Conformational Regulation of Cyclophanes by Formation of Pseudorotaxane Based on a Charge-transfer Complex
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- Tsuge Akihiko
- Department of Applied Chemistry, Kyushu Institute of Technology
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- Nakamura Katsuji
- Department of Applied Chemistry, Kyushu Institute of Technology
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- Moriguchi Tetsuji
- Department of Applied Chemistry, Kyushu Institute of Technology
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- Araki Koji
- Department of Applied Chemistry, Kyushu Institute of Technology
Abstract
Cyclophanes consisting of diethylene glycol-substituted oligothiophene units as a component have been synthesized. Formation of pseudorotaxane arising from complexation of the cyclophanes and the cyclobis(paraquat-p-phenylene) (CBPQT4+) has been confirmed. It has also been discovered that conformational properties of the cyclophanes are strongly affected by the formation of pseudorotaxane.
Journal
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- Chemistry Letters
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Chemistry Letters 41 (9), 880-882, 2012
The Chemical Society of Japan
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Details
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- CRID
- 1390282679565571456
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- NII Article ID
- 130004426674
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- COI
- 1:CAS:528:DC%2BC38XhsVWhtLnE
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- ISSN
- 13480715
- 03667022
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed