{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679530922112.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2343/geochemj.2.0477"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"028718798"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/028718798"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I028718798"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/geochemj/51/6/51_2.0477/_pdf"}},{"identifier":{"@type":"NAID","@value":"130006243141"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Cooling rate responsiveness of pyroxene geothermometry"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"<p>Geothermometry is fundamentally important to explore thermal processes within the Earth. An extremely popular geothermometer is the two-pyroxene thermometer, which is based on the temperature dependence of elemental partitioning between pyroxenes in a rock. This technique is ambiguous in terms of its responsiveness to change in the temperature of the system. We performed a numerical simulation of one-dimensional calcium diffusion in a clinopyroxene using Ca-Mg inter-diffusion coefficients. While applying the simulation to rock bodies with various temperature conditions and both heating and cooling rates, we investigated the time scale for the re-equilibration of elemental partitioning between enstatite and diopside. Those results enable us to evaluate the responsiveness of the two-pyroxene thermometer to change in temperature. For heating processes up to 1300°C, chemical zoning is not well developed at a heating rate faster than 10°C/yr because the duration for the diffusion is insufficient. In addition, at a heating rate 10<sup>–4</sup>°C/yr and >1200°C, the simulated diffusion profiles show no chemical zoning. This occurs because the chemical equilibrium between the pyroxenes is achieved via elemental diffusion. For cooling processes, a rock body will cool down to closure temperature before making an observable zoning at a high cooling rate such as 100°C/yr. In addition, no detectable zoning of Ca in clinopyroxene developed under high temperature (>~1100°C) and a slow cooling rate (<~10<sup>–4</sup>°C/yr) down to 700°C, properly reflecting temperature without detectable zoning of Ca. In contrast, for a rock body with detectable chemical zoning, it is difficult to ascertain the appropriate pyroxene temperature. Model diffusion profiles reflect conditions of changing temperature. Therefore, a graphic representation of diffusion profiles under various initial temperatures and different rates of temperature change would be useful to estimate the thermal history of rock bodies.</p>"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420282801189605376","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70456854"},{"@type":"NRID","@value":"1000070456854"},{"@type":"ORCID","@value":"0000-0002-1290-5160"},{"@type":"NRID","@value":"9000004602787"},{"@type":"NRID","@value":"9000399259201"},{"@type":"NRID","@value":"9000414373453"},{"@type":"NRID","@value":"9000347138313"},{"@type":"NRID","@value":"9000402796953"},{"@type":"NRID","@value":"9000414373566"},{"@type":"NRID","@value":"9000414373604"},{"@type":"NRID","@value":"9000400159939"},{"@type":"NRID","@value":"9000400158667"},{"@type":"NRID","@value":"9000380981651"},{"@type":"NRID","@value":"9000413247148"},{"@type":"NRID","@value":"9000411392556"},{"@type":"NRID","@value":"9000258434917"},{"@type":"NRID","@value":"9000415425607"},{"@type":"NRID","@value":"9000347137984"},{"@type":"NRID","@value":"9000408782995"},{"@type":"NRID","@value":"9000415352486"},{"@type":"NRID","@value":"9000406037479"},{"@type":"NRID","@value":"9000409896315"},{"@type":"NRID","@value":"9000415352830"},{"@type":"NRID","@value":"9000259311789"},{"@type":"NRID","@value":"9000414373532"},{"@type":"NRID","@value":"9000414373554"},{"@type":"NRID","@value":"9000380981217"},{"@type":"NRID","@value":"9000414373735"},{"@type":"NRID","@value":"9000396138834"},{"@type":"NRID","@value":"9000411392576"},{"@type":"NRID","@value":"9000408782759"},{"@type":"NRID","@value":"9000318561381"},{"@type":"NRID","@value":"9000019974105"},{"@type":"NRID","@value":"9000375860432"},{"@type":"NRID","@value":"9000414373738"},{"@type":"NRID","@value":"9000396139376"},{"@type":"NRID","@value":"9000406037501"},{"@type":"NRID","@value":"9000400158611"},{"@type":"NRID","@value":"9000318561282"},{"@type":"NRID","@value":"9000400162672"},{"@type":"NRID","@value":"9000375860141"},{"@type":"NRID","@value":"9000380981422"},{"@type":"NRID","@value":"9000375859881"},{"@type":"NRID","@value":"9000380980934"},{"@type":"NRID","@value":"9000376926611"},{"@type":"NRID","@value":"9000370280915"},{"@type":"NRID","@value":"9000414373713"},{"@type":"NRID","@value":"9000258434640"},{"@type":"NRID","@value":"9000380981290"},{"@type":"NRID","@value":"9000414227684"},{"@type":"NRID","@value":"9000414373558"},{"@type":"NRID","@value":"9000414373714"},{"@type":"NRID","@value":"9000400158442"},{"@type":"NRID","@value":"9000408782733"},{"@type":"NRID","@value":"9000259311800"},{"@type":"NRID","@value":"9000380981300"},{"@type":"NRID","@value":"9000375860383"},{"@type":"NRID","@value":"9000288834125"},{"@type":"NRID","@value":"9000380980713"},{"@type":"NRID","@value":"9000380981648"},{"@type":"NRID","@value":"9000414373440"},{"@type":"NRID","@value":"9000408783165"},{"@type":"NRID","@value":"9000415352412"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/hidemiishibashi"}],"foaf:name":[{"@language":"en","@value":"Ishibashi Hidemi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Geoscience, Faculty of Science, Shizuoka University"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751157343744","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"00378580"},{"@type":"NRID","@value":"1000000378580"},{"@type":"NRID","@value":"9000017048483"},{"@type":"NRID","@value":"9000250193355"},{"@type":"NRID","@value":"9000347135765"},{"@type":"NRID","@value":"9000392139328"},{"@type":"NRID","@value":"9000016835625"},{"@type":"NRID","@value":"9000375860657"},{"@type":"NRID","@value":"9000411392312"},{"@type":"NRID","@value":"9000258405343"},{"@type":"NRID","@value":"9000004618263"},{"@type":"NRID","@value":"9000017396247"},{"@type":"NRID","@value":"9000002103212"},{"@type":"NRID","@value":"9000392139097"},{"@type":"NRID","@value":"9000329011471"},{"@type":"NRID","@value":"9000347674415"},{"@type":"NRID","@value":"9000023607922"},{"@type":"NRID","@value":"9000290826149"},{"@type":"NRID","@value":"9000401434663"},{"@type":"NRID","@value":"9000258416954"},{"@type":"NRID","@value":"9000258222982"},{"@type":"NRID","@value":"9000243871241"},{"@type":"NRID","@value":"9000412200091"},{"@type":"NRID","@value":"9000408576829"},{"@type":"NRID","@value":"9000376926612"},{"@type":"NRID","@value":"9000258433435"},{"@type":"NRID","@value":"9000283783228"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/k_nishimura117"}],"foaf:name":[{"@language":"en","@value":"Nishimura Koshi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Natural Science Laboratory, Toyo University"}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276187253760","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60378536"},{"@type":"NRID","@value":"1000060378536"},{"@type":"ORCID","@value":"0000-0002-2636-1002"},{"@type":"NRID","@value":"9000004602771"},{"@type":"NRID","@value":"9000325000535"},{"@type":"NRID","@value":"9000018767685"},{"@type":"NRID","@value":"9000262360209"},{"@type":"NRID","@value":"9000412202662"},{"@type":"NRID","@value":"9000345265468"},{"@type":"NRID","@value":"9000272989527"},{"@type":"NRID","@value":"9000258403885"},{"@type":"NRID","@value":"9000001938956"},{"@type":"NRID","@value":"9000283905466"},{"@type":"NRID","@value":"9000257728913"},{"@type":"NRID","@value":"9000415425606"},{"@type":"NRID","@value":"9000004626931"},{"@type":"NRID","@value":"9000345303818"},{"@type":"NRID","@value":"9000317558325"},{"@type":"NRID","@value":"9000283905516"},{"@type":"NRID","@value":"9000283783556"},{"@type":"NRID","@value":"9000397705381"},{"@type":"NRID","@value":"9000409492106"},{"@type":"NRID","@value":"9000403267189"},{"@type":"NRID","@value":"9000367824711"},{"@type":"NRID","@value":"9000023607915"},{"@type":"NRID","@value":"9000397863253"},{"@type":"NRID","@value":"9000329431917"},{"@type":"NRID","@value":"9000020280343"},{"@type":"NRID","@value":"9000391664681"},{"@type":"NRID","@value":"9000329432027"},{"@type":"NRID","@value":"9000399564798"},{"@type":"NRID","@value":"9000396138441"},{"@type":"NRID","@value":"9000378067884"},{"@type":"NRID","@value":"9000410147751"},{"@type":"NRID","@value":"9000376926610"},{"@type":"NRID","@value":"9000397863149"},{"@type":"NRID","@value":"9000283908484"},{"@type":"NRID","@value":"9000258403893"},{"@type":"NRID","@value":"9000257725418"},{"@type":"NRID","@value":"9000410965010"},{"@type":"NRID","@value":"9000001397670"},{"@type":"NRID","@value":"9000303993324"},{"@type":"NRID","@value":"9000258405324"},{"@type":"NRID","@value":"9000018863421"},{"@type":"NRID","@value":"9000392872628"},{"@type":"NRID","@value":"9000283729302"},{"@type":"NRID","@value":"9000297496708"},{"@type":"NRID","@value":"9000242091153"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/jyamac"}],"foaf:name":[{"@language":"en","@value":"Yamamoto Junji"}],"jpcoar:affiliationName":[{"@language":"en","@value":"The Hokkaido University Museum"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00167002"},{"@type":"LISSN","@value":"00167002"},{"@type":"EISSN","@value":"18805973"},{"@type":"NDL_BIB_ID","@value":"000000128646"},{"@type":"ISSN","@value":"00167002"},{"@type":"NCID","@value":"AA00654975"}],"prism:publicationName":[{"@language":"en","@value":"GEOCHEMICAL JOURNAL"},{"@language":"ja","@value":"ＧＥＯＣＨＥＭＩＣＡＬ　ＪＯＵＲＮＡＬ"},{"@language":"en","@value":"Geochem. J."},{"@language":"ja","@value":"Ｇｅｏｃｈｅｍ．　Ｊ．"}],"dc:publisher":[{"@language":"en","@value":"GEOCHEMICAL SOCIETY OF JAPAN"},{"@language":"ja","@value":"一般社団法人日本地球化学会"}],"prism:publicationDate":"2017","prism:volume":"51","prism:number":"6","prism:startingPage":"457","prism:endingPage":"467"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/028718798"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I028718798"},{"@id":"https://www.jstage.jst.go.jp/article/geochemj/51/6/51_2.0477/_pdf"}],"availableAt":"2017","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=two-pyroxene%20thermometer","dc:title":"two-pyroxene thermometer"},{"@id":"https://cir.nii.ac.jp/all?q=mantle%20xenolith","dc:title":"mantle xenolith"},{"@id":"https://cir.nii.ac.jp/all?q=chemical%20zoning","dc:title":"chemical zoning"},{"@id":"https://cir.nii.ac.jp/all?q=cooling-rate%20responsiveness","dc:title":"cooling-rate responsiveness"},{"@id":"https://cir.nii.ac.jp/all?q=numerical%20simulation","dc:title":"numerical simulation"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040000781974732288","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"17K18794"},{"@type":"JGN","@value":"JP17K18794"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17K18794/"}],"notation":[{"@language":"ja","@value":"ピコモル炭素に適用できる新たな炭素同位体比測定法の開発"},{"@language":"en","@value":"Development of a new analysis method for isotope ratios of pico-mole carbon"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282256875821184","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"16H04079"},{"@type":"JGN","@value":"JP16H04079"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16H04079/"}],"notation":[{"@language":"ja","@value":"マントルウェッジ炭素の起源をさぐる"},{"@language":"en","@value":"The origin of mantle wedge carbon"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257286916480","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"26610136"},{"@type":"JGN","@value":"JP26610136"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-26610136/"}],"notation":[{"@language":"ja","@value":"ゼロ次元応力源を利用した鉱物の弾性特性測定法の開発"},{"@language":"en","@value":"A new analysis method for elastic property of mantle minerals"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050025031481019008","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Thermal structure beneath Far Eastern Russia inferred from geothermobarometric analyses of mantle xenoliths: Direct evidence for high geothermal gradient in backarc lithosphere"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145082641152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Diffusion in Minerals and Melts: Theoretical Background"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145869707136","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hawaiian mantle xenoliths and magmas: Composition and thermal character of the lithosphere"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292617915364736","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A model for the global variation in oceanic depth and heat flow with lithospheric age"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620848453760","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetic processes and thermal history of slowly cooling solids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567185955893888","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Melt-rich lithosphere-asthenosphere boundary inferred from petit-spot volcanoes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093509125120","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An experimental test of some geothermometer and geobaro-meter formulations for upper mantle peridotites with application to the ther-mobarometry of fertile lherzolite and garnet websterite"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574094502870400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Near conductive cooling rates in the upper-plutonic section of crust formed at the East Pacific Rise"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574094658410880","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Paleo-Moho depth determined from the pressure of CO2 fluid inclusions: Raman spectroscopic barometry of mantle- and crust-derived rocks"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096137372928","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Diffusion in Pyroxene, Mica and Amphibole"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045824487168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Comparative study of equilibrated and