{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679565550720.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/cl.130987"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DC%2BC2cXivFSgtb4%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"11303554"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/digimeta/11303554"}},{"identifier":{"@type":"URI","@value":"https://dl.ndl.go.jp/pid/11303554"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/chemlett/article-pdf/43/1/36/55643458/cl.130987.pdf"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.201421296"}},{"identifier":{"@type":"NAID","@value":"130004427109"}}],"dc:title":[{"@language":"en","@value":"Layer-by-layer Nanoarchitectonics: Invention, Innovation, and Evolution"},{"@value":"Layer-by-layer nanoarchitectonics"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Materials fabrication with nanoscale structural precision based on bottom-up-type self-assembly has become more important in various current disciplines in chemistry including materials chemistry, organic chemistry, physical chemistry, analytical chemistry, biochemistry, colloid and surface chemistry, and supramolecular chemistry. Although the design of new materials based on nanoscale self-assembly is anticipated as a key concept, preparing complete three-dimensional structures at nanoscale precision remains a difficult target using current technologies. Rather, dimension-reduced approaches such as layering of two-dimensional nanostructures into precisely controlled lamellar nanomaterials are currently achievable. In particular, layer-by-layer (LbL) assembly is known as a highly versatile method for fabrication of controlled layered structures from various kinds of component materials using very simple, inexpensive, and rapid procedures. Therefore, fabrication of multilayer films through the LbL deposition process has attracted growing interest from various research communities. The high versatility and flexibility of LbL assembly is continuously creating new concepts, new materials, new procedures, and new applications. In this highlight review, we focus on nanoarchitectonics by LbL assembly. After an initial introduction on the invention and a brief history of the LbL assembly technique, innovations and the evolution of the technique are described based mainly on recent examples, which are categorized into two sections: (i) developments in methodology (technical, material, and phenomenological aspects with expansion of concept) and (ii) progress in applications (physical, chemical/biochemical, and biomedical applications)."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420001326221251712","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"50193082"},{"@type":"NRID","@value":"1000050193082"},{"@type":"ORCID","@value":"0000-0002-2445-2955"},{"@type":"NRID","@value":"9000004209585"},{"@type":"NRID","@value":"9000411623500"},{"@type":"NRID","@value":"9000257707755"},{"@type":"NRID","@value":"9000257897837"},{"@type":"NRID","@value":"9000256014708"},{"@type":"NRID","@value":"9000241574639"},{"@type":"NRID","@value":"9000241828678"},{"@type":"NRID","@value":"9000252961008"},{"@type":"NRID","@value":"9000366513986"},{"@type":"NRID","@value":"9000391396367"},{"@type":"NRID","@value":"9000412319560"},{"@type":"NRID","@value":"9000283388434"},{"@type":"NRID","@value":"9000340457337"},{"@type":"NRID","@value":"9000305637142"},{"@type":"NRID","@value":"9000257707951"},{"@type":"NRID","@value":"9000254400838"},{"@type":"NRID","@value":"9000413931433"},{"@type":"NRID","@value":"9000412231091"},{"@type":"NRID","@value":"9000257709125"},{"@type":"NRID","@value":"9000413566212"},{"@type":"NRID","@value":"9000319068711"},{"@type":"NRID","@value":"9000243722778"},{"@type":"NRID","@value":"9000018804740"},{"@type":"NRID","@value":"9000345274136"},{"@type":"NRID","@value":"9000240067364"},{"@type":"NRID","@value":"9000411623550"},{"@type":"NRID","@value":"9000254935284"},{"@type":"NRID","@value":"9000301713428"},{"@type":"NRID","@value":"9000411623620"},{"@type":"NRID","@value":"9000254935523"},{"@type":"NRID","@value":"9000257735145"},{"@type":"NRID","@value":"9000257737776"},{"@type":"NRID","@value":"9000391396351"},{"@type":"NRID","@value":"9000363178237"},{"@type":"NRID","@value":"9000402039409"},{"@type":"NRID","@value":"9000399757769"},{"@type":"NRID","@value":"9000257709868"},{"@type":"NRID","@value":"9000257713721"},{"@type":"NRID","@value":"9000257712014"},{"@type":"NRID","@value":"9000414070160"},{"@type":"NRID","@value":"9000402039400"},{"@type":"NRID","@value":"9000018265017"},{"@type":"NRID","@value":"9000391396360"},{"@type":"NRID","@value":"9000401604343"},{"@type":"NRID","@value":"9000410323833"},{"@type":"NRID","@value":"9000256014218"},{"@type":"NRID","@value":"9000345293646"},{"@type":"NRID","@value":"9000257704490"},{"@type":"NRID","@value":"9000258731093"},{"@type":"NRID","@value":"9000412368630"},{"@type":"NRID","@value":"9000396150883"},{"@type":"NRID","@value":"9000257772035"},{"@type":"NRID","@value":"9000257728198"},{"@type":"NRID","@value":"9000392701464"},{"@type":"NRID","@value":"9000391396461"},{"@type":"NRID","@value":"9000400181247"},{"@type":"NRID","@value":"9000410323880"},{"@type":"NRID","@value":"9000256048341"},{"@type":"NRID","@value":"9000256048343"},{"@type":"NRID","@value":"9000283394092"},{"@type":"NRID","@value":"9000356685127"},{"@type":"NRID","@value":"9000018850054"},{"@type":"NRID","@value":"9000402111933"},{"@type":"NRID","@value":"9000384339164"},{"@type":"NRID","@value":"9000347547475"},{"@type":"NRID","@value":"9000257734273"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0124890"}],"foaf:name":[{"@language":"en","@value":"Ariga Katsuhiko"}],"jpcoar:affiliationName":[{"@language":"en","@value":"World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)"},{"@language":"en","@value":"Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency (JST)"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679565550723","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000257737777"}],"foaf:name":[{"@language":"en","@value":"Yamauchi Yusuke"}],"jpcoar:affiliationName":[{"@language":"en","@value":"World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)"},{"@language":"en","@value":"Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST)"},{"@language":"en","@value":"Faculty of Science and Engineering, Waseda 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Lett."}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"},{"@language":"ja","@value":"公益社団法人 日本化学会"}],"prism:publicationDate":"2014","prism:volume":"43","prism:number":"1","prism:startingPage":"36","prism:endingPage":"68"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/digimeta/11303554"},{"@id":"https://dl.ndl.go.jp/pid/11303554"},{"@id":"https://academic.oup.com/chemlett/article-pdf/43/1/36/55643458/cl.130987.pdf"}],"availableAt":"2014","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Charge-Transfer%20Interaction","dc:title":"Charge-Transfer Interaction"},{"@id":"https://cir.nii.ac.jp/all?q=Aqueous%20Surfactant%20Solutions","dc:title":"Aqueous Surfactant Solutions"},{"@id":"https://cir.nii.ac.jp/all?q=Scanning-Electron-Microscopy","dc:title":"Scanning-Electron-Microscopy"},{"@id":"https://cir.nii.ac.jp/all?q=Polyelectrolyte%20Multilayer%20Films","dc:title":"Polyelectrolyte Multilayer Films"},{"@id":"https://cir.nii.ac.jp/all?q=Cationic%20Bipolar%20Amphiphiles","dc:title":"Cationic Bipolar Amphiphiles"},{"@id":"https://cir.nii.ac.jp/all?q=620","dc:title":"620"},{"@id":"https://cir.nii.ac.jp/all?q=Self-Assembled%20Monolayers","dc:title":"Self-Assembled Monolayers"},{"@id":"https://cir.nii.ac.jp/all?q=Prussian%20Blue%20Analog","dc:title":"Prussian Blue Analog"},{"@id":"https://cir.nii.ac.jp/all?q=Highly-Active%20Electrocatalysts","dc:title":"Highly-Active Electrocatalysts"},{"@id":"https://cir.nii.ac.jp/all?q=Mesoporous%20Nanocompartment%20Films","dc:title":"Mesoporous Nanocompartment Films"},{"@id":"https://cir.nii.ac.jp/all?q=Metal-Organic%20Frameworks","dc:title":"Metal-Organic Frameworks"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050290857727239424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Glowing gold nanoparticle coating: restoring the lost property from bulk gold"}]},{"@id":"https://cir.nii.ac.jp/crid/1050296829527063296","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Bio-based wrinkled surfaces harnessed from biological design principles of wood and peroxidase activity"},{"@value":"Bio‐based Wrinkled Surfaces Harnessed from Biological Design Principles of Wood and Peroxidase Activity"}]},{"@id":"https://cir.nii.ac.jp/crid/1050306506455344256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Synthesis of magnetic mesoporous titania colloidal crystals through evaporation induced self-assembly in emulsion as effective and recyclable photocatalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1050564288761637760","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Sequential structural control of open-framework nanoparticles both in dispersion and in film for electrochemical performance tuning"}]},{"@id":"https://cir.nii.ac.jp/crid/1050584870603523840","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Layer-by-Layer Nanoarchitectonics: A Method for Everything in Layered Structures"}]},{"@id":"https://cir.nii.ac.jp/crid/1050868361845624960","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Nanoarchitectonics of Polymers at Interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1050869456408766464","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"A Novel Physical Approach for Cationic-Thiolate Protected Fluorescent Gold Nanoparticles"},{"@value":"Approach for cationic-thiolate protected fluorescent gold nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216077323264","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Direct inclusion of triphenylphosphine derivatives into the zeolite Y supercage"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216819459072","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"What are the emerging concepts and challenges in NANO? 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