Absorption- and Pressure-induced Structural Transition Exhibiting V-shaped Density Change in Imidazolium-based Ionic Liquid + CO<sub>2</sub> System

  • Okumura Shuhei
    Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
  • Ushio Masayoshi
    Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
  • Oishi Akina
    Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
  • Nishikawa Keiko
    Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University
  • Morita Takeshi
    Division of Nanoscience, Graduate School of Advanced Integration Science, Chiba University

Bibliographic Information

Other Title
  • Absorption- and Pressure-induced Structural Transition Exhibiting V-shaped Density Change in Imidazolium-based Ionic Liquid + CO2 System

Abstract

The density of ionic liquid (IL) + CO2 systems was measured by X-ray absorption method and excess molar volume was evaluated to investigate the volumetric behavior under a CO2 absorption process up to 20 MPa. A V-shaped density plot was observed, and three types of expanded/compressed trends were classified based on the excess molar volume of the IL. The volumetric behavior of the IL strongly depends on the CO2 amount absorbed in the IL’s cavities.

Journal

  • Chemistry Letters

    Chemistry Letters 44 (7), 937-939, 2015

    The Chemical Society of Japan

Citations (1)*help

See more

References(16)*help

See more

Related Projects

See more

Details

Report a problem

Back to top