Absorption- and Pressure-induced Structural Transition Exhibiting V-shaped Density Change in Imidazolium-based Ionic Liquid + CO<sub>2</sub> System
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- Okumura Shuhei
- Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
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- Ushio Masayoshi
- Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
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- Oishi Akina
- Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
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- Nishikawa Keiko
- Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
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- Morita Takeshi
- Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
Bibliographic Information
- Other Title
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- Absorption- and Pressure-induced Structural Transition Exhibiting V-shaped Density Change in Imidazolium-based Ionic Liquid + CO2 System
Abstract
The density of ionic liquid (IL) + CO2 systems was measured by X-ray absorption method and excess molar volume was evaluated to investigate the volumetric behavior under a CO2 absorption process up to 20 MPa. A V-shaped density plot was observed, and three types of expanded/compressed trends were classified based on the excess molar volume of the IL. The volumetric behavior of the IL strongly depends on the CO2 amount absorbed in the IL’s cavities.
Journal
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- Chemistry Letters
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Chemistry Letters 44 (7), 937-939, 2015
The Chemical Society of Japan
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Keywords
Details
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- CRID
- 1390282679564949632
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- NII Article ID
- 130005085155
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- ISSN
- 13480715
- 03667022
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed