A Single-component Molecular Conductor with Metal–Metal Bonding, [Pd(hfdt)<sub>2</sub>] (hfdt: bis(trifluoromethyl)tetrathiafulvalenedithiolate)
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- Zhou Biao
- Department of Chemistry, College of Humanities and Sciences, Nihon University
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- Ogura Satomi
- Department of Chemistry, College of Humanities and Sciences, Nihon University
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- Liu Qi Zhi
- Department of Chemistry, College of Humanities and Sciences, Nihon University
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- Kasai Hidetaka
- Faculty of Pure and Applied Science, Center for Integrated Research in Fundamental Science and Engineering (CiRfSE), and Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), University of Tsukuba
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- Nishibori Eiji
- Faculty of Pure and Applied Science, Center for Integrated Research in Fundamental Science and Engineering (CiRfSE), and Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), University of Tsukuba
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- Kobayashi Akiko
- Department of Chemistry, College of Humanities and Sciences, Nihon University
Bibliographic Information
- Other Title
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- A Single-component Molecular Conductor with Metal–Metal Bonding, [Pd(hfdt)2] (hfdt: bis(trifluoromethyl)tetrathiafulvalenedithiolate)
Abstract
A new single-component palladium complex, [Pd(hfdt)2] (hfdt: bis(trifluoromethyl)tetrathiafulvalenedithiolate), was prepared. Single-crystal structure analysis showed that [Pd(hfdt)2] is a rare case of single-component molecular conductor possessing metal–metal bonding. The observed non-magnetic susceptibility behavior of [Pd(hfdt)2] originates from its dimeric structure. The semiconducting behavior of [Pd(hfdt)2] is consistent with the result of the density functional theory (DFT) band structure calculations.
Journal
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- Chemistry Letters
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Chemistry Letters 45 (3), 303-305, 2016
The Chemical Society of Japan
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Details
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- CRID
- 1390282679564524544
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- NII Article ID
- 130005132157
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- ISSN
- 13480715
- 03667022
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed