{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679545012736.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1252/jcej.36.788"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DC%2BD3sXmtV2ht70%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"6616603"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/6616603"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I6616603"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/jcej/36/7/36_7_788/_pdf"}},{"identifier":{"@type":"NAID","@value":"10013413769"}}],"dc:title":[{"@language":"en","@value":"A Study of Trimethylolethane Hydrate as a Phase Change Material."},{"@language":"ja-Kana","@value":"Study of Trimethylolethane Hydrate as a Phase Change Material"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The authors thought that Trimethylolethane (TME) hydrate had a great potential as a brand-new phase change material (PCM) due to organic hydrate, which was no flammable and no corrosive against metals. The present paper investigates the physical properties, phase separation and corrosiveness against metal about TME hydrate. The phase separation phenomena of TME hydrate in the stagnant melt was investigated on condition that the hydrate was used with a capsule type heat storage system. Furthermore, the corrosiveness of TME hydrate against metals had evaluated to ascertain the possibility of being used as a metal heat exchanger.<BR>It was confirmed that the melting point of TME hydrate is 302.8 K and heat of fusion is 218 kJ/kg. Moreover, basic physical properties were measured, such as specific heat capacity, thermal conductivity and density. It was found that TME hydrate can be used as a heat storage material without thickening agent under some concentration. The concentration of TME that occurs phase separation changes according to the melting temperature and retention time in a general system condition. Also, it was found that TME hydrate has no corrosiveness against aluminum, copper, carbon steel and stainless steel. It was suggested that metal heat exchangers made of copper and aluminum could be used for TME hydrate."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410001204566428033","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000498541"}],"foaf:name":[{"@language":"en","@value":"Kakiuchi Hiroyuki"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Science and Technology Research Center, Mitsubishi Chemical Corporation"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679545012737","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Yabe Masayoshi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Science and Technology Research Center, Mitsubishi Chemical Corporation"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679545012738","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Yamazaki Masanori"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Science and Technology Research Center, Mitsubishi Chemical Corporation"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219592"},{"@type":"EISSN","@value":"18811299"},{"@type":"NDL_BIB_ID","@value":"000000128548"},{"@type":"ISSN","@value":"00219592"},{"@type":"LISSN","@value":"00219592"},{"@type":"NCID","@value":"AA00709658"}],"prism:publicationName":[{"@language":"en","@value":"JOURNAL OF CHEMICAL ENGINEERING OF JAPAN"},{"@language":"en","@value":"J. Chem. Eng. Japan /  JCEJ"},{"@language":"en","@value":"jcej"},{"@language":"en","@value":"J. Chem. Eng. Japan"},{"@language":"en","@value":"Journal of Chemical Engineering of Japan"}],"dc:publisher":[{"@language":"en","@value":"The Society of Chemical Engineers, Japan"},{"@language":"ja","@value":"公益社団法人 化学工学会"}],"prism:publicationDate":"2003","prism:volume":"36","prism:number":"7","prism:startingPage":"788","prism:endingPage":"793"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/6616603"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I6616603"},{"@id":"http://www.jstage.jst.go.jp/article/jcej/36/7/36_7_788/_pdf"}],"availableAt":"2003","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Latent%20Heat%20Storage","dc:title":"Latent Heat Storage"},{"@id":"https://cir.nii.ac.jp/all?q=Phase%20Change%20Material","dc:title":"Phase Change Material"},{"@id":"https://cir.nii.ac.jp/all?q=Phase%20separation","dc:title":"Phase separation"},{"@id":"https://cir.nii.ac.jp/all?q=Trimethylolethane","dc:title":"Trimethylolethane"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360285707184019968","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ammonia alum hydrate-based phase change materials for effective use of excess exhaust heat from gas engines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292618788150912","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Thermal energy storage for solar heating and off-peak air conditioning"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620325334144","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Biotechnology Patent Pitfalls"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292621470355968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Feasibility of trichlorofluoromethane (CCl3F, R11) 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surfactant"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204569186688","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Molar Ratio of Counter-Ions to Cationic Surfactants Treating Trimethylolethane Hydrate Slurries"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204666447616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Heat capacity, heat of transition, and thermal conductivity of pentaerythritol and its slurry."},{"@language":"ja","@value":"ペンタエリトリトールとそのスラリーの熱容量、 転移熱、 および熱伝導率"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679484610304","@type":"Article","relationType":["references","cites"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of New PCM using Sodium Acetate Trihydrate and Characteristic Evaluation of Capsule Type Heat Storage 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