{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679545110784.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1252/jcej.09we054"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"10612047"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/10612047"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I10612047"}},{"identifier":{"@type":"URI","@value":"http://www.jstage.jst.go.jp/article/jcej/43/1/43_09we054/_pdf"}},{"identifier":{"@type":"NAID","@value":"10027152411"}}],"dc:title":[{"@language":"en","@value":"Continuous Toluene Hydrogenation System Using Compressed Carbon Dioxide"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The effect of the addition of compressed carbon dioxide in continuous hydrogenation of toluene has been evaluated with process simulation software and tested with a fixed-bed reactor. The simulation results show that the temperature rise is significantly suppressed in the presence of compressed carbon dioxide and that the equilibrium conversion of toluene (toluene/hydrogen = 1/3) reaches 99.9%, whereas around 60% in the absence of carbon dioxide. Experimental results show that the continuous hydrogenation of toluene (toluene/hydrogen/carbon dioxide = 1/3.1/31, inlet temperature: 20 °C, outlet temperature: <70 °C, and total pressure: 11 MPa) over activated carbon-supported rhodium catalysts proceeds without deactivation. The conversion of toluene reaches 99% and methylcyclohexane is the only product detected."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420845751140703616","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"50415733"},{"@type":"NRID","@value":"1000050415733"},{"@type":"KAKEN_RESEARCHERS","@value":"50415377"},{"@type":"NRID","@value":"9000006968939"},{"@type":"NRID","@value":"9000257731820"},{"@type":"NRID","@value":"9000257729703"},{"@type":"NRID","@value":"9000258691413"},{"@type":"NRID","@value":"9000257723524"},{"@type":"NRID","@value":"9000000536294"},{"@type":"NRID","@value":"9000283777591"},{"@type":"NRID","@value":"9000283777364"},{"@type":"NRID","@value":"9000258691213"},{"@type":"NRID","@value":"9000258689968"},{"@type":"NRID","@value":"9000258679803"},{"@type":"NRID","@value":"9000258690327"},{"@type":"NRID","@value":"9000240539232"},{"@type":"NRID","@value":"9000258690474"},{"@type":"NRID","@value":"9000257729416"},{"@type":"NRID","@value":"9000018659726"},{"@type":"NRID","@value":"9000248231109"},{"@type":"NRID","@value":"9000258690677"},{"@type":"NRID","@value":"9000257730620"},{"@type":"NRID","@value":"9000347146799"},{"@type":"NRID","@value":"9000258691105"},{"@type":"NRID","@value":"9000258689053"},{"@type":"NRID","@value":"9000257725717"},{"@type":"NRID","@value":"9000021470377"},{"@type":"NRID","@value":"9000258689770"},{"@type":"NRID","@value":"9000347087688"},{"@type":"NRID","@value":"9000257734720"},{"@type":"NRID","@value":"9000257733926"},{"@type":"NRID","@value":"9000257726144"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0120878"}],"foaf:name":[{"@language":"en","@value":"Hiyoshi 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Chem. Eng. Japan /  JCEJ"},{"@language":"en","@value":"jcej"},{"@language":"en","@value":"J. Chem. Eng. Japan"},{"@language":"en","@value":"Journal of Chemical Engineering of Japan"}],"dc:publisher":[{"@language":"en","@value":"The Society of Chemical Engineers, Japan"},{"@language":"ja","@value":"公益社団法人 化学工学会"}],"prism:publicationDate":"2010","prism:volume":"43","prism:number":"1","prism:startingPage":"82","prism:endingPage":"86"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/10612047"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I10612047"},{"@id":"http://www.jstage.jst.go.jp/article/jcej/43/1/43_09we054/_pdf"}],"availableAt":"2010","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Carbon%20Dioxide%20Solvent","dc:title":"Carbon Dioxide Solvent"},{"@id":"https://cir.nii.ac.jp/all?q=Continuous%20Hydrogenation","dc:title":"Continuous Hydrogenation"},{"@id":"https://cir.nii.ac.jp/all?q=Toluene","dc:title":"Toluene"},{"@id":"https://cir.nii.ac.jp/all?q=Methylcyclohexane","dc:title":"Methylcyclohexane"},{"@id":"https://cir.nii.ac.jp/all?q=Process%20Simulation","dc:title":"Process Simulation"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011143800233600","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalytic Hydrogenation in Supercritical CO<sub>2</sub>:  Kinetic Measurements in a Gradientless Internal-Recycle Reactor"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169064084608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enhanced Selectivity to Decalin in Naphthalene Hydrogenation under Supercritical Carbon Dioxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169064601216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Particle-size Effects of Activated Carbon-supported Rhodium Catalysts on 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