The Convenient and Useful Esterification of Bulky Tertiary Alcohols Using Strontium Compounds

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  • Miyoshi Norikazu
    Department of Chemistry, Faculty of Integrated Arts and Sciences, University of Tokushima
  • Asaoka Masashi
    Department of Chemistry, Faculty of Integrated Arts and Sciences, University of Tokushima
  • Miyazaki Yasuaki
    Department of Chemistry, Faculty of Integrated Arts and Sciences, University of Tokushima
  • Tajima Takahiro
    Department of Chemistry, Faculty of Integrated Arts and Sciences, University of Tokushima
  • Kikuchi Makoto
    Department of Chemistry, Faculty of Integrated Arts and Sciences, University of Tokushima
  • Wada Makoto
    Department of Chemistry, Faculty of Integrated Arts and Sciences, University of Tokushima

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Abstract

Various esters reacted with metallic strontium and alkyl iodides to give dialkylated products, followed by adding acid chlorides or acid anhydrides to afford the corresponding bulky tert-alcohol esters in good yields.

Journal

  • Chemistry Letters

    Chemistry Letters 41 (1), 35-36, 2012

    The Chemical Society of Japan

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