unequilibrated eucrites: Subsolidus thermal histories of Haraiya and Pasamonte"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470828063872","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stratigraphy of the lunar highland crust; depths of burial of lunar samples from cooling-rate studies"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470981941120","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Petrology of Mantle Wedge Lithosphere: New Data on Supra-Subduction Zone Peridotite Xenoliths from the Andesitic Avacha Volcano, Kamchatka"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981471071382400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Calcium self-diffusion in natural diopside single crystals"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944139600768","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Garnet-orthopyroxene and orthopyroxene-clinopyroxene relationships in simple and complex systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419755279232","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Calcium self-diffusion in diopside at high temperature: implications for transport properties"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544421353319296","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Diopside-enstatite equilibria at 850 degrees to 1400 degrees C, 5 to 35 kb"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825893473137920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chemical zoning of olivine in several pallasites"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825895680714240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Closure temperature in cooling geochronological and petrological systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825895738166400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pyroxene thermometry in simple and complex systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825896111280512","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Thermal history of iherzolite xenoliths—I. Petrology of iherzolite xenoliths from the ichinomegata crater, oga peninsula, northeast Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843719130368","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Noble gas isotopic compositions of mantle xenoliths from northwestern Pacific lithosphere"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319835369600","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rates of Thermal and Chemical Evolution of Magmas in a Cooling Magma Chamber: a Chronological and Theoretical Study on Basaltic and Andesitic Lavas from Rishiri Volcano, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320129273984","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ca–Mg diffusion in diopside: tracer and chemical inter-diffusion coefficients"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320687162624","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Diffusion closure temperature and age of a mineral with arbitrary extent of diffusion: theoretical formulation and applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795473284736","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The join Mg<sub>2</sub>Si<sub>2</sub>O<sub>6</sub>-CaMgSi<sub>2</sub>O<sub>6</sub>at 30 kilobars pressure and its application to pyroxenes from kimberlites"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795772435840","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Crystal and magma residence at Kilauea Volcano, Hawaii: 230Th–226Ra dating of the 1955 east rift eruption"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269111697536","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Closure Profiles in Cooling Systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269382145536","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Premelting and high-temperature diffusion of Ca in synthetic diopside: An increase of the cation mobility"}]},{"@id":"https://cir.nii.ac.jp/crid/2051433317043074688","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Lithological structure of western Pacific lithosphere reconstructed from mantle xenoliths in a petit-spot volcano"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:2003484169"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I028718798"},{"@type":"CROSSREF","@value":"10.2343/geochemj.2.0477"},{"@type":"CIA","@value":"130006243141"},{"@type":"KAKEN","@value":"PRODUCT-21514044"},{"@type":"KAKEN","@value":"PRODUCT-21741123"},{"@type":"KAKEN","@value":"PRODUCT-20848580"},{"@type":"KAKEN","@value":"PRODUCT-21111848"},{"@type":"OPENAIRE","@value":"doi_dedup___::6bcf46c6832e6ead89c3c6fd8321f4fb"},{"@type":"CROSSREF","@value":"10.1186/s40645-022-00518-y_references_DOI_DEPeL34is7FYPO47Xw5Nzt4DC4e"}]}