors give J<FONT SIZE=\"-1\"><SUB>π d</SUB></FONT>. From this, the most stable spin alignments are decided, and such quantities as the Néel and Weiss temperatures, as well as the magnitude of spin polarization on the π-molecules are evaluated on the basis of the mean-field theory of πd-systems. The calculation is extended to several other πd-conductors, which are classified depending on the relative magnitudes of the direct dd- and indirect πd-interactions."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420001326222362880","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60174372"},{"@type":"NRID","@value":"1000060174372"},{"@type":"CINII_AUTHOR_ID","@value":"DA12634608"},{"@type":"URI","@value":"https://ci.nii.ac.jp/author/DA12634608#entity"},{"@type":"URI","@value":"https://viaf.org/viaf/NII%7CDA12634608"},{"@type":"NRID","@value":"9000241467422"},{"@type":"NRID","@value":"9000045659837"},{"@type":"NRID","@value":"9000364896784"},{"@type":"NRID","@value":"9000006722303"},{"@type":"NRID","@value":"9000242447791"},{"@type":"NRID","@value":"9000402088076"},{"@type":"NRID","@value":"9000402088077"},{"@type":"NRID","@value":"9000243743230"},{"@type":"NRID","@value":"9000003450756"},{"@type":"NRID","@value":"9000331904851"},{"@type":"NRID","@value":"9000346926361"},{"@type":"NRID","@value":"9000401964743"},{"@type":"NRID","@value":"9000401889153"},{"@type":"NRID","@value":"9000256017376"},{"@type":"NRID","@value":"9000256024735"},{"@type":"NRID","@value":"9000258196189"},{"@type":"NRID","@value":"9000267779549"},{"@type":"NRID","@value":"9000242848999"},{"@type":"NRID","@value":"9000401975354"},{"@type":"NRID","@value":"9000257703845"},{"@type":"NRID","@value":"9000258197034"},{"@type":"NRID","@value":"9000003392460"},{"@type":"NRID","@value":"9000401564604"},{"@type":"NRID","@value":"9000401894476"},{"@type":"NRID","@value":"9000401903993"},{"@type":"NRID","@value":"9000257703928"},{"@type":"NRID","@value":"9000257730583"},{"@type":"NRID","@value":"9000004600534"},{"@type":"NRID","@value":"9000401890030"},{"@type":"NRID","@value":"9000401902318"},{"@type":"NRID","@value":"9000258196180"},{"@type":"NRID","@value":"9000045664535"},{"@type":"NRID","@value":"9000267779485"},{"@type":"NRID","@value":"9000401969493"},{"@type":"NRID","@value":"9000401906167"},{"@type":"NRID","@value":"9000401897246"},{"@type":"NRID","@value":"9000257704464"},{"@type":"NRID","@value":"9000256021549"},{"@type":"NRID","@value":"9000019058518"},{"@type":"NRID","@value":"9000414105852"},{"@type":"NRID","@value":"9000003250261"},{"@type":"NRID","@value":"9000267779407"},{"@type":"NRID","@value":"9000346926568"},{"@type":"NRID","@value":"9000401989522"},{"@type":"NRID","@value":"9000401885936"},{"@type":"NRID","@value":"9000401890021"},{"@type":"NRID","@value":"9000401893553"},{"@type":"NRID","@value":"9000258197716"},{"@type":"NRID","@value":"9000257711693"},{"@type":"NRID","@value":"9000267779501"},{"@type":"NRID","@value":"9000409599792"},{"@type":"NRID","@value":"9000256027065"},{"@type":"NRID","@value":"9000258196480"},{"@type":"NRID","@value":"9000009810496"},{"@type":"NRID","@value":"9000401571725"},{"@type":"NRID","@value":"9000399852171"},{"@type":"NRID","@value":"9000256016748"},{"@type":"NRID","@value":"9000248231164"},{"@type":"NRID","@value":"9000045436183"},{"@type":"NRID","@value":"9000401884914"},{"@type":"NRID","@value":"9000401889833"},{"@type":"NRID","@value":"9000401888444"},{"@type":"NRID","@value":"9000000805714"},{"@type":"NRID","@value":"9000018233117"},{"@type":"NRID","@value":"9000267779465"},{"@type":"NRID","@value":"9000238934697"},{"@type":"NRID","@value":"9000238906404"},{"@type":"NRID","@value":"9000366513981"},{"@type":"NRID","@value":"9000401690028"},{"@type":"NRID","@value":"9000401566156"},{"@type":"NRID","@value":"9000401909306"},{"@type":"NRID","@value":"9000256020053"},{"@type":"NRID","@value":"9000256020586"},{"@type":"NRID","@value":"9000256022321"},{"@type":"NRID","@value":"9000401975879"},{"@type":"NRID","@value":"9000401967107"},{"@type":"NRID","@value":"9000401889099"},{"@type":"NRID","@value":"9000401906668"},{"@type":"NRID","@value":"9000401910872"},{"@type":"NRID","@value":"9000000821634"},{"@type":"NRID","@value":"9000019191347"},{"@type":"NRID","@value":"9000107353427"},{"@type":"NRID","@value":"9000003247661"},{"@type":"NRID","@value":"9000391396568"},{"@type":"NRID","@value":"9000346929935"},{"@type":"NRID","@value":"9000396109119"},{"@type":"NRID","@value":"9000258195430"},{"@type":"NRID","@value":"9000258193794"},{"@type":"NRID","@value":"9000045664712"},{"@type":"NRID","@value":"9000401883614"},{"@type":"NRID","@value":"9000255728291"},{"@type":"NRID","@value":"9000258200806"},{"@type":"NRID","@value":"9000258731296"},{"@type":"NRID","@value":"9000408500962"},{"@type":"NRID","@value":"9000267779529"},{"@type":"NRID","@value":"9000401968622"},{"@type":"NRID","@value":"9000401901281"},{"@type":"NRID","@value":"9000401889620"},{"@type":"NRID","@value":"9000401893546"},{"@type":"NRID","@value":"9000402087678"},{"@type":"NRID","@value":"9000402087677"},{"@type":"NRID","@value":"9000242856361"},{"@type":"NRID","@value":"9000247078145"},{"@type":"NRID","@value":"9000247078164"},{"@type":"NRID","@value":"9000346924694"},{"@type":"NRID","@value":"9000401972248"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0179464"}],"foaf:name":[{"@language":"en","@value":"Mori Takehiko"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679160334977","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000258196481"},{"@type":"NRID","@value":"9000401889621"}],"foaf:name":[{"@language":"en","@value":"Katsuhara Mao"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00319015"},{"@type":"LISSN","@value":"00319015"},{"@type":"EISSN","@value":"13474073"}],"prism:publicationName":[{"@language":"en","@value":"Journal of the Physical Society of Japan"},{"@language":"ja","@value":"Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ"},{"@language":"en","@value":"JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN"},{"@language":"en","@value":"JPSJ"},{"@language":"ja","@value":"ＪＰＳＪ"}],"dc:publisher":[{"@language":"en","@value":"THE PHYSICAL SOCIETY OF JAPAN"},{"@language":"ja","@value":"一般社団法人 日本物理学会"}],"prism:publicationDate":"2002","prism:volume":"71","prism:number":"3","prism:startingPage":"826","prism:endingPage":"844"},"reviewed":"false","url":[{"@id":"http://journals.jps.jp/doi/pdf/10.1143/JPSJ.71.826"}],"availableAt":"2002","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=organic%20conductor","dc:title":"organic conductor"},{"@id":"https://cir.nii.ac.jp/all?q=%CF%80d-interaction","dc:title":"πd-interaction"},{"@id":"https://cir.nii.ac.jp/all?q=mean%20field%20approximation","dc:title":"mean field approximation"},{"@id":"https://cir.nii.ac.jp/all?q=antiferromagnetism","dc:title":"antiferromagnetism"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050022089736387328","@type":"Article","resourceType":"学術雑誌論文(journal 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mathvariant=\"normal\">GaCl</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:math>"}]},{"@id":"https://cir.nii.ac.jp/crid/1050306506450065280","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Antiferromagnetic ordering and estimation of the exchange interaction in the π-d system λ-(BEDSe-TTF)2FeCl4 studied using 13C NMR"},{"@value":"Antiferromagnetic ordering and estimation of the exchange interaction in the \n<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\"><mml:mi>π</mml:mi><mml:mtext>−</mml:mtext><mml:mi>d</mml:mi></mml:math>\n system \n<mml:math 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xmlns:mml=\"http://www.w3.org/1998/Math/MathML\"><mml:mrow><mml:mi>λ</mml:mi></mml:mrow></mml:math>\n-type organic conductors studied by \n<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\"><mml:mmultiscripts><mml:mi>Ga</mml:mi><mml:mprescripts/><mml:none/><mml:mrow><mml:mn>69</mml:mn><mml:mo>,</mml:mo><mml:mn>71</mml:mn></mml:mrow></mml:mmultiscripts></mml:math>\n-NMR spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219104398848","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Molecular Magnets Based on Organic Charge Transfer Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219104628224","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Magnetic Properties of TTF-Type Charge Transfer Salts in the Mott Insulator Regime"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219104784384","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Magnetic Properties of Mixed Triangle-Based Ladder Magnets (C1TET-TTF)(FeBr4)1 - <i>x</i>(FeCl4)<i>x</i> (C1TET-TTF: 4,5-Ethylenedithio-4′,5′-bis(methylthio)tetrathiafulvalene)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219107772416","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"MOLECULAR ORBITAL (MO) THEORY FOR MAGNETICALLY INTERACTING ORGANIC COMPOUNDS. AB-INITIO MO CALCULATIONS OF THE EFFECTIVE EXCHANGE INTEGRALS FOR CYCLOPHANE-TYPE CARBENE DIMERS"}]},{"@id":"https://cir.nii.ac.jp/crid/1360003449880914816","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Crystal Structure and Physical Properties of π–<i>d</i>System κ-(BDH-TTP)<sub>2</sub>FeBr<sub>4</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360003449881288064","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Stabilization of Long-Range Order by Additional Anisotropic Spins in Two-Dimensional Isotropic Heisenberg Antiferromagnets —A Possible Model of an Organic Compound with Magnetic Anions—"}]},{"@id":"https://cir.nii.ac.jp/crid/1360003449881516928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effective Field Study of Canted Antiferromagnetic Insulating Phase in Magnetic Organic 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Review"}]},{"@id":"https://cir.nii.ac.jp/crid/1360005520018698368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effects of electron correlations and chemical pressures on superconductivity of \n<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\"><mml:msup><mml:mi>β</mml:mi><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math>\n-type organic compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360006529434560768","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Organic Conductors with Narrow Bandwidth Based on 2-(Pyran-4-ylidene)-1,3-dithiole"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011143880525312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Novel Antiferromagnetic Organic Superconductor κ-(BETS)<sub>2</sub>FeBr<sub>4</sub> [Where BETS = Bis(ethylenedithio)tetraselenafulvalene]"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011143914880256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"BETS as a source of molecular magnetic superconductors (BETS = bis(ethylenedithio)tetraselenafulvalene)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145852713600","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"New BETS Conductors with Magnetic Anions (BETS = bis(ethylenedithio)tetraselenafulvalene)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013168771043456","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Modern History of Organic Conductors: An Overview"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017282426142976","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Organic Molecular Conductors Based on Tetramethyl-TTP: 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