{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679161246592.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1143/jpsj.51.2628"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DyaL38XltFyntro%3D"}},{"identifier":{"@type":"BIBCODE","@value":"1982JPSJ...51.2628S"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"2458595"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/2458595"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I2458595"}},{"identifier":{"@type":"URI","@value":"http://journals.jps.jp/doi/pdf/10.1143/JPSJ.51.2628"}},{"identifier":{"@type":"NAID","@value":"210000090240"}},{"identifier":{"@type":"NAID","@value":"110001965953"}},{"identifier":{"@type":"NAID","@value":"130003897566"}}],"dc:title":[{"@language":"en","@value":"Crystal Structure and Phase Transition of Ag<SUB>3</SUB>SBr<SUB>0.5</SUB>I<SUB>0.5</SUB>"},{"@value":"Crystal Structure and Phase Transition of Ag3SBr0.5I0.5"},{"@language":"ja-Kana","@value":"Crystal Structure and Phase Transition"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The phase transition and the structure of a superionic conductor Ag<SUB>3</SUB>SBr<SUB>0.5</SUB>I<SUB>0.5</SUB> were investigated by specific heat, X-ray diffraction and dielectric measurements. The ordered phase (γ-phase) concerning the Ag distribution was discovered below 115 K. The transition heat and the entropy change for the γ-β phase transition are 0.19 kcal/mol. and 1.6 cal/mol. deg., respectively.<BR>X-ray structure analysis showed that the structure of the β-phase was isomorphous with that of β-Ag<SUB>3</SUB>SI and β-Ag<SUB>3</SUB>SBr, but the structure of the γ-phase was neither the same as γ-Ag<SUB>3</SUB>SI nor γ-Ag<SUB>3</SUB>SBr. The structure of γ-Ag<SUB>3</SUB>SBr<SUB>0.5</SUB>I<SUB>0.5</SUB> belongs to the orthorhombic system with the lattice constant <I>a</I>(\\simeq<I>b</I>\\simeq<I>c</I>)=9.637±0.002 Å at 99 K which is almost doubled the lattice constant of the β-phase at room temperature (<I>a</I>=4.842±0.003 Å). The structure and the phase transitions of the system Ag<SUB>3</SUB>SBr<I><SUB>x</SUB></I>I<SUB>1−<I>x</I></SUB> are discussed."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1030003658312632576","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"50005500"},{"@type":"NRID","@value":"1000050005500"},{"@type":"NRID","@value":"9000004595386"},{"@type":"NRID","@value":"9000254558338"},{"@type":"NRID","@value":"9000257856028"},{"@type":"NRID","@value":"9000256655794"},{"@type":"NRID","@value":"9000003289536"},{"@type":"NRID","@value":"9000006353299"},{"@type":"NRID","@value":"9000391848442"},{"@type":"NRID","@value":"9000350622256"},{"@type":"NRID","@value":"9000254131575"},{"@type":"NRID","@value":"9000392797336"},{"@type":"NRID","@value":"9000257843169"},{"@type":"NRID","@value":"9000256659840"},{"@type":"NRID","@value":"9000000234115"},{"@type":"NRID","@value":"9000002963041"},{"@type":"NRID","@value":"9000350652519"},{"@type":"NRID","@value":"9000020008644"},{"@type":"NRID","@value":"9000256072555"},{"@type":"NRID","@value":"9000008378911"},{"@type":"NRID","@value":"9000401845223"},{"@type":"NRID","@value":"9000392798027"},{"@type":"NRID","@value":"9000004425024"},{"@type":"NRID","@value":"9000364085717"},{"@type":"NRID","@value":"9000021984252"},{"@type":"NRID","@value":"9000256659289"},{"@type":"NRID","@value":"9000350651827"},{"@type":"NRID","@value":"9000004395173"},{"@type":"NRID","@value":"9000004400685"},{"@type":"NRID","@value":"9000391869808"},{"@type":"NRID","@value":"9000350618985"},{"@type":"NRID","@value":"9000256660343"},{"@type":"NRID","@value":"9000018343189"},{"@type":"NRID","@value":"9000020006519"},{"@type":"NRID","@value":"9000392792928"},{"@type":"NRID","@value":"9000255899438"},{"@type":"NRID","@value":"9000256655431"},{"@type":"NRID","@value":"9000256655697"},{"@type":"NRID","@value":"9000020602859"},{"@type":"NRID","@value":"9000401839763"},{"@type":"NRID","@value":"9000392797248"},{"@type":"NRID","@value":"9000256434646"},{"@type":"NRID","@value":"9000257843173"},{"@type":"NRID","@value":"9000256659669"},{"@type":"NRID","@value":"9000010663484"},{"@type":"NRID","@value":"9000021961254"},{"@type":"NRID","@value":"9000350587518"},{"@type":"NRID","@value":"9000255899341"},{"@type":"NRID","@value":"9000350620254"},{"@type":"NRID","@value":"9000257955693"},{"@type":"NRID","@value":"9000020124330"},{"@type":"NRID","@value":"9000392809604"},{"@type":"NRID","@value":"9000392793175"},{"@type":"NRID","@value":"9000392799384"},{"@type":"NRID","@value":"9000009898891"},{"@type":"NRID","@value":"9000350637923"},{"@type":"NRID","@value":"9000401847977"},{"@type":"NRID","@value":"9000257856033"},{"@type":"NRID","@value":"9000001201822"},{"@type":"NRID","@value":"9000392792942"},{"@type":"NRID","@value":"9000020123168"},{"@type":"NRID","@value":"9000392809383"},{"@type":"NRID","@value":"9000018355717"},{"@type":"NRID","@value":"9000254129429"},{"@type":"NRID","@value":"9000392791043"}],"foaf:name":[{"@language":"en","@value":"Sakuma 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Darstellung, Eigenschaften und Phasenverhältnisse von Ag<sub>3</sub>SBr und Ag<sub>3</sub>SJ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204178479360","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The Existence of New Phases in CuBrTe, CuITe and CuITe<SUB>2</SUB>"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204182991616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The Phase Transition and the Structures of Superionic Conductor Ag<SUB>3</SUB>SBr"},{"@value":"The Phase Transition and the Structures of Superionic Conductor Ag3SBr"},{"@language":"ja-Kana","@value":"Phase Transition and the Structures of"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204184539264","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A Structural Phase Transition in Superionic Conductor Ag<SUB>3</SUB>SI"},{"@value":"A Structural Phase Transition in Superionic Conductor Ag3SI"},{"@language":"ja-Kana","@value":"Structural Phase Transition in Superion"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204195092480","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Low-Temperature Phase in Superionic Conductor Ag<SUB>3</SUB>SBr<I><SUB>x</SUB></I>I<SUB>1−<I>x</I></SUB>"},{"@value":"Low-temperature phase in superionic conductor Ag3SBrxI1-x"},{"@value":"Low-Temperature Phase in Superionic Conductor Ag<sub>3</sub>SBr<sub><i>x</i></sub>I<sub>1-<i>x</i></sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679160840320","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Anharmonic Thermal Vibration of Cations in β-Ag<SUB>3</SUB>SI"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679166400000","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The Existence of the Order Phase in Superionic Conductor Ag<SUB>3</SUB>SI"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679174740736","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Crystal Structure of γ-Ag<SUB>3</SUB>SBr<SUB>0.6</SUB>I<SUB>0.4</SUB>"},{"@value":"Crystal structure of γ-Ag3SBr0.6I0.4"},{"@language":"ja-Kana","@value":"Crystal structure of g Ag3SBr0 6I0 4"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0019364536"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I2458595"},{"@type":"CROSSREF","@value":"10.1143/jpsj.51.2628"},{"@type":"CIA","@value":"130003897566"},{"@type":"CIA","@value":"110001965953"},{"@type":"CIA","@value":"210000090240"},{"@type":"OPENAIRE","@value":"doi_dedup___::ec939afc28fe77f9284af56918cd9c83"},{"@type":"CROSSREF","@value":"10.1143/jpsj.76.114603_references_DOI_OisKyWMwujrT8gR6CLd3qhSDJ0i"},{"@type":"CROSSREF","@value":"10.1143/jpsj.60.1136_references_DOI_OisKyWMwujrT8gR6CLd3qhSDJ0i"},{"@type":"CROSSREF","@value":"10.1143/jpsj.77.114601_references_DOI_OisKyWMwujrT8gR6CLd3qhSDJ0i"}]}