{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679366109952.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi.1987.858"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1972/1987/5/1987_5_858/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004158741"}}],"dc:title":[{"@language":"en","@value":"The Chlorination of Benzhydrols with Iron(III) Chloride"},{"@language":"ja","@value":"塩化鉄(III)を用いたベンズヒドロール類の塩素化"},{"@value":"Synthetic reaction using iron(III) chloride. II The chlorination of benzhydrols with iron(III) chloride."}],"description":[{"type":"abstract","notation":[{"@language":"en","@value":"In the equimolar reaction of benzhydrol and its derivatives with iron(III) chloride (FeCl<SUB>3</SUB>)in nitromethane, chlorination took place to yield chlorodiphenylmethanes with corresponding benzophenones as a by-products. The use of FeCl<SUB>3</SUB> with small amounts of tribenzylamine can bring about the increasing yield without the formation of benzophenones. Similarly, the yield of chlorodiphenylmethanes increased with elavated molar ratio (benzhydrols/FeCl<SUB>3</SUB>=1.5)."},{"@language":"ja","@value":"ベンズヒドロール〔1〕および二,三の誘導体を塩化鉄(III)(FeCl3)とともにニトロメタン中で加熱すると,クロロジフェニルメタン〔7〕と相当する誘導体が得られたが,同時にかなりの量のベンゾフェノン類が副生した。反応系の基質に対して10分の1molのトリベンジルアミンを添加すると,ベンゾフェノン類は生成せず〔7〕とその誘導体の収率が向上した。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410569923320141313","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256046577"}],"foaf:name":[{"@language":"en","@value":"YAMAMOTO Jiro"},{"@language":"ja","@value":"山本 二郎"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"鳥取大学工学部工業化学科"},{"@language":"en","@value":"Department of Industrial Chemistry, Faculty of Engineering, Tottori University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410569923320141312","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256046578"}],"foaf:name":[{"@language":"en","@value":"AKIMORI Shinji"},{"@language":"ja","@value":"秋森 伸治"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"鳥取大学工学部工業化学科"},{"@language":"en","@value":"Department of Industrial Chemistry, Faculty of Engineering, Tottori University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03694577"},{"@type":"EISSN","@value":"21850925"}],"prism:publicationName":[{"@language":"en","@value":"NIPPON KAGAKU KAISHI"},{"@language":"ja","@value":"日本化学会誌（化学と工業化学）"},{"@language":"en","@value":"Nippon Kagaku Kaishi"},{"@language":"ja","@value":"日化"},{"@language":"en","@value":"NIPPON KAGAKU KAISHI"},{"@language":"ja","@value":"日本化学会誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"1987-05-10","prism:volume":"1987","prism:number":"5","prism:startingPage":"858","prism:endingPage":"861"},"reviewed":"false","url":[{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1972/1987/5/1987_5_858/_pdf"}],"availableAt":"1987-05-10","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0021592471"},{"@type":"CROSSREF","@value":"10.1246/nikkashi.1987.858"},{"@type":"CIA","@value":"130004158741"}]}