{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679488007680.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.4164/sptj.50.28"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DC%2BC3sXjslGltrc%3D"}},{"identifier":{"@type":"NAID","@value":"130004696930"}}],"dc:title":[{"@language":"en","@value":"Modeling of Heterogeneous Chemical Reactions, Volume Reduction and Thermal Conduction during Pyrolysis of Woody Biomss in a Packed Bed"},{"@language":"ja","@value":"木質バイオマス充填層の熱分解における不均一反応，減容および熱伝導のモデリング"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"In this review, experimental and numerical studies for heterogeneous chemical reaction, volume reduction and thermal conduction during pyrolysis of biomass in a packed bed were reported. The yield of solid component could be reproduced by the calculation using the Millers reaction model even if the heating rate and the lignin content changed. The volume reduction of the packed bed for softwood was closely related with the pyrolysis and divided into three regions ; i） region of dehydration from biomass, ii） region of pyrolysis of cellulose and iii） region of pyrolysis of lignin. The reduction process was explained by not only the Miller's chemical reaction model with dependence of gas volume in the bed on the temperature but also the reversible first-order chemical reaction model. The calculated gas flow rate, taking into account the effect of the temperature distribution in the packed bed, agreed with the experimental results except for the flow rate due to tar decomposition. The time course of the average gas temperature in the packed bed was partly agreed with the calculation in taking account of porosity change. Furthermore, the temperature could be reproduced by the calculation with having the effect of volume reduction."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420282801211461504","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70293892"},{"@type":"NRID","@value":"1000070293892"},{"@type":"NRID","@value":"9000298258216"},{"@type":"NRID","@value":"9000256249652"},{"@type":"NRID","@value":"9000399375716"},{"@type":"NRID","@value":"9000399363178"},{"@type":"NRID","@value":"9000408892424"},{"@type":"NRID","@value":"9000256240410"},{"@type":"NRID","@value":"9000361696807"},{"@type":"NRID","@value":"9000392392820"},{"@type":"NRID","@value":"9000399363117"},{"@type":"NRID","@value":"9000402389709"},{"@type":"NRID","@value":"9000402389630"},{"@type":"NRID","@value":"9000411826182"},{"@type":"NRID","@value":"9000399362956"},{"@type":"NRID","@value":"9000392388969"},{"@type":"NRID","@value":"9000003738454"},{"@type":"NRID","@value":"9000403034731"},{"@type":"NRID","@value":"9000399363350"},{"@type":"NRID","@value":"9000021315212"},{"@type":"NRID","@value":"9000392383058"},{"@type":"NRID","@value":"9000402389571"},{"@type":"NRID","@value":"9000386207722"},{"@type":"NRID","@value":"9000392392811"},{"@type":"NRID","@value":"9000386207716"},{"@type":"NRID","@value":"9000398259532"},{"@type":"NRID","@value":"9000392388937"},{"@type":"NRID","@value":"9000403422392"},{"@type":"NRID","@value":"9000399363186"},{"@type":"NRID","@value":"9000408892421"},{"@type":"NRID","@value":"9000408892429"},{"@type":"NRID","@value":"9000386207904"},{"@type":"NRID","@value":"9000386207787"},{"@type":"NRID","@value":"9000411956686"},{"@type":"NRID","@value":"9000403422385"},{"@type":"NRID","@value":"9000392020233"},{"@type":"NRID","@value":"9000397683438"},{"@type":"NRID","@value":"9000411955515"},{"@type":"NRID","@value":"9000402390033"},{"@type":"NRID","@value":"9000265257936"},{"@type":"NRID","@value":"9000403422299"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0051983"}],"foaf:name":[{"@language":"en","@value":"Tanoue Ken-ichiro"},{"@language":"ja","@value":"田之上 健一郎"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658364114944","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90136135"},{"@type":"NRID","@value":"1000090136135"},{"@type":"NRID","@value":"9000241964278"},{"@type":"NRID","@value":"9000298257839"},{"@type":"NRID","@value":"9000392388970"},{"@type":"NRID","@value":"9000257780136"},{"@type":"NRID","@value":"9000256249648"},{"@type":"NRID","@value":"9000002358623"},{"@type":"NRID","@value":"9000021579057"},{"@type":"NRID","@value":"9000000407070"},{"@type":"NRID","@value":"9000283898986"},{"@type":"NRID","@value":"9000329419538"},{"@type":"NRID","@value":"9000256280616"},{"@type":"NRID","@value":"9000258663137"},{"@type":"NRID","@value":"9000283125854"},{"@type":"NRID","@value":"9000002049566"},{"@type":"NRID","@value":"9000021530570"},{"@type":"NRID","@value":"9000020305399"},{"@type":"NRID","@value":"9000021494643"},{"@type":"NRID","@value":"9000006162499"},{"@type":"NRID","@value":"9000021356521"},{"@type":"NRID","@value":"9000283899410"},{"@type":"NRID","@value":"9000256235724"},{"@type":"NRID","@value":"9000329419377"},{"@type":"NRID","@value":"9000021315182"},{"@type":"NRID","@value":"9000253503123"},{"@type":"NRID","@value":"9000392383059"},{"@type":"NRID","@value":"9000001350431"},{"@type":"NRID","@value":"9000020302758"},{"@type":"NRID","@value":"9000263042295"},{"@type":"NRID","@value":"9000326646761"},{"@type":"NRID","@value":"9000016412342"},{"@type":"NRID","@value":"9000004576189"},{"@type":"NRID","@value":"9000329419082"},{"@type":"NRID","@value":"9000329419071"},{"@type":"NRID","@value":"9000021991241"},{"@type":"NRID","@value":"9000020836605"},{"@type":"NRID","@value":"9000243905431"},{"@type":"NRID","@value":"9000254860172"},{"@type":"NRID","@value":"9000256237005"},{"@type":"NRID","@value":"9000256237885"},{"@type":"NRID","@value":"9000398783724"},{"@type":"NRID","@value":"9000003811132"},{"@type":"NRID","@value":"9000284633835"},{"@type":"NRID","@value":"9000020788126"},{"@type":"NRID","@value":"9000254357129"},{"@type":"NRID","@value":"9000256286374"},{"@type":"NRID","@value":"9000256249609"},{"@type":"NRID","@value":"9000398036811"},{"@type":"NRID","@value":"9000021421158"},{"@type":"NRID","@value":"9000020761491"},{"@type":"NRID","@value":"9000020759417"},{"@type":"NRID","@value":"9000386207717"},{"@type":"NRID","@value":"9000283899004"},{"@type":"NRID","@value":"9000256230646"},{"@type":"NRID","@value":"9000256245704"},{"@type":"NRID","@value":"9000253502287"},{"@type":"NRID","@value":"9000253504157"},{"@type":"NRID","@value":"9000258672244"},{"@type":"NRID","@value":"9000256249322"},{"@type":"NRID","@value":"9000256233960"},{"@type":"NRID","@value":"9000020148550"},{"@type":"NRID","@value":"9000020539651"},{"@type":"NRID","@value":"9000392388938"},{"@type":"NRID","@value":"9000258663152"},{"@type":"NRID","@value":"9000283125780"},{"@type":"NRID","@value":"9000256242564"},{"@type":"NRID","@value":"9000256245426"},{"@type":"NRID","@value":"9000340455071"},{"@type":"NRID","@value":"9000001414486"},{"@type":"NRID","@value":"9000344123057"},{"@type":"NRID","@value":"9000003813447"},{"@type":"NRID","@value":"9000003810855"},{"@type":"NRID","@value":"9000020672514"},{"@type":"NRID","@value":"9000386207905"},{"@type":"NRID","@value":"9000386207788"},{"@type":"NRID","@value":"9000258206127"},{"@type":"NRID","@value":"9000258674419"},{"@type":"NRID","@value":"9000256250615"},{"@type":"NRID","@value":"9000404096730"},{"@type":"NRID","@value":"9000392020236"},{"@type":"NRID","@value":"9000258663139"},{"@type":"NRID","@value":"9000258663130"},{"@type":"NRID","@value":"9000265258165"},{"@type":"NRID","@value":"9000006162372"},{"@type":"NRID","@value":"9000022012508"},{"@type":"NRID","@value":"9000345324401"},{"@type":"NRID","@value":"9000253503877"},{"@type":"NRID","@value":"9000265257937"},{"@type":"NRID","@value":"9000256238205"},{"@type":"NRID","@value":"9000256245500"},{"@type":"NRID","@value":"9000329419530"},{"@type":"NRID","@value":"9000346928038"},{"@type":"NRID","@value":"9000256231747"},{"@type":"NRID","@value":"9000256243710"},{"@type":"NRID","@value":"9000364841121"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0017147"}],"foaf:name":[{"@language":"en","@value":"Nishimura Tatsuo"},{"@language":"ja","@value":"西村 龍夫"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03866157"},{"@type":"LISSN","@value":"03866157"},{"@type":"EISSN","@value":"18837239"}],"prism:publicationName":[{"@language":"ja","@value":"粉体工学会誌"},{"@language":"en","@value":"Journal of the Society of Powder Technology, Japan"},{"@language":"ja","@value":"粉体工学会誌"},{"@language":"en","@value":"Funtai Kogakkaishi"},{"@language":"en","@value":"J. Soc. Powder Technol., Japan"},{"@language":"en","@value":"J. Soc. Powder Technolo, Japan"},{"@language":"ja","@value":"粉工誌"}],"dc:publisher":[{"@language":"en","@value":"The Society of Powder Technology, Japan"},{"@language":"ja","@value":"一般社団法人 粉体工学会"}],"prism:publicationDate":"2013","prism:volume":"50","prism:number":"1","prism:startingPage":"28","prism:endingPage":"38"},"reviewed":"false","availableAt":"2013","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Pyrolysis","dc:title":"Pyrolysis"},{"@id":"https://cir.nii.ac.jp/all?q=Woody%20biomass","dc:title":"Woody biomass"},{"@id":"https://cir.nii.ac.jp/all?q=Heterogeneous%20chemical%20reaction","dc:title":"Heterogeneous chemical reaction"},{"@id":"https://cir.nii.ac.jp/all?q=Volume%20reduction","dc:title":"Volume reduction"},{"@id":"https://cir.nii.ac.jp/all?q=Thermal%20conduction","dc:title":"Thermal conduction"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011145239444864","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A kinetic approach to the flash pyrolysis of biomass in a fluidized bed reactor"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619998107008","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Robert Herrick's Gift Trouble: Male Subjects "Trans-shifting" into Objects"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519732159232","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Experimental weight loss kinetics of wood pyrolysis under vacuum"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520077928064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Heat transfer and kinetics in the pyrolysis of shrinking biomass particle"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520765796608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetics of Primary Product Formation from Wood Pyrolysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993928050560","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Heat, momentum and mass transport through a shrinking biomass particle exposed to thermal radiation"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981471279971968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetic investigation of wood pyrolysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420601103360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetics of the pyrolysis of almond shells and almond shells impregnated with cobalt dichloride in a fluidized bed reactor and in a pyroprobe 100"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825893465610368","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetic Study of the Pyrolysis of Waste Wood"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894949522944","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Generalized Biomass Pyrolysis Model Based on Superimposed Cellulose, Hemicelluloseand Liqnin Kinetics"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318625887488","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Experimental and theoretical investigation of heat and mass transfer processes during wood pyrolysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319616164608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Review of the Vapor Phase Pyrolysis of Biomass Derived Volatile Matter"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793591943552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Flash pyrolysis kinetics of pine wood"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793834102912","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Modeling of heterogeneous chemical reactions caused in pyrolysis of biomass particles"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794967144576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Modeling chemical and physical processes of wood and biomass pyrolysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233268643589248","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Calculation of higher heating values of biomass fuels"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233268732127616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Modelling of the pyrolysis of biomass particles. Studies on kinetics, thermal and heat transfer effects"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269098966656","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Product compositions and kinetics in the rapid pyrolysis of sweet gum hardwood"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233271136544512","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effects of reactor severity on the gas-phase pyrolysis of cellulose- and kraft lignin-derived volatile matter"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204358550656","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Quantitative Prediction of Yield and Elemental Composition during Pyrolysis of Wood Biomass"},{"@value":"木質バイオマスの迅速熱分解における収率，チャー組成の予測"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206260963712","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Pyrolysis and Gasification Experiments of Biomass Under Elevated Pressure Condition"},{"@value":"加圧下におけるバイオマスの熱分解・ガス化特性"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679335423616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A Relationship between the Formation Rate of Solid Component and Volume Reduction of Packed Bed of Woody Biomass Particles during Pyrolysis"},{"@language":"ja","@value":"木質バイオマスの熱分解中に生じる減容過程と固形分生成速度との関係"},{"@language":"ja-Kana","@value":"キシツ バイオマス ノ ネツ ブンカイ チュウ ニ ショウジル ゲンヨウ カテイ ト コケイ ブン セイセイ ソクド ト ノ カンケイ"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:1001806215"},{"@type":"CROSSREF","@value":"10.4164/sptj.50.28"},{"@type":"CIA","@value":"130004696930"}]}