{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679233003136.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2116/analsci.18.585"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DC%2BD38XjvFGksrY%3D"}},{"identifier":{"@type":"PMID","@value":"12036130"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"6264062"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/6264062"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I6264062"}},{"identifier":{"@type":"URI","@value":"https://link.springer.com/content/pdf/10.2116/analsci.18.585.pdf"}},{"identifier":{"@type":"URI","@value":"https://link.springer.com/article/10.2116/analsci.18.585/fulltext.html"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/analsci/18/5/18_5_585/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004440606"}},{"identifier":{"@type":"NAID","@value":"10011313200"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Effect of Di-2-ethylhexyl Sodium Sulfosuccinate Reversed Micelles on the Iron-Tetrasulfonatophthalocyanine-Catalyzed Fluorogenic Oxidation Reaction of L-Tyrosine with Hydrogen Peroxide."}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The catalytic behavior of iron tetrasulfonatophthalocyanine (FeTSPc) for the oxidation reaction of <font size=-2>L</font>-tyrosine with H<sub>2</sub>O<sub>2</sub> in a di-2-ethylhexyl sodium sulfosuccinate (AOT) reversed-micellar system (AOT/cyclohexane) was studied. It was indicated that the reversed micelles could not only enhance the catalytic activity of FeTSPc, but could also increase the fluorescence intensity of the product. Factors that may influence the catalytic reaction, including the concentration of AOT, the cosolubilized water, temperature and pH, were further examined. The possibility of its analytical application was also tested. Experimental results show that the calibration graphs for the determinations of FeTSPc and H<sub>2</sub>O<sub>2</sub> under optimum conditions are linear over the range of 1.0 × 10<sup>-8</sup> - 1.0 × 10<sup>-6</sup> mol L<sup>-1</sup> and 0.0 - 3.0 × 10<sup>-6</sup> mol L<sup>-1</sup>, respectively, with detection limits of 1.1 × 10<sup>-9</sup> mol L<sup>-1</sup> and 3.1 × 10<sup>-9</sup> mol L<sup>-1</sup> for FeTSPc and H<sub>2</sub>O<sub>2</sub>, respectively."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410282679233003136","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001042192"},{"@type":"NRID","@value":"9000257790120"}],"foaf:name":[{"@language":"en","@value":"WEI Ling"}],"jpcoar:affiliationName":[{"@language":"en","@value":"The Key Laboratory of Analytical Science of MOE, Department of Chemistry, Xiamen University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679233003137","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001042195"},{"@type":"NRID","@value":"9000257790121"}],"foaf:name":[{"@language":"en","@value":"CHEN Xiao-Lan"}],"jpcoar:affiliationName":[{"@language":"en","@value":"The Key Laboratory of Analytical Science of MOE, Department of Chemistry, Xiamen University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679233003139","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001042198"},{"@type":"NRID","@value":"9000257790122"}],"foaf:name":[{"@language":"en","@value":"YANG Huang-Hao"}],"jpcoar:affiliationName":[{"@language":"en","@value":"The Key Laboratory of Analytical Science of MOE, Department of Chemistry, Xiamen University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679233003138","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001042201"},{"@type":"NRID","@value":"9000257790123"}],"foaf:name":[{"@language":"en","@value":"XU Jin-Gou"}],"jpcoar:affiliationName":[{"@language":"en","@value":"The Key Laboratory of Analytical Science of MOE, Department of Chemistry, Xiamen University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09106340"},{"@type":"LISSN","@value":"09106340"},{"@type":"EISSN","@value":"13482246"},{"@type":"NDL_BIB_ID","@value":"000000140209"},{"@type":"ISSN","@value":"09106340"},{"@type":"NCID","@value":"AA10500785"}],"prism:publicationName":[{"@language":"en","@value":"Analytical Sciences"},{"@language":"en","@value":"Anal. Sci."}],"dc:publisher":[{"@language":"en","@value":"The Japan Society for Analytical Chemistry"},{"@language":"ja","@value":"社団法人 日本分析化学会"}],"prism:publicationDate":"2002","prism:volume":"18","prism:number":"5","prism:startingPage":"585","prism:endingPage":"589"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/6264062"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I6264062"},{"@id":"https://link.springer.com/content/pdf/10.2116/analsci.18.585.pdf"},{"@id":"https://link.springer.com/article/10.2116/analsci.18.585/fulltext.html"},{"@id":"http://www.jstage.jst.go.jp/article/analsci/18/5/18_5_585/_pdf"}],"availableAt":"2002","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Analytical%20Chemistry","dc:title":"Analytical Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360292621224966528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rules for the regulation of enzyme activity in reserved micelles as illustrated by the conversion of apolar steroids by 20beta-hydroxysteroid dehydrogenase"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292621317033600","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The cross-linking of tyrosine by treatment with tetranitromethane"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095107035264","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Novel spectrofluorimetric method for the determination of thiamine with iron(III) tetrasulfonatophthalocyanine as a catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855568869611648","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalysis in water pools"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569579101440","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Study on Fluorometric Determination of Hydrogen Peroxide Catalyzed by Iron(III)-Tetrasulfonato-Phthalocyanine with Thiamine Hydrochloride as a Substrate"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570036307584","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micellar enzymology"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855571182525056","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Microemulsion Concept in Nonpolar Surfactant Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137043898608640","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Water A Comprehensive Treatise"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518817931776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Activation of enzymes by reversed micelles"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981468784089216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Application of iron-tetrasulfonatophthalocyanine as a new mimetic peroxidase in the determination of hydrogen peroxide with p-hydroxyphenylpropionic acid as a substrate"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418950851584","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Microheterogeneous Medium for Chemical (Enzymic) Reactions Based on a Colloidal Solution of Water in an Organic Solvent"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894341158400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Complexes Derived from Strong Field Ligands. XIX. Magnetic Properties of Transition Metal Derivatives of 4,4',4\",4'''-Tetrasulfophthalocyanine"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370732787712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Dramatic rate enhancement of the aquation of the tris(oxalato)chromate(III) anion by surfactant solubilized water in benzene"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845448788992","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micellar enzymology: its relation to membranology"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318712777344","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micellar solubilization of biopolymers in organic solvents. 5. Activity and conformation of .alpha.-chymotrypsin in isooctane-AOT reverse micelles"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320012176896","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micellar solubilization of enzymes in hydrocarbon solvents, enzymatic activity and spectroscopic properties of ribonuclease in n-octane"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793268232576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Micellar Enzymology: Superactivity of Enzymes in Reversed Micelles of Surfactants Solvated by Water/Organic Cosolvent Mixtures"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793492724224","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enzyme catalysis in water pools"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794863056768","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Interactions and reactions in reversed micellar systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270276365696","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Colloidal Solution of Water in Organic Solvents: a Microheterogeneous Medium for Enzymatic Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1570009749783256320","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570291224759965184","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570572699975085440","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570572699975086592","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570572699975089920","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570854174951794432","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570854174951799680","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571135649928507008","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571135649928509440","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571417124199149312","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571698599881929728","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572261549709633920","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572824498921399168","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572824499788771456","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572824499788774016","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974059416192","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974765479040","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974765480064","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974765482112","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974765483392","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573950398989461504","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573950399695612928","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573950399695616000","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573950399695617024","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1574231874672325888","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1574231874672328192","@type":"Article","relationType":["cites"]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0015678094"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I6264062"},{"@type":"CROSSREF","@value":"10.2116/analsci.18.585"},{"@type":"PUBMED","@value":"12036130"},{"@type":"CIA","@value":"10011313200"},{"@type":"CIA","@value":"130004440606"}]}