{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679485693056.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1252/kakoronbunshu.23.188"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"4161077"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/4161077"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I4161077"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/kakoronbunshu1975/23/2/23_2_188/_pdf"}},{"identifier":{"@type":"NAID","@value":"10002767200"}}],"dc:title":[{"@language":"en","@value":"Influence of Platinum Ammine Complex Ion Species on the Preparation of Pre-Pelletized Zeolite Supported Platinum Catalysts."},{"@value":"造粒ゼオライトへの白金担持に及ぼす白金アンミン錯イオン種の影響"},{"@language":"ja-Kana","@value":"ゾウリュウ ゼオライト エ ノ ハッキン タンジ ニ オヨボス ハッキン アン"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Usually, platinum supported on zeolite catalyst is applied as a pelletized form from Pt-zeolite powder which is prepared by calcination and reduction of [Pt (NH<SUB>3</SUB>) <SUB>4</SUB>] ion supported on zeolite powder by ion exchange method. In this study, platinum was supported onto pre-pelletized zeolite by an ion exchange method using tetraammineplatinum (II) dichloride and hydroxopentaammineplatinum (IV) trichloride, hereafter referred to simply as Pt (II) ammine and Pt (IV) ammine, and their adsorption behavior and catalytic activity were compared.<BR>A substantial difference in the distribution of platinum into the pellets was observed between the platinum ammine complex ion species. Pt (IV) ammine resulted in egg shell-type supported catalysts. The behavior was studied as a diffusion control of Pt complex ion in the pellet from the results of the relations between Pt penetration depth and soaking time. The catalyst from Pt (IV) ammine showed lower temperature performance than Pt (II) ammine in the catalytic combustion of methane."},{"@value":"白金担持ゼオライト触媒は, 一般的に [Pt (NH<SUB>3</SUB>) <SUP>4</SUP>] イオンをイオン交換法で粉末ゼオライトに担持し, 焼成, 還元したものを造粒して用いている.本研究では, 先に造粒されたゼオライトを担体として, テトラアンミン白金 (II) ジクロライドと, ヒドロキソペンタアンミン白金 (IV) トリクロライド (以降, Pt (II) アンミン及びPt (IV) アンミンと称する) によってイオン交換担持する方法で触媒を調製し, その担持状態と触媒作用の比較を行った.<BR>Ptアンミン錯体種の違いにより, ゼオライト造粒体内部へのPt担持深度に大きな差が生じた.Pt (IV) アンミンは, egg shell型の担持特性を示すことが判った.この差は, 担持深度と時間の関係から白金錯イオンの粒内拡散過程が律速であるためと考察した.メタンの触媒燃焼試験では, Pt (IV) アンミンによる白金ゼオライト触媒の方が外層担持型のために低温燃焼特性を示した."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410282679485296256","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000137170"}],"foaf:name":[{"@language":"en","@value":"Tsurumi Kazunori"},{"@language":"ja","@value":"鶴見 和則"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Tanaka Kikinzoku Kogyo K. K., Technical Center"},{"@language":"ja","@value":"田中貴金属工業 (株) 技術開発センター"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679485693057","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Inoue Katsutoshi"},{"@language":"ja","@value":"井上 勝利"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Industrial Chemistry, Saga University"},{"@language":"ja","@value":"佐賀大学理工学部 工業化学科"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"0386216X"},{"@type":"LISSN","@value":"0386216X"},{"@type":"EISSN","@value":"13499203"},{"@type":"NDL_BIB_ID","@value":"000000026852"},{"@type":"ISSN","@value":"0386216X"},{"@type":"NCID","@value":"AN00037234"}],"prism:publicationName":[{"@language":"en","@value":"KAGAKU KOGAKU RONBUNSHU"},{"@language":"ja","@value":"化学工学論文集"},{"@language":"en","@value":"KAGAKU KOGAKU RONBUNSHU"},{"@language":"ja","@value":"化学工学論文集"}],"dc:publisher":[{"@language":"en","@value":"The Society of Chemical Engineers, Japan"},{"@language":"ja","@value":"公益社団法人 化学工学会"}],"prism:publicationDate":"1997","prism:volume":"23","prism:number":"2","prism:startingPage":"188","prism:endingPage":"193"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/4161077"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I4161077"},{"@id":"http://www.jstage.jst.go.jp/article/kakoronbunshu1975/23/2/23_2_188/_pdf"}],"availableAt":"1997","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Platinum%20Ammine%20Complex","dc:title":"Platinum Ammine Complex"},{"@id":"https://cir.nii.ac.jp/all?q=Zeolite","dc:title":"Zeolite"},{"@id":"https://cir.nii.ac.jp/all?q=Ion%20Exchange","dc:title":"Ion Exchange"},{"@id":"https://cir.nii.ac.jp/all?q=Platinum%20Supported%20Catalysts","dc:title":"Platinum Supported Catalysts"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1362544419128335232","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@value":"On the merits of partially impregnated catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1570291224276050688","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572543024089734912","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572824499081081856","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573387449019868032","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1574231876207805568","@type":"Article","relationType":["cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Use of Partially Impregnated Catalysts for Yield Enhancement in Nonisothermal Nonadiabatic Fixed Bed Reactors"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0004529431"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I4161077"},{"@type":"CROSSREF","@value":"10.1252/kakoronbunshu.23.188"},{"@type":"CIA","@value":"10002767200"},{"@type":"OPENAIRE","@value":"doi_dedup___::155d0ddd67fa906d98e85009e12816b0"}]}