{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679367170176.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi.2002.103"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DC%2BD38XntVCltw%3D%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"6046455"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/6046455"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I6046455"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi/2002/1/2002_1_103/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004053983"}},{"identifier":{"@type":"NAID","@value":"10007768990"}}],"dc:title":[{"@language":"en","@value":"Hydrogenation Reaction of CO<sub>2</sub> by Using FSM-16 and SiO<sub>2</sub> Supported Rh Catalysts"},{"@language":"ja","@value":"FSM-16およびSiO<sub>2</sub>担持ロジウム触媒を用いた二酸化炭素の水素化反応"},{"@value":"FSM-16およびSiO2担持ロジウム触媒を用いた二酸化炭素の水素化反応"},{"@language":"ja-Kana","@value":"FSM 16 オヨビ SiO2 タンジ ロジウム ショクバイ オ モチイタ 2サンカタンソ ノ スイソカ ハンノウ"},{"@value":"Hydrogenation Reaction of CO2 by Using FSM-16 and SiO2 Supported Rh Catalysts."}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Hydrogenation reaction of CO<sub>2</sub> over Rh/FSM-16 and Rh/SiO<sub>2</sub> catalysts prepared by impregnation method was carried out. The Rh/FSM-16 catalyst showed higher CO<sub>2</sub> conversion and turnover frequency than Rh/SiO<sub>2</sub> one. The main product was CO over SiO<sub>2</sub> supported catalyst, but it was CH<sub>4</sub> over FSM-16 supported one irrespective of reaction temperature. From the results of TEM and H<sub>2</sub> chemisorption, the mean particle size of Rh for Rh/FSM-16 was smaller than that for Rh/SiO<sub>2</sub>. The ratio of chemisorbed CO to chemisorbed H was smaller for Rh/FSM-16 catalyst than Rh/SiO<sub>2</sub> one. It was suggested that this finding reflected the difference in product selectivity of CO<sub>2</sub> hydrogenation between FSM-16 and SiO<sub>2</sub> supported Rh catalysts."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420564276177255424","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70356913"},{"@type":"NRID","@value":"1000070356913"},{"@type":"NRID","@value":"9000000006078"},{"@type":"NRID","@value":"9000253310772"},{"@type":"NRID","@value":"9000253311446"},{"@type":"NRID","@value":"9000255680020"},{"@type":"NRID","@value":"9000257734804"},{"@type":"NRID","@value":"9000252842506"},{"@type":"NRID","@value":"9000255680070"},{"@type":"NRID","@value":"9000255680072"},{"@type":"NRID","@value":"9000256051789"},{"@type":"NRID","@value":"9000257710416"},{"@type":"NRID","@value":"9000257732769"},{"@type":"NRID","@value":"9000256010932"},{"@type":"NRID","@value":"9000240539176"},{"@type":"NRID","@value":"9000000081227"},{"@type":"NRID","@value":"9000000966773"},{"@type":"NRID","@value":"9000253312009"},{"@type":"NRID","@value":"9000018232402"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0004957"}],"foaf:name":[{"@language":"en","@value":"KUSAMA Hitoshi"},{"@language":"ja","@value":"草間 仁"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"産業技術総合研究所"},{"@language":"en","@value":"National Institute of Advanced Industrial Science and Technology"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001206296987010","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000006734735"},{"@type":"NRID","@value":"9000255680073"},{"@type":"NRID","@value":"9000253311844"}],"foaf:name":[{"@language":"en","@value":"OKABE Kiyomi"},{"@language":"ja","@value":"岡部 清美"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"産業技術総合研究所"},{"@language":"en","@value":"National Institute of Advanced Industrial Science and Technology"}]},{"@id":"https://cir.nii.ac.jp/crid/1410001205812642692","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000003214220"},{"@type":"NRID","@value":"9000255680074"}],"foaf:name":[{"@language":"en","@value":"ARAKAWA Hironori"},{"@language":"ja","@value":"荒川 裕則"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"産業技術総合研究所"},{"@language":"en","@value":"National Institute of Advanced Industrial Science and Technology"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03694577"},{"@type":"EISSN","@value":"21850925"},{"@type":"NDL_BIB_ID","@value":"000000018251"},{"@type":"ISSN","@value":"03694577"},{"@type":"LISSN","@value":"03694577"},{"@type":"NCID","@value":"AN00186595"}],"prism:publicationName":[{"@language":"en","@value":"NIPPON KAGAKU KAISHI"},{"@language":"ja","@value":"日本化学会誌（化学と工業化学）"},{"@language":"en","@value":"Nippon Kagaku Kaishi"},{"@language":"ja","@value":"日化"},{"@language":"en","@value":"NIPPON KAGAKU KAISHI"},{"@language":"ja","@value":"日本化学会誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"2002","prism:volume":"2002","prism:number":"1","prism:startingPage":"103","prism:endingPage":"105"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/6046455"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I6046455"},{"@id":"https://www.jstage.jst.go.jp/article/nikkashi/2002/1/2002_1_103/_pdf"}],"availableAt":"2002","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219104256896","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Syntheses of Highly Ordered Mesoporous Materials, FSM-16, Derived from Kanemite"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093879890304","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Support effect on surface reaction rates in carbon monoxide hydrogenation over supported rhodium 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