{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679482179840.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1271/nogeikagaku1924.53.2_51"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DyaE1MXktFyntrg%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"2042919"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/2042919"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I2042919"}},{"identifier":{"@type":"NAID","@value":"130001226671"}},{"identifier":{"@type":"URI","@value":"https://search.jamas.or.jp/link/ui/1980036548"}}],"dc:title":[{"@value":"食用色素の光増感作用による油脂の酸化"},{"@language":"en","@value":"Photosensitized Oxidation of Oils with Food Colors"},{"@language":"ja-Kana","@value":"ショクヨウ シキソ ノ ヒカリ ゾウカン サヨウ ニヨル ユシ ノ サンカ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Eleven artificial food colorings approved by the Food Sanitation Law of Japan and fourteen of those prohibited were examined for their abilities to sensitize the photooxidation of methyl linoleate by incubating under illumination of visible light. Erythrosine, rose bengale, phloxine and eosine were found to act as a sensitizer of photooxidation and gave the 9-, 10-, 12- and 13-hydroperoxide isomers. The proportions of the 9- and 13-isomers were slightly higher than those of the 10- and 12-isomers. The isomeric compositions obtained suggest that these food colorings. generate singlet oxygen.<br> Twenty natural food coloring preparations were also examined for their abilities to sensitize the photooxidation, and two preparations containing chlorophyll were found to act as a sensitizer of photooxidation.<br> Photooxidation of triglycerides purified from safflower oil was accelerated with the higher concentration of chlorophyll. Although β-carotene inhibited photooxidation of triglycerides in the presence of chlorophyll, BHT had little influence as an inhibitor."},{"@value":"(1) 食品衛生法で食品に使用許可されている食用タール色素11種と使用禁止のタール色素14種について,リノール酸メチルの光増感酸化反応を検討した結果, erythrosine, phloxine, rose bengale, eosineに増感作用があることを確認した.<br> (2) 食用天然色素製剤20種についても,タール色素と同様に検討した結果, 2種の色素製剤に増感作用があることを確認し,これらはいずれもクロロフィル製剤であった<br> (3) クロロフィルの濃度が高くなるに従って,精製サフラワー油の光増感酸化反応が促進され,カロチンの濃度が高くなるに従って抑制が増加した.また,食品衛生法で規定されている範囲のBHTの濃度では抑制の効果は期待できなかった."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410853646151032832","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021899938"}],"foaf:name":[{"@language":"en","@value":"UMEHARA Tatsumi"},{"@language":"ja","@value":"梅原 龍海"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Osaka City Institute of Public Health and Environmental Sciences"},{"@language":"ja","@value":"大阪市立環境科学研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1410853646151032833","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021899941"}],"foaf:name":[{"@language":"en","@value":"TERAO Junji"},{"@language":"ja","@value":"寺尾 純二"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Research Institute for Food Science, Kyoto University"},{"@language":"ja","@value":"京都大学食糧科学研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658340491521","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70027176"},{"@type":"NRID","@value":"1000070027176"},{"@type":"NRID","@value":"9000021200329"},{"@type":"NRID","@value":"9000021897706"},{"@type":"NRID","@value":"9000302144227"},{"@type":"NRID","@value":"9000252805584"},{"@type":"NRID","@value":"9000002428521"},{"@type":"NRID","@value":"9000253151778"},{"@type":"NRID","@value":"9000253137449"},{"@type":"NRID","@value":"9000253137324"},{"@type":"NRID","@value":"9000253142475"},{"@type":"NRID","@value":"9000021921050"},{"@type":"NRID","@value":"9000021202348"},{"@type":"NRID","@value":"9000021149019"},{"@type":"NRID","@value":"9000020721184"},{"@type":"NRID","@value":"9000252805505"},{"@type":"NRID","@value":"9000253142290"},{"@type":"NRID","@value":"9000021137428"},{"@type":"NRID","@value":"9000020775275"},{"@type":"NRID","@value":"9000253144206"},{"@type":"NRID","@value":"9000253147970"},{"@type":"NRID","@value":"9000283229971"},{"@type":"NRID","@value":"9000021164599"},{"@type":"NRID","@value":"9000020138819"},{"@type":"NRID","@value":"9000022199964"},{"@type":"NRID","@value":"9000253137791"},{"@type":"NRID","@value":"9000253141203"},{"@type":"NRID","@value":"9000253140642"},{"@type":"NRID","@value":"9000253645051"},{"@type":"NRID","@value":"9000253644888"},{"@type":"NRID","@value":"9000022204270"},{"@type":"NRID","@value":"9000253143907"},{"@type":"NRID","@value":"9000253137489"},{"@type":"NRID","@value":"9000253138374"},{"@type":"NRID","@value":"9000253149215"},{"@type":"NRID","@value":"9000252878433"},{"@type":"NRID","@value":"9000021250679"},{"@type":"NRID","@value":"9000021898940"},{"@type":"NRID","@value":"9000253143096"},{"@type":"NRID","@value":"9000253138479"},{"@type":"NRID","@value":"9000253147091"},{"@type":"NRID","@value":"9000253643926"},{"@type":"NRID","@value":"9000020092006"},{"@type":"NRID","@value":"9000021128371"},{"@type":"NRID","@value":"9000021491931"},{"@type":"NRID","@value":"9000252804721"},{"@type":"NRID","@value":"9000253141217"},{"@type":"NRID","@value":"9000253141276"},{"@type":"NRID","@value":"9000253644920"},{"@type":"NRID","@value":"9000021129528"},{"@type":"NRID","@value":"9000020991229"},{"@type":"NRID","@value":"9000253645856"},{"@type":"NRID","@value":"9000021409601"},{"@type":"NRID","@value":"9000022201246"},{"@type":"NRID","@value":"9000021909080"},{"@type":"NRID","@value":"9000252805391"},{"@type":"NRID","@value":"9000253646251"},{"@type":"NRID","@value":"9000004166775"},{"@type":"NRID","@value":"9000021129424"},{"@type":"NRID","@value":"9000021254441"},{"@type":"NRID","@value":"9000022202299"},{"@type":"NRID","@value":"9000021874304"},{"@type":"NRID","@value":"9000253150140"},{"@type":"NRID","@value":"9000021250291"},{"@type":"NRID","@value":"9000021149001"},{"@type":"NRID","@value":"9000253143334"},{"@type":"NRID","@value":"9000021162968"},{"@type":"NRID","@value":"9000253147968"},{"@type":"NRID","@value":"9000253145819"},{"@type":"NRID","@value":"9000253149302"},{"@type":"NRID","@value":"9000253646370"},{"@type":"NRID","@value":"9000021149606"},{"@type":"NRID","@value":"9000252807222"},{"@type":"NRID","@value":"9000253143112"},{"@type":"NRID","@value":"9000253145547"},{"@type":"NRID","@value":"9000253645795"},{"@type":"NRID","@value":"9000008348588"},{"@type":"NRID","@value":"9000020006468"},{"@type":"NRID","@value":"9000021906909"},{"@type":"NRID","@value":"9000021929357"},{"@type":"NRID","@value":"9000253470457"},{"@type":"NRID","@value":"9000253138255"},{"@type":"NRID","@value":"9000253150111"},{"@type":"NRID","@value":"9000021899943"},{"@type":"NRID","@value":"9000253150336"},{"@type":"NRID","@value":"9000253644855"}],"foaf:name":[{"@language":"en","@value":"MATSUSHITA Setsuro"},{"@language":"ja","@value":"松下 雪郎"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Research Institute for Food Science, Kyoto University"},{"@language":"ja","@value":"京都大学食糧科学研究所"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00021407"},{"@type":"EISSN","@value":"18836844"},{"@type":"NDL_BIB_ID","@value":"000000018803"},{"@type":"ISSN","@value":"00021407"},{"@type":"LISSN","@value":"00021407"},{"@type":"NCID","@value":"AN00196191"}],"prism:publicationName":[{"@language":"en","@value":"Nippon Nōgeikagaku Kaishi"},{"@language":"ja","@value":"日本農芸化学会誌"},{"@language":"en","@value":"Journal of the agricultural chemical society of Japan"},{"@language":"ja","@value":"日本農芸化学会誌"}],"dc:publisher":[{"@language":"en","@value":"Japan Society for Bioscience, Biotechnology, and Agrochemistry"},{"@language":"ja","@value":"公益社団法人 日本農芸化学会"}],"prism:publicationDate":"1979","prism:volume":"53","prism:number":"2","prism:startingPage":"51","prism:endingPage":"56"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/2042919"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I2042919"},{"@id":"https://search.jamas.or.jp/link/ui/1980036548"}],"availableAt":"1979","dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0027907656"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I2042919"},{"@type":"CROSSREF","@value":"10.1271/nogeikagaku1924.53.2_51"},{"@type":"CIA","@value":"130001226671"}]